• Title/Summary/Keyword: active materials

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The Study of Corrosion Behavior of Active Screen Plasma Nitrided Stainless Steels

  • Chiu, L.H.;Chang, C.A.;Yeh, S.H.;Chen, F.S.;Chang, Heng
    • Corrosion Science and Technology
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    • v.6 no.5
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    • pp.251-256
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    • 2007
  • Plasma nitriding is a surface treatment process which is increasingly used to improve wear, fatigue and corrosion resistance of industrial parts. Active screen plasma nitriding (ASPN) has both the advantages of the classic cold wall and the hot wall conventional dc plasma nitriding (DCPN) method and the parts to be nitrided are no longer directly exposed to the plasma. In this study, AS plasma nitriding has been used to nitride the UNS S31803 duplex stainless steel, AISI 304 and AISI 316 austenitic stainless steel, and AISI 420 martensitic stainless steel. Treated specimenswere characterized by means of microstructural analysis, microhardness measurements and electrochemical tests in NaCl aerated solutions. Hardness of the nitride cases of AISI 420 stainless steel by Knoop test can get up to 1300 HK0.1. From polarization tests, the corrosion current densities of AISI 420 and UNS S31803specimens ASPN at $420^{\circ}C$ were generally lower than those of their untreated substrates. The corrosion resistance of UNS S31803 duplex stainless steel can be enhanced by plasma nitriding at $420^{\circ}C$ Cowing to the formation of the S-phase.

Active Metal Brazing Applied to Joining of ZrO2-Ti Alloy (ZrO2-Ti합금의 활성금속 브레이징)

  • Kee, Se-Ho;Park, Sang-Yoon;Jung, Jae-Pil;Kim, Won-Joong
    • Journal of Welding and Joining
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    • v.30 no.3
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    • pp.38-43
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    • 2012
  • In this study, active metal brazing methods for $ZrO_2$ and Ti alloy were discussed. To get a successful metal-ceramic bonding, various factors (melting temperature, corrosion, sag resistance, thermal expansion coefficient etc. of base materilas and filler metal) should be considered. Moreover, in order to clarify bonding between the metal and ceramic, the mechanism of the interfacial structure of the joints should be identified. The driving force for the formation of metal and ceramic interfaces is the reduction of the free energy which occurs when their contact becomes complete. Interfacial bonding depends on the material combinations and the bonding processes. This study describes the bonding between ceramic and metal in an active metal brazing.

Development of a DDA+PGA-combined non-destructive active interrogation system in "Active-N"

  • Kazuyoshi Furutaka;Akira Ohzu;Yosuke Toh
    • Nuclear Engineering and Technology
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    • v.55 no.11
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    • pp.4002-4018
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    • 2023
  • An integrated neutron interrogation system has been developed for non-destructive assay of highly-radioactive special nuclear materials, to accumulate knowledge of the method through developing and using it. The system combines a differential die-away (DDA) measurement system for the quantification of nuclear materials and a prompt gamma-ray analysis (PGA) system for the detection of neutron poisons which disturb the DDA measurements; a common D-T neutron generator is used. A special care has been taken for the selection of materials to reduce the background gamma rays produced by the interrogation neutrons. A series of measurements were performed to test the basic performance of the system. The results show that the DDA system can quantify plutonium of as small as 20 mg and it is not affected by intense neutron background up to 1.57 × 107 s-1 and gamma ray of 4.43 × 1010 s-1. The gamma-ray background counting rate at the PGA detector was reduced down to 3.9 × 103 s-1 even with the use of the D-T neutron generator. The test measurements show that the PGA system is capable of detecting 0.783 g of boron and about 86.8 g of gadolinium in 30 min.

Bulk Heterojunction Organic Photovoltaics- Nano Morphology Control and Interfacial Layers

  • Kim, Gyeong-Gon
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.59.2-59.2
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    • 2012
  • Polymer solar cells utilize bulk heterojunction (BHJ) type photo-active layer in which the electron donating polymer and electron accepting $C_{60}$ derivatives are blended. We found there is significant charge recombination at the interface between the BHJ active layer and electrode. The charge recombination at the interface was effectively reduced by inserting wide band gap inorganic interfacial layer, which resulted in efficiency and stability enhancement of BHJ polymer solar cell.

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Channel Protection Layer Effect on the Performance of Oxide TFTs

  • KoPark, Sang-Hee;Cho, Doo-Hee;Hwang, Chi-Sun;Yang, Shin-Hyuk;Ryu, Min-Ki;Byun, Chun-Won;Yoon, Sung-Min;Cheong, Woo-Seok;Cho, Kyoung-Ik;Jeon, Jae-Hong
    • ETRI Journal
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    • v.31 no.6
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    • pp.653-659
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    • 2009
  • We have investigated the channel protection layer (PL) effect on the performance of an oxide thin film transistor (TFT) with a staggered top gate ZnO TFT and Al-doped zinc tin oxide (AZTO) TFT. Deposition of an ultra-thin PL on oxide semiconductor films enables TFTs to behave well by protecting the channel from a photo-resist (PR) stripper which removes the depleted surface of the active layer and increases the carrier amount in the channel. In addition, adopting a PL prevents channel contamination from the organic PR and results in high mobility and small subthreshold swings. The PL process plays a critical role in the performance of oxide TFTs. When a plasma process is introduced on the surface of an active layer during the PL process, and as the plasma power is increased, the TFT characteristics degrade, resulting in lower mobility and higher threshold voltage. Therefore, it is very important to form an interface using a minimized plasma process.

ZnO nanoparticles with different concentrations inside organic solar cell active layer

  • Saravanan, Shanmugam;Ismail, Yasser A.M.;Silambarasan, Murugesan;Kishi, Naoki;Soga, Tetsuo
    • Advances in Energy Research
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    • v.4 no.4
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    • pp.275-284
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    • 2016
  • In the present work, ZnO nanoparticles (NPs) have been dispersed alone in the same solvent of the active layer for improving performance parameters of the organic solar cells. Different concentrations of the ZnO NPs have been blended inside active layer of the solar cell based on poly(3-hexylthiophene) (P3HT), which forms the hole-transport network, and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM), which forms the electron-transport network. In the present investigations, the ZnO NPs may represent an efficient tool for improving light harvesting through light scattering inside active layer, electron mobility, and electron acceptance strength which tend to improve photocurrent and performance parameters of the investigated solar cell. The fill factor (FF) of the ZnO-doped solar cell increases nearly 14% compared to the non-doped solar cell when the doping is 50%. The present investigations show that ZnO NPs improve power conversion efficiency of the solar cell from 1.23% to 1.64% with increment around 25% that takes place after incorporation of 40% as a volume ratio of the ZnO NPs inside P3HT:PCBM active layer.

Electrochemical Properties of $LiMnO_2$ Cathode as a Function of Addition of Electric Active Materials for Lithium Polymer Batteries (리튬 폴리머 전지용 $LiMnO_2$정극의 도전재에 따른 전기 화학적 특성)

  • 조영재;김종욱;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.474-477
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    • 2001
  • The properties of LiMnO$_2$ was studied as a cathode active material for lithium polymer batteries. LiMnO$_2$ cathode active materials were synthesized by the reaction of LiOH . $H_2O$ and Mn$_2$O$_3$at various temperature under argon atmosphere. For lithium polymer battery applications, the LiMnO$_2$cell was characterized electrochemically by charge-discharge experiments and a.c. impedance spectroscopy. And the relationship between the characteristics of powders and electrochemical properties was studied in this research. A maximum discharge capacity of 160-170 mAh/g for ο-LiMnO$_2$ cell was achieved. Used that SP270 as electric active material in LiMnO$_2$, it is excellent than property of electric active material used Acetylene black or KS6 at charge/discharge capacity.

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Active control of three-phase CNT/resin/fiber piezoelectric polymeric nanocomposite porous sandwich microbeam based on sinusoidal shear deformation theory

  • Navi, B. Rousta;Mohammadimehr, M.;Arani, A. Ghorbanpour
    • Steel and Composite Structures
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    • v.32 no.6
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    • pp.753-767
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    • 2019
  • Vibration control in mechanical equipments is an important problem where unwanted vibrations are vanish or at least diminished. In this paper, free vibration active control of the porous sandwich piezoelectric polymeric nanocomposite microbeam with microsensor and microactuater layers are investigated. The aim of this research is to reduce amplitude of vibration in micro beam based on linear quadratic regulator (LQR). Modified couple stress theory (MCST) according to sinusoidal shear deformation theory is presented. The porous sandwich microbeam is rested on elastic foundation. The core and face sheet are made of porous and three-phase carbon nanotubes/resin/fiber nanocomposite materials. The equations of motion are extracted by Hamilton's principle and then Navier's type solution are employed for solving them. The governing equations of motion are written in space state form and linear quadratic regulator (LQR) is used for active control approach. The various parameters are conducted to investigate on the frequency response function (FRF) of the sandwich microbeam for vibration active control. The results indicate that the higher length scale to the thickness, the face sheet thickness to total thickness and the considering microsensor and microactutor significantly affect LQR and uncontrolled FRF. Also, the porosity coefficient increasing, Skempton coefficient and Winkler spring constant shift the frequency response to higher frequencies. The obtained results can be useful for micro-electro-mechanical (MEMS) and nano-electro-mechanical (NEMS) systems.