• 제목/요약/키워드: active material

검색결과 1,832건 처리시간 0.033초

성능향상을 위한 리튬전지의 Cathode active material에 관한 연구 (A Study on Cathode active material of Li/MnO$_2$ Battery for performance improvement)

  • 김학주;송수정
    • 한국산학기술학회:학술대회논문집
    • /
    • 한국산학기술학회 2001년도 추계산학기술 심포지엄 및 학술대회 발표논문집
    • /
    • pp.79-84
    • /
    • 2001
  • 본 논문에서는 리튬전지의 Cathode active material로 CMD(chemical manganese dioxide)를 사용하여 현재 사용중인 EMD(electrolytic manganese dioxide)와 공정 수율 및 특성과 방전 성능을 비교함으로써 새로운 cathode active material.로의 적용 가능성을 확인하기 위함이다.

Effects of the Mixing of an Active Material and a Conductive Additive on the Electric Double Layer Capacitor Performance in Organic Electrolyte

  • Yang, Inchan;Kwon, Soon Hyung;Kim, Bum-Soo;Kim, Sang-Gil;Lee, Byung-Jun;Kim, Myung-Soo;Jung, Ji Chul
    • 한국재료학회지
    • /
    • 제25권3호
    • /
    • pp.132-137
    • /
    • 2015
  • The effects of the mixing of an active material and a conductive additive on the electrochemical performance of an electric double layer capacitor (EDLC) electrode were investigated. Coin-type EDLC cells with an organic electrolyte were fabricated using the electrode samples with different ball-milling times for the mixing of an active material and a conductive additive. The ball-milling time had a strong influence on the electrochemical performance of the EDLC electrode. The homogeneous mixing of the active material and the conductive additive by ball-milling was very important to obtain an efficient EDLC electrode. However, an EDLC electrode with an excessive ball-milling time displayed low electrical conductivity due to the characteristic change of a conductive additive, leading to poor electrochemical performance. The mixing of an active material and a conductive additive played a crucial role in determining the electrochemical performance of EDLC electrode. The optimal ball-milling time contributed to a homogeneous mixing of an active material and a conductive additive, leading to good electrochemical performance of the EDLC electrode.

석고계 바인더를 활용한 습도도절 세라믹 보드의 특성 평가 (Evaluation of Humidity Control Ceramic Board Using Gypsum Binder)

  • 이종규;김태연
    • 한국재료학회지
    • /
    • 제28권1호
    • /
    • pp.62-67
    • /
    • 2018
  • Active clay, bentonite and zeolite were used as porous materials for humidity controlling ceramic boards. The specific area and the pore volume of active clay were higher than bentonite and zeolite. The flexible strength of the gypsum board decreased with an increasing amount of porous material, and the flexible strength was lowest when active clay with a higher specific surface area than others porous materials was added. The specific surface area and total pore volume of ceramic boards containing porous material were highest at $102.25m^2/g$, $0.142cm^3/g$, respectively, when the active clay was added. In addition, as the amount of added porous materials increased, the specific surface area and total pore volume of the ceramic board increased, but the average pore diameter decreased. The addition of s porous materials with a high specific area and a large pore volume improved the moisture absorptive and desorptive performance of the ceramic board. Therefore, in this experiment, the moisture absorptive and desorptive properties were the best when active clay was added. Furthermore, as the amount of added porous materials increased, the moisture absorptive and desorptive properties improved. When 70 mass% of active clay was added to ${\alpha}$-type gypsum, the hygroscopicity was the highest, about $300g/m^2$, in this experiment.

Design of a Plasmonic Switch Using Ultrathin Chalcogenide Phase-change Material

  • Lee, Seung-Yeol
    • Current Optics and Photonics
    • /
    • 제1권3호
    • /
    • pp.239-246
    • /
    • 2017
  • A compact plasmonic switching scheme, based on the phase change of a thin-film chalcogenide material ($Ge_2Sb_2Te_5$), is proposed and numerically investigated at optical-communication wavelengths. Surface plasmon polariton modal analysis is conducted for various thicknesses of dielectric and phase-change material layers, and the optimized condition is induced by finding the region of interest that shows a high extinction ratio of surface plasmon polariton modes before and after the phase transition. Full electromagnetic simulations show that multiple reflections inside the active region may conditionally increase the overall efficiency of the on/off ratio at a specific length of the active region. However, it is shown that the optimized geometrical condition, which shows generally large on/off ratio for any length of active region, can be distinguished by observing the multiple-reflection characteristic inside the active region. The proposed scheme shows an on/off switching ratio greater than 30 dB for a length of a few micrometers, which can be potentially applied to integrated active plasmonic systems.

젖산과 옥살산을 이용한 폐 이차 리튬이온 전지 양극 활물질로부터 희유금속들의 회수 (Recovery of Rare Metals from the Waste Secondary Lithium Ion Battery Cathode Active Materials Using Lactic Acid and Oxalic acid)

  • 김연정;한지선;최식영;오인경;홍용표;유건상
    • 대한화학회지
    • /
    • 제63권6호
    • /
    • pp.446-452
    • /
    • 2019
  • 젖산을 이용하여 안전하게 양극활물질에 있는 Co, Mn, Ni을 침출할 수 있는 방법을 개발하였다. 양극활물질을 젖산으로 침출 시켰을 때, 젖산의 농도는 1N과 4 N 이상에서 보다는 2 N에서 가장 높은 효율을 보였다. 양극활물질을 단계적으로 젖산 용액에 첨가 하였을 때, 최대 용해도는 2 N의 젖산 용액에서 1 L 당 30 g이었다. 젖산 용액에 옥살산을 첨가하였고 희유금속들은 1 L 당 4 g에서 가장 경제적인 회수율을 보였다. 본 연구를 바탕으로 해서, 양극활물질로부터 희유금속들을 회수하기 위한 최적의 조건은 무게비로 옥살산과 양극활물질이 7 : 1이라는 것을 확인할 수 있었다. 첨가하여, 옥살산에 의해서 생성된 침전물은 Co, Ni, Mn 3성분이 결합되어 있는 다핵 결정성 물질이었다.

분산제 PVA에 따른 수퍼커패시터용 이산화망간전극의 전기 화학적 특성 (Electrochemical Properties of MnO$_2$electrode for supercapactor wish a Diffuser (Polyvinylalcohol))

  • 이상오;김한주;박수길
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
    • /
    • pp.753-756
    • /
    • 2001
  • This research made a study of MnO$_2$electrode for supercapacitor with a diffuser (Polyvinyl alcohol). Manganese dioxide was used as active material. We tried to increase specific surface area by adding PVA. Manganese dioxide was synthesized by a sol-gel method using fumaric acid and oxalic acid in low temperature with high yield. Therefore, We prepared Manganese dioxide powder. This powder was used by active materials. The electrode was made by a mixture of active material, ketjen-black which is a large specific surface area, and PVdF-co-HFP as binder agent with using Nickel mesh as current collector. Here we reported on the synthesis and electrochemical performance of a enhanced material. All active materials have been submitted to X-ray diffraction and Scanning electron microscopy.

  • PDF

리튬 폴리머 전지용 $LiMnO_2$정극의 도전재에 따른 전기 화학적 특성 (Electrochemical Properties of $LiMnO_2$ Cathode as a Function of Addition of Electric Active Materials for Lithium Polymer Batteries)

  • 조영재;김종욱;구할본
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
    • /
    • pp.474-477
    • /
    • 2001
  • The properties of LiMnO$_2$ was studied as a cathode active material for lithium polymer batteries. LiMnO$_2$ cathode active materials were synthesized by the reaction of LiOH . $H_2O$ and Mn$_2$O$_3$at various temperature under argon atmosphere. For lithium polymer battery applications, the LiMnO$_2$cell was characterized electrochemically by charge-discharge experiments and a.c. impedance spectroscopy. And the relationship between the characteristics of powders and electrochemical properties was studied in this research. A maximum discharge capacity of 160-170 mAh/g for ο-LiMnO$_2$ cell was achieved. Used that SP270 as electric active material in LiMnO$_2$, it is excellent than property of electric active material used Acetylene black or KS6 at charge/discharge capacity.

  • PDF

정극 활물질 Li(Cr0.4Mn0.6)O2의 충ㆍ방전 특성 (Charge-discharge Properties of Positive Active Material Li(Cr0.4Mn0.6)O2)

  • 위성동;정인성;구할본
    • 한국전기전자재료학회논문지
    • /
    • 제17권10호
    • /
    • pp.1085-1089
    • /
    • 2004
  • An impedance properties of the positive active material Li(Cr$_{0.4}$Mn$_{0.6}$)O$_2$ are measured by the changeable trend to the time. The charge-discharge capacities of 297 mAh(g)$^{-1}$ 175 mAh(g)$^{-1}$ are obtained by the made cell with the active material that the Cr was added to LiMnO$_2$ to prevent structural degradation of an electrode active material with impedance of 75 Ω to get at an initial hour. Resultantly, these variations which the impedances enhanced continually, were not watched the impeditive variations as the results of the delay time that the positive thin films and the references have been soaked all together in the solution of electrolyte of 1M LiPF$_{6}$ EC/DEC(l/2). Accordingly, it means an amount increased of the discharged capacities in the view of the results that the impeditive values were decreased are known already through a authorized paper.per.

과붕산나트륨 양극 활물질 첨가에 따른 차량용 납산배터리 성능 특성 (Performance Characteristics of Lead Acid Battery with the Contents of Sodium Perborate Tetrahydrate (SPT) in Positive Plate Active Material)

  • 임태섭;김성준;김상동;양승철;정연길
    • 한국재료학회지
    • /
    • 제30권8호
    • /
    • pp.426-434
    • /
    • 2020
  • The performance characteristics of a lead acid battery are investigated with the content of Sodium Perborate Tetrahydrate (SPT, NaBO3·4H2O) in a positive plate active material. SPT, which reacts with water to form hydrogen peroxide, is applied as an additive in the positive plate active material to increase adhesion between the substrate (positive plate) and the active material; this phenomenon is caused by a chemical reaction on the surface of substrate. A positive plate with the increasing content of SPT is prepared to compare its properties. It is confirmed that the oxide layer increases at the interface between the substrate and the active material with increasing content of SPT; this is proven to be an oxide layer through EDS analysis. Battery performance is confirmed: when SPT content is 2.0 wt%, the charging acceptance and high rate discharge properties are improved. In addition, the lifetime performance according to the Standard of Battery Association of Japan (SBA) S0101 test is improved with increasing content of SPT.

농촌주부의 가정생활양식에 관한 연구 (A Study on Life Style of Rural Homemakers)

  • 박선화;채옥희
    • 한국농촌생활과학회지
    • /
    • 제7권1호
    • /
    • pp.69-80
    • /
    • 1996
  • The purpose of this study is to offer basic data of education to improve farm lives though investigating rural homemakers' life style. The results of this study are as follows : 1. The life structure of rural homemakers was classified into two structures as a material resources and human resources. The life style of rural homemakers was classified into systematical life style, traditional value style, social active style, and progressive active style. 2. The life styles of rural homemakers according to social population variance were as follows. The lower of age, homemakers whose family incomes more 30 million won or below 10 million won, who has religions, who employed in livestock were showed at very systematical life style. The homemakers who live in mountain village, higher the much age becomes, and the education level become lower, have showed traditional value style. Rural homemakers the lower of age, the higher incomes, composed of single parent + children who remain single were appeared social active style. Rural homemakers the lower of age, the more shortened farm life periods, who employed in livestock were appeared progressive active style. 3. Systematical life style was more affected by material resources structure, traditional value style was affected by material resources. And social active style was more affected by human resources, progressive active style was affected by human resources.

  • PDF