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Ammonia Decomposition Over Tantalum Carbides of Hydrogen Fuel Cell (수소연료전지용 탄탈륨 탄화물에 대한 암모니아 분해반응)

  • Choi, Jeong-Gil
    • New & Renewable Energy
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    • v.9 no.1
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    • pp.51-59
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    • 2013
  • Tantalum carbide crystallites which is to be used for $H_2$ fuel cell has been synthesized via a temperature-programmed reduction of $Ta_2O_5$ with pure $CH_4$. The resultant Ta carbide crystallites prepared using two different heating rates and space velocity exhibit the different surface areas. The $O_2$ uptake has a linear relation with surface area, corresponding to an oxygen capacity of $1.36{\times}10^{13}\;O\;cm^{-2}$. Tantalum carbide crystallites are very active for hydrogen production form ammonia decomposition reaction. Tantalum carbides are as much as two orders of magnitude more active than Pt/C catalyst (Engelhard). The highest activity has been observed at a ratio of $C_1/Ta^{{\delta}+}=0.85$, suggesting the presence of electron transfer between metals and carbon in metal carbides.

AN INVERSION METHOD FOR DERIVING PHYSICAL PROPERTIES OF A SUBSURFACE MAGNETIC FIELD FROM SURFACE MAGNETIC FIELD EVOLUTION I. APPLICATION TO SIMULATED DATA

  • Magara, Tetsuya
    • Journal of The Korean Astronomical Society
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    • v.50 no.6
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    • pp.179-184
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    • 2017
  • We present a new method for solving an inverse problem of flux emergence which transports subsurface magnetic flux from an inaccessible interior to the surface where magnetic structures may be observed to form, such as solar active regions. To make a quantitative evaluation of magnetic structures having various characteristics, we derive physical properties of subsurface magnetic field that characterize those structures formed through flux emergence. The derivation is performed by inversion from an evolutionary relation between two observables obtained at the surface, emerged magnetic flux and injected magnetic helicity, the former of which provides scale information while the latter represents the configuration of magnetic field.

Structural Arrangement for Functional Requirements of Brain Recombinant 4-Aminobutyrate Aminotransferase

  • Sung, Bo-Kyung;Kim, Young-Tae
    • BMB Reports
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    • v.33 no.1
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    • pp.43-48
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    • 2000
  • 4-Aminobutyrate aminotransferase is a key enzyme of the 4-aminobutyric acid shunt. It converts the neurotransmitter 4-aminobutyric acid to succinic semialdehyde. In order to study the structural and functional aspects of catalytically active Cys residues of pig brain 4-aminobutyrate aminotransferase, we purified the active form in E. coli by coproduction of thioredoxin. The structural arrangement for functional requirements of a dimeric protein using a bifunctional sultbydryl reagent was then characterized, and the spatial proximity between the essential SH groups and a cofactor (pyridoxal-5'-phosphate) binding site was determined. The bifunctional sultbydryl reagent DMDS reacted with the enzyme at the ratio of one molecule per enzyme dimer. This resulted in an approximately 50% loss of enzymatic activity. The spatial proximity of the distance between the essential SH groups and the cofactor-binding site was determined by the energy transfer measurement technique. The result (approximate 20 ${\AA}$) suggested that cross-linking of two sulfhydryl groups with DMDS is not near a PLP binding site.

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Weld Quality of MCFC Separators With Large Active Area (MCFC용 대면적 분리판의 용접부 품질에 관한 고찰)

  • Kim, K.C.;Jun, J.H.;Kim, S.G.;Kuk, S.T.;Lim, H.C.;Jung, B.S.
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.135-138
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    • 2009
  • Quality evaluation of laser welded MCFC separator panels with large active area was performed. Lap joint was applied to produce stable air-tight seam weld by employing Nd:YAG laser. Results showed that surface contamination played a key role to form weld defects at the joint interface. However, there was no evidence that weld width at the lap joint changed after the stack operation time of 2,890h. Test results also revealed that the reinforcement values which were measured on the weld line after long time operation, were stable.

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Formation of the Quiet Zone in an Automobile using Headset (헤드셋을 이용한 승용차 실내 저소음 영역의 생성)

  • Lee, Chul;Kim, In-Soo;Hong, Suk-Yoon
    • Journal of KSNVE
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    • v.7 no.2
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    • pp.301-310
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    • 1997
  • This paper presents active noise control method to form the near-field quiet zone for passengers in an automobile. The actuator model including interior acoustic plant, speaker and amplifier is experimentally identified in forms of auto-regressive and moving average by means of least mean square algorithm, The digital controller is composed of the regulator and Kalman filter to be designed based on LQG (linear quadratic gaussian). If the actuator model is prefiltered with digital filter to be properly designed for concentrating control performance index on the frequency band of primary noise source, LQG design approach can be effectively applied for the design of headset controller. Experimental results demonstrate that near-field quiet zone showing about 10dB noise reduction at microphone position can be formed using the headset located at passenger seat.

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On FEM modeling of piezoelectric actuators and sensors for thin-walled structures

  • Marinkovic, Dragan;Marinkovic, Zoran
    • Smart Structures and Systems
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    • v.9 no.5
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    • pp.411-426
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    • 2012
  • Thin-walled adaptive structures render a large and important group of adaptive structures. Typical material system used for them is a composite laminate that includes piezoelectric material based sensors and actuators. The piezoelectric active elements are in the form of thin patches bonded onto or embedded into the structure. Among different types of patches, the paper considers those polarized in the thickness direction. The finite element method (FEM) imposed itself as an essential technical support for the needs of structural design. This paper gives a brief description of a developed shell type finite element for active/adaptive thin-walled structures and the element is, furthermore, used as a tool to consider the aspect of mesh distortion over the surface of actuators and sensors. The aspect is of significance for simulation of behavior of adaptive structures and implementation of control algorithms.

Association of Riboflavin and Drug Molecules (Riboflavin과 약품 분자와의 회합)

  • 유병설
    • YAKHAK HOEJI
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    • v.28 no.2
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    • pp.101-127
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    • 1984
  • The study of interaction between riboflavin derivatives and biologically active substances was reviewed. With combination of spectroscopic methods such as NMR, UV, Fluorescence and IR, informations about interaction mechanism including hydrogen bond formation, conformation of association complex, and association constant were obtained. 1. Riboflavin associated with adenine but not with other bases found in the nucleic acids. -CONHCO- group was included in the formation of hydrogen bond with adenine. 2. Riboflavin interacted with alcohol to make a 1 : 1 association complex through the 3N-imino and 2C-carbonyl group of the isoalloxazine ring and the hydroxyl group of the alcohols. 3. Riboflavin associated with salicylates to produce the cyclic hydrogen-bonded dimer. The strongest complex was formed with salicylic acid, a weaker one with aspirin, and an even weaker one with salicylamide. 4. Other bio-active substances, orotic acid and inhibitors such as phenol, trichloroacetic acid and indol also formed hydrogen bond with riboflavin. 5. Reduced riboflavin showed strong self-association to produce the cyclic hydrogen-bonded complex and it associated with adenine and with cytosine to form 1 : 3 complex.

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A Study of the Hull Form of Oil Recovery Vessel by Using Magnetic Fluid (자성유체를 이용한 유회수선박의 선형연구)

  • 이귀주;박영식;김경화;노준혁;장희문
    • Journal of Ocean Engineering and Technology
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    • v.15 no.2
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    • pp.1-5
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    • 2001
  • A study on the new active type oil-water separation system including the oil-water separation system of magnetic film was carried out. Separation system is composed of several active types of circulating oil separation steps and one magnetic film separation step at final stage. At the magnetic separation step, ferrofluid easily forms a weak magnetic mixture with oil, which is from the water by magnetic field gradient. The vessel has been designed to run at the maximum speed of 25 knots. And two typical forms of SWATH and Catamaran have been studied as a new type of oil recovery vessel.

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Development of Non-Contacting Automatic Inspection Technology of Precise Parts (정밀부품의 비접촉 자동검사기술 개발)

  • Lee, Woo-Sung;Han, Sung-Hyun
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.6
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    • pp.110-116
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    • 2007
  • This paper presents a new technique to implement the real-time recognition for shapes and model number of parts based on an active vision approach. The main focus of this paper is to apply a technique of 3D object recognition for non-contacting inspection of the shape and the external form state of precision parts based on the pattern recognition. In the field of computer vision, there have been many kinds of object recognition approaches. And most of these approaches focus on a method of recognition using a given input image (passive vision). It is, however, hard to recognize an object from model objects that have similar aspects each other. Recently, it has been perceived that an active vision is one of hopeful approaches to realize a robust object recognition system. The performance is illustrated by experiment for several parts and models.

Thin Film Transistor with Transparent ZnO as active channel layer (투명 ZnO를 활성 채널층으로 하는 박막 트랜지스터)

  • Shin Paik-Kyun
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.1
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    • pp.26-29
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    • 2006
  • Transparent ZnO thin films were prepared by KrF pulsed laser deposition (PLD) technique and applied to a bottom-gate type thin film transistor device as an active channel layer. A high conductive crystalline Si substrate was used as an metal-like bottom gate and SiN insulating layer was then deposited by LPCVD(low pressure chemical vapour deposition). An aluminum layer was then vacuum evaporated and patterned to form a source/drain metal contact. Oxygen partial pressure and substrate temperature were varied during the ZnO PLD deposition process and their influence on the thin film properties were investigated by X-ray diffraction(XRD) and Hall-van der Pauw method. Optical transparency of the ZnO thin film was analyzed by UV-visible phometer. The resulting ZnO-TFT devices showed an on-off ration of $10^6$ and field effect mobility of 2.4-6.1 $cm^2/V{\cdot}s$.