• Title/Summary/Keyword: activated nitrogen

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Analysis of the Activated Sludge of a Municipal WWTP by Several Bio-Parameters

  • Cho Sun-Ja;Jung Yong-Ju;Park Tae-Joo;Lee Sang-Joon
    • Journal of Environmental Science International
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    • v.14 no.9
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    • pp.811-815
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    • 2005
  • The activated sludge from the aeration basin of the Su-yeong municipal wastewater treatment plant which has operated by a standard activated sludge process in Busan, Korea was investigated during April 2004 and January 2005 with several bio-indicators. The number of bacteria and fungi per gram of dry weight of MLSS were estimated to be $3.1\times10^6\sim1.5\times10^8\;and\;l.1\times10^3\sim1.1\times10^5$ colony forming units, respectively, by the plate agar method. By cultivation-independent methods, such as 4',6-diamidino-2-phenylindole stain and fluorescence in situ hybridization, the ratio of eubacteria to the entire biomass was evaluated by more than $80\%$ (v/v). The ratio of ammonia-oxidizing bacteria and nitrite-oxidizing bacteria to the total eubacteria was detennined to be $7.0\sim9.8\%\;and\;3.3\sim6.2\%$ without heavy variation in spite of a period of relatively low temperature in the basin. It would be expected that the nitrification would occur or at least co-exist throughout the year in the sludge of many municipal WWTP with influents that contain the sufficient nitrogen sources although the WWTP does not have any specialized processes for the removal of nitrogen.

Efficiency Evaluation of Adsorbents for the Removal of VOC and NO2 in an Underground Subway Station

  • Son, Youn-Suk;Kang, Young-Hoon;Chung, Sang-Gwi;Park, Hyun-Ju;Kim, Jo-Chun
    • Asian Journal of Atmospheric Environment
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    • v.5 no.2
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    • pp.113-120
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    • 2011
  • Adsorbent combination studies have been carried out to remove nitrogen dioxide ($NO_2$) and volatile organic compounds (VOCs: BTEX) out of a subway environment characterized by high flow and low concentration. Optimal conditions for the high removal efficiency of the concerned target compounds were obtained through testing a series of control factors such as adsorbent sorts, thicknesses, and superficial velocity. It was found that the efficiencies increased as the specific surface area of activated carbon and its thickness increased, and external void fraction decreased. Furthermore, mixed activated carbon with granular and constructed contents was extensively tested to reduce pressure drop through the carbon bed. It was found that the performance of higher contents of granular activated carbon was better than that of higher contents of the constructed carbon. When the mixed carbon was applied to the subway ventilation system in order to eliminate $NO_2$ and VOC simultaneously, the removal efficiencies were found to be 75% and 85%, respectively.

Successful start-up of pilot-scale single-stage ANAMMOX reactor through cultivation of ammonia oxidizing and ANAMMOX bacteria (암모니아 산화균 및 아나목스균의 배양을 통한 파일롯 규모 단일 아나목스 반응기의 성공적인 시운전)

  • Choi, Daehee;Jin, Yangoh;Lee, Chulwoo;Jung, Jinyoung
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.5
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    • pp.371-379
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    • 2018
  • The lack of seed sludges for Ammonium Oxidizing Bacteria (AOB) and slow-growing ANaerobic AMMonium OXidation (ANAMMOX) bacteria is one of the major problem for large-scale application. In this study, $24m^3$ of single-stage SBR (Sequencing Batch Reactor) was operated to remove nitrogen from reject water using AOB and ANAMMOX bacteria cultivated from activated sludge in the field. The ANAMMOX activity was found after 44 days of cultivation in the ANAMMOX cultivation reactor, and then $0.66kg\;N/m^3/d$ of the nitrogen removal rate was achieved at $0.78kg\;N/m^3/d$ of the nitrogen loading rate at 153 days of cultivation. The AOB cultivation reactor showed $0.2kg\;N/m^3/d$ of nitrite production rate at $0.4kg\;N/m^3/d$ of nitrogen loading rate after 36 days of operation. The cultivated ANAMMOX bacteria and AOB was mixed into the single-stage SBR. The feed distribution was applied to remove total nitrogen stably in the single-stage SBR. The nitrogen removal rate in the single-stage SBR was gradually enhanced with an increase of specific activities of both AOB and ANAMMOX bacteria by showing $0.49kg\;N/m^3/d$ of the nitrogen removal rate at $0.56kg\;N/m^3/d$ of the nitrogen loading rate at 54 days of operation.

Electrolytic Treatment of Ammonium Nitrogen and Nitrate Nitrogen by Bipolar Packed Bed Electrolytic Cell (충전복극전해조에 의한 암모니아성 및 질산성 질소의 전해처리)

  • Yun, Churl-Jong;Yu, Hyun-Chul;Kim, Jung-Sup;Lee, Bong-Seob;Kawk, Myoung-Hwa;Park, Seung-Cho
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.7
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    • pp.686-689
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    • 2005
  • This study was conducted to investigate the effect of ammonium and nitrate nitrogen removal to applied voltage, electrolytic time and activated carbon packing height. Batch bipolar packed bed electrolytic cell reactor was packed with $4{\times}8$ mesh granular activated carbon (GAC). Afterward electrolysis was performed in 20 V for 30 min. As a result, as the filling height adjusted to 80 mm high, the removal efficiency of ammonium nitrogen was 99.9%. and as the electrolytic time varied to 60 min, the removal efficiency of ammonium nitrogen was 97.6%. and in case of continuous electrolytic treatment of ammonium and nitrate nitrogen removal efficiency of total nitrogen was over 80% in bipolar packed bed electrolytic cell reactor for 72 hours as the packing height, sample concentration and input rate of sample adjusted to 280 mm, 30 mg/L, 6.7 mL/min, respectively.

The Preparation of PAN-based Activated Carbon Fiber by KOH (KOH 활성화에 의한 PAN계 활성탄소섬유의 제조)

  • 김기원;정승훈;임연수;정윤중
    • Journal of the Korean Ceramic Society
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    • v.36 no.6
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    • pp.577-582
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    • 1999
  • Activated carbon fibers were prepared from stabilized PAN fibers by chemical activation using hydroxide. The variations in specific surface area amount of iodine adsorption micro-structure and pore size distribution in the activated carbon fibers after the activation process were discussed. In the chemical activation using potassium hydroxide specific surface area of about 2545m2/g and amount of iodine adsorption of 2049 mg/g were obtained at the condition of KOH/fiber ratio of 1 and 800$^{\circ}C$ Nitrogen adsorption isotherms for PAN based activated carbon fibers showed the type I in the Brunauer-Deming-Deming-Teller classification indicating the micro-pores consisting the activated fibers.

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Preparation of Activated Carbon from Wastepaper and Adsorption of Endocrine Disrupting Chemicals

  • Okayama, Takayuki;Matsushita, Kiyofumi;Sasuzuki, Hiroma;Shimada, Masahiro
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.279-284
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    • 2006
  • Activated carbon is proposed as a new application of wastepaper recycling other than the paper-making. Waste kraft bag is considered to be a suitable raw material for activated carbon because of its low ash content. Small pellets of wastepaper squeezed out from the continuous kneader were carbonized in a nitrogen atmosphere and activated using carbon dioxide. The BET specific surface areas of activated carbon prepared from waste kraft bag was $1,285m^{2}/g$, which is higher than commercially available activated carbons. The activated carbon prepared from wastepaper has a well-developed porous structure, particularly in mesopore and macropore ranges. As a result, activated carbon with iodine adsorption capacity of 1,400 mg/g was obtained from waste kraft bag. In this paper, adsorption amount of Bisphenol A (BPA) was determined to investigate adsorbability of activated carbon from waste kraft bag. Adsorption measurements were on solutions ranging from $0.1{mu}g/L\;to\;100mg/L$. The activated carbon from waste kraft bag gave higher BPA adsorbabilities over a wide range, compared with commercially available activated carbons.

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Fuzzy Control and Optimization for the Wastewater Treatment Process (퍼지제어기를 이용한 하폐수처리공정의 최적화)

  • 천성표;김봉철;김성신
    • Proceedings of the Korean Institute of Intelligent Systems Conference
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    • 2000.11a
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    • pp.452-455
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    • 2000
  • There are increasingly important financial incentives and environmental consideration to improve the effluent quality of wastewater from domestic and industrial users. The activated sludge process is a widely used biological wastewater treatment process. The activated sludge process is complicated due to the many factors such as the variation of influent flowrate and concentration, the complexity of biological reactions and the various operation conditions. Nowadays, not only suspended solids and residual carbon, but also nitrogen and phosphorous concentration of the effluent water must be taken into account for the design and operation of wastewater treatment plants. Also, the effluent quality to be met are more stringent. Therefore, an intelligent control approach is required in order to successful biological nitrogen removal. In this paper, the strategies for dosage of extra carbon in the anoxic zone and DO concentration in the aerobic zone are presented and evaluated through the simulation using the denitrification layout of the IWA simulation benchmark implemented by Matlab$\^$/5.3/Simulink$\^$/3.0. The control strategy to achieve sufficient denitrification rates in an anoxic zone. Methanol is used as an external extra carbon source. The external extra carbon source is required for the nitrogen removal process because nitrogen and organic concentration are fluctuated in the influent flowrate. The dissolved oxygen is calculated by So concentration in the activated sludge model NO.1. The air flowrate of each aerobic reactor is intelligently controlled to achieve the predefined setpoints. Air flowrate is adjusted by the fuzzy logic controller that includes two inputs and one output. The objective function for the optimization procedure is designed to improve effluent quality and reduce the operating cost.

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Evaluation of the Removal Performance of Nitrogen Oxides of Foam Composites Using Activated Carbon and Titanium Dioxide (활성탄소와 이산화 타이타늄을 활용한 폼 복합체의 질소산화물의 제거 성능 평가)

  • Choi, Hyun-Chul;Choi, Young-Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.6
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    • pp.120-127
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    • 2022
  • Nitrogen oxide(NOx) is a major cause of air pollution, exists in the form of nitrogen monoxide and nitrogen dioxide, and is harmful to the human body. Recently, a number of studies to reduce NOx in the atmosphere have been conducted, and these efforts have been the same in the field of construction materials. It is known that NOx can be efficiently removed by using a photocatalytic reaction. In this study, the NOx removal performance of the foam composite using activated carbon(AC) and titanium dioxide(TiO2) was investigated. AC was used to enhance the photocatalytic reaction of TiO2 by increasing the internal specific surface area of the foam composite. In this study, foam composites were prepared using the substitution rate of AC as the main variable. The NOx removal performance of specimen was evaluated according to the test method presented in ISO-22197-1. The specific surface area of the foam composite showed a tendency to increase according to the AC content, but decreased at 15% or more. Also, when the AC substitution rate was 15%, the NOx removal efficiency was the highest.

A Study on the Municipal Wastewater Treatment Using Biofilm Process (생물막공법을 이용한 도시하수처리에 관한 연구)

  • Kwak, Byung Chan;Tak, Seong Jae;Kim, Nam Cheon;HWang, Yong Woo
    • Journal of Korean Society of Water and Wastewater
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    • v.14 no.1
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    • pp.62-75
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    • 2000
  • Most of biological treatment to remove contaminants in municipal wastewater have been conducted by activated sludge process. But, the process have several probIems such as enormous site needed for construction of treatment facilities, unstable treatment due to limited ability to control load fluctuation, frequent sludge bulking and appearance of lots of surplus sludge. In this study, the experiments were performed through submerging biofilm of PEPP media in existing aeration tank with raw water from municipal wastewater treatment plant and then submerging PVDC and PEPP media, different from shape and chemical peculiarity in anoxic reactor. Throughout the experience, nutrient removal efficiency according to HRT, nitrogen phosphorous removal efficiency, behavior of nitrogen and dewatering efficiency have been compared and analysed with those of activated sludge process. As the results, BOD removal efficiency according to BOD volumetric load and F/M ratio was not found any differency in two processes, but was decreased below 90% as going along the condition of high load in activated sludge process. Kinetic coefficient was $K_{max}=1.162day^{-1}$, $K_s=53.77mg/L$, $Y=0.166mgVSS/mgBOD_{rem}$. and $K_d=0.019day^{-1}$. It was found that the removal efficiency, even though in aerobic condition, in biofilm process equipped anoxic reactor was higher than the one in activated sludge process within the range of 70~80%, and became better as HRT increased. Phosphorous removal efficiency was not found any differency in two processes. In biofilm process, treament efficiency even in conditions of high load was not decreased, because the biomass concentration could be maintained in high condition compared with activated sludge process. As HRT increased, suspended and attached biomass was increased and the other hand, F/M ratio was decreased as biomass' increasing. Biomass thickness was increased. from $10.43{\mu}m$ to $10.55{\mu}m$ as HRT increased and density of biomass within $40.79{\sim}41.16mg/cm^2$. The results also present that the dewatering efficiency of sludge generated in biofilm process was higher than in activated sludge process, and became better as HRT increased.

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Rapid Determination of the Maximum Specific Growth Rates of Nitrogen Oxidizing Bacteria by Fed-Batch Experiments (Fed-Batch 실험장치(實驗裝置)를 이용한 질산화(窒酸化) 미생물(微生物)들의 최대(最大) 성장율(成長率)의 결정(決定)에 관한 실험적(實驗的) 연구(硏究))

  • Lee, Byonghi
    • Journal of Korean Society of Water and Wastewater
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    • v.10 no.3
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    • pp.55-63
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    • 1996
  • Nitrification reaction consists of two reactions: nitritification which oxidizes ammonia nitrogen to nitrite nitrogen and nitratification which oxidizes nitrite nitrogen to nitrate nitrogen. Each reaction is carried out by Nitrosomonas and Nitrobacter, respectively. The effective maximum growth rates for both bacteria have to be determined to design aeration tank whenever the aeration tanks have to nitrify ammonia nitrogen in influent. And these values are very important to use mathematical models such as IAWPRC model to simulate nitrification in activated sludge. There are several methods to determine these valves, however, the Fed-Batch experiments can determine these values within 72 hours. In this study, the mathematical equations and experimental procedures for Fed-Batch test are presented. Also, the experimental data and reported values are compared. The estimated mean values of maximum specific growth rates for Nitrosomonas and Nitrobacter are $0.5010day^{-1}$ and $0.6704day^{-1}$, respectively.

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