• Title/Summary/Keyword: acrylamide.

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Acrylamide Polymerization on Ceramic Powders (III) -Effect on Molecular Structure of Polymer Dispersant on SiN4 Gelcasting Process- (세라믹분체 표면에서 아크릴아마이드 중합(제3보)-고분자 분산제의 분자구조가 질화규소 겔캐스팅공정에 미치는 영향-)

  • 류병환;김은영;이재도
    • Journal of the Korean Ceramic Society
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    • v.36 no.3
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    • pp.266-273
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    • 1999
  • 본 연구에서는 겔캐스팅법의 제조공정 확립을 위하여 분산제의 분자구조가 질화규소 슬립의 점성특성 및 성형체의 상대밀도와 기계적 특성에 미치는 영향을 조사하였다. 슬립과 겔캐스팅 성형체의 제조방법은 기보고된 방법과 동일하게 하였다. 그 결과, 겔캐스팅 슬립의 점성은 분산제의 분자구조와 모노머와 분산제의 구성비율에 크게 의존하였다. PMAA 분산제를 사용한 슬립의 점성은 PAA 및 PAAm 분산제 보다 높은 점도를 나타내었다. 성형체의 상대밀도는 슬립의 농도에 크게 의존하였으며, 분산제양과 모노머의 양변화에는 그다지 변화가 없었다. 그리고, 겔캐스팅 성형체의 기계적 특성은 크게 모노머의 농도에 의존하였으며, 분산제양과 슬립의 농도에는 큰 변화가 없었다.

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Modification of Polymer Surface by Corona Discharge and the Subsequent Graft Polymerization of Acrylamide (코로나 방전처리와 아크릴아미드 그라프트 중합에 의한 고분자 표면개질)

  • 김형우;김찬영;박병기
    • Textile Coloration and Finishing
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    • v.5 no.1
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    • pp.26-32
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    • 1993
  • This study is concerned with the graft polymerization of acrylamide onto the surfaces of polyethylene and polyethylene terephthalate films treated with on corona discharge. In the case, peroxides formed by the corona discharge treatment are likely to be the species responsible for initiating the graft polymerization. This treatment produced a continuous charge in wettability and also amid group density on the polymer surface, as evidenced by water contact angle measurement, Fourier-transform infrared spectroscopy in the attenuated total reflectance mode, and electron spectroscopy for chemical analysis. Both of the merely corona-treated film and the subsequently grafted film are discussed as a function of time after treatment and water washings.

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Effect of Modification of SeO2/Acrylamide Ratios on Diffraction Efficiencies in PVA/AA Photopolymer Films

  • Kim, Dae-Heum;Lim, Ji-Yun;Nam, Seung-Woong;Chung, Dae-Won
    • Journal of the Optical Society of Korea
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    • v.11 no.4
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    • pp.183-191
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    • 2007
  • The highest diffraction efficiency(DE) value after illumination and post-curing of photopolymer films were obtained at the $SeO_2$/Acrylamide(AA) Ratios of AA 3.0 g, $SeO_2$ 1.0g and the DE's were stable values of over 90%. By the addition of $SeO_2$, the maximum DE at the initial stage of illumination was reached at 300 seconds, which suggests $SeO_2$ slows down the photopolymerization of AA, which enhances the maximum DE value by giving more migration time. DE variation curve for the optimum composition during extended-time illumination of 9,000 seconds resembles a sine curve due to the combination of the monomer diffusion and the photopolymerization, and the photopolymer film expanded by about 8% after photopolymerization due to monomer migration.

Fractionation of Plasma Protein on the Several Fresh Water Fishes by Disc Electrophoresis (Disc 전기영동법에 의한 수종 담수어 혈장 단백질의 분획)

  • 홍사욱;박성배
    • YAKHAK HOEJI
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    • v.22 no.1
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    • pp.42-50
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    • 1978
  • The plasma proteins of fresh water fishes have been fractionated by disc electrophoresis in acrylamide gels utilized as an electrophoretic supporting medium. The species of fishes examined in this experiment were Anguilla japonica, Misgurnus mizolepis, Parasilurus asotus, Siniperca scherzeri, Pelteobagrus fulvidra, Carassius carassius, Cyprinus carpio, and Hemibarbus labeo, obtained in the Han River. Disc electrophoresis was performed as described by Ornstein and Davis. Gels and buffer solution were prepared by the method developed by W.J.Kim. The separation gels were 7% acrylamide gel. The fractionation of plasma proteins showed 13 bands in Anguilla japonica, 10 in Misgurnus mizolepis, 15 in Parasilurus asotus, 12 in Siniperca scherzeri, 11 in Pelteobagrus fulvidra, 13 in Carassius carassius, 9 in Cyprinus carpio, and 13 in Hemibarbus labeo. The patterns of plasma protein on the each species of fishes were different in the number of bands, ratio of contents, relative mobilities, and forms of fractionation.

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Acrylamide Polymerization on Ceramic Powders(II) : Effect of MeOH on Si$_3$N$_4$ Gelcasting (세라믹분체 표면에서 아크릴아마이드 중합(제2보) : MeOH가 질화규소 겔캐스팅에 미치는 영향)

  • 류병환;김은영;이재도
    • Journal of the Korean Ceramic Society
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    • v.36 no.2
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    • pp.220-224
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    • 1999
  • For the process control of silicon nitride gelcasting, the effect of MeOH on the apparent gel induction time of slip, drying rate, and mechanical property of gelcast body were investigated. The apparent gel induction time showed maximum at 10~20 vol% MeOH and the drying rate of gelcast body increased in the ranged of 25~40%. The gelcast body was still machinable in the 40% of MeOH, though the mechanical property and relative density slightly decreased with increasing the amount of MeOH.

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Synthesis of Block Copolymers Composed of Poly(N,N-dimethylamino ethyl methacrylate) and PEG and Formation of Nanoaggregation (Poly(N,N-dimethylamino ethyl methacrylate)와 PEG로 이루어진 블록공중합체 합성 및 나노복합체 형성)

  • 김은정;최호석;이지나;박기동;육순홍
    • Polymer(Korea)
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    • v.24 no.6
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    • pp.854-859
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    • 2000
  • The synthesis of poly(N,N-dimethylamino ethyl methacrylate (DMAEMA)-block-poly(ethylene glycol) (PEG)) copolymer has been carried out and the block copolymer was characterized by FT-IR, DSC, and $^1$H-NMR. The formation of polymeric nanoaggregation was observed in the solution mixture of poly(DMAEMA) -block-PEG copolymer and poly (ethyl acrylamide) (EAAm) due to the intermolecular interaction via hydrogen bond between DMAEMA and poly(EAAm). The formation of polymeric nanoaggregation was observed above critical micelle concentration (CMC).

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A Study of Drag Reduction by Polymer Additives in Rotating Disk Geometry (회전 Disk계에서 고분자 첨가제에 의한 마찰저항감소 연구)

  • 최형진
    • The Korean Journal of Rheology
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    • v.3 no.1
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    • pp.76-85
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    • 1991
  • 적은양의 분자량이 큰선형 고부자를 수용액에 첨가함으로서 얻어지는 마찰저항가소 연구가 rotating disk 장치를 이용해 수행되었다. 마찰저항 감소제로 poly(ethylene oxide)와 poly(acrylamide)를 사용하였으며 고분자 분자량 고분자 농도, disk 의 회전속도 및 온도 등 여러 가지 인자에 대한 마찰정항감소의 의존성을 연구하였다. 또한 마찰저항 감소 효과와 고분자 용액의 점도평균 분자량을 동시에 측정함으로서 고분자 퇴화에 대한 연구도 수행하 였다. 마찰저항감소는 고분자 농도가 증가함에 따라 임계농도에 도달할때까지 증가하였고 낮은 농도에서는 분자량이 큰 고분자일수록 더욱 큰 마찰저항 감소효과를 나타내었다. 마찰 감소 진행 중의 높은 전단력에 기인하는 고분자의 분해는 고분자 농도가 낮은데에서 더욱두 드러지게 나타났으며 온도 효과의 연구로부터 poly(acrylamide)가 poly(ethylene oxide)보다 열적으로 안정함을 알수 있었다.

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Dyeing Properties of Cationized Cotton Fabrics with Reactive Dye (캐티온화한 면직물에 대한 반응성염료의 염색성)

  • Jung, Young Jin;Lee, Young Hee;Kim, Kyung Hwan
    • Textile Coloration and Finishing
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    • v.5 no.4
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    • pp.20-28
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    • 1993
  • Primary amino group was introduced into cellulose by the Hofmann reaction from carbamoylethylated cotton fabrics. Cabamoylethylated cotton was prepared by treating the cotton fabrics with acrylamide and sodium hydroxide catalysts. These amino group altered physical and chemical properties of cotton fabrics. The influence of reactive dyeing, tensile strength and crease recovery was investigated. The exhaustion of reactive dye with cationized cotton fabrics was increase with acrylamide concentration. The pH value of maximum exhaustion was exchanged from 11.0 to 9.0 in cationized cotton fabrics.

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pH-dependent Swelling Properties of Methacrylic Acid Copolymer Hydrogels (pH 의존성 Methacrylic acid 공중합체의 팽윤특성)

  • Kim, Kyung-Chung;Lee, Seung-Jin
    • YAKHAK HOEJI
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    • v.33 no.6
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    • pp.372-376
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    • 1989
  • Equilibrium swelling and pH-sensitivity of a polyelectrolyte copolymer hydrogel were controlled by employing copolymers with different hydrophilic-hydrophobic balances. Model pH-sensitive hydrogels, e.g., poly(methacrylic acid), poly(methacrylic acid-co-acrylamide), poly(methacrylic acid-co-2-hydroxyethylmethacrylate), poly(methacrylic acid-co-styrene) were synthesized at various monomer compositions. As hydrophobicity of the copolymer hydrogels increased, the equilibrium swelling decreased while the pH-sensitivity increased. In the case of poly(methacrylic acid-co-acrylamide), polymer-polymer interaction significantly affected the equilibrium swelling and provided a wide range control of pH-sensitivity.

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Photochemical bleaching properties of photopolymer (포토폴리머의 광화학 표백 특성)

  • 성기영;경천수;이영락;곽종훈;최옥식;이윤우;이인원;서호형
    • Korean Journal of Optics and Photonics
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    • v.10 no.4
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    • pp.335-341
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    • 1999
  • We fabricate acrylamide photopolymer as a holographic recording material and investigrate photobleaching characteristics. To explain the photobleaching kinetics of photopolymer we adopt two models of the Beer-Lambert law and optical transmittance based on rate equations obtained from a simplified energy-band model. The Beer-Lambert law is in good agreement with the experimental results in a first short-time region but not in long-time region. But the optical transmittance model based on rate equations explains the experimental results very well in both short-and long-time regions.

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