• Title/Summary/Keyword: acryl

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A Study on the Application to Anti-corrosive Film of Acryl Emulsion for the Reducing of Environmental Pollutants (환경유해물질 저감을 위한 Acryl emulsion의 방청필름 응용 연구)

  • Lee, S.H.
    • Corrosion Science and Technology
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    • v.8 no.5
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    • pp.197-202
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    • 2009
  • The high toxicity of wax, oil, varnish and volatile corrosion inhibitor(VCI) corrosion inhibitors lead to an increasing interest in using non-toxic alternatives such as anti-corrosive film. This study aims to investigate the possibility to use acryl based anti-corrosive film as a substitution of toxic corrosion inhibitors. Acryl emulsions were polymerized by several acryl monomers(acrylonitrile(AN), n-butyl acrylate(nBA), methylmethacrylate(MMA) and glycycyl methacrylate(GMA)), non-toxic corrosion inhibitor, crosslinking agents(diethylene glycol dimethacrylate(DEGDA)) and various additives in order to apply substrate of anti-corrosive film. Acryl emulsion for anti-corrosive film(AeACF) as a substrate of corrosion inhibitor film has excellent removal characteristic at above $25^{\circ}C$. The crosslinked by DEGDA in a range of above 4 wt% content anti-corrosive film can easily remove from the metal surface by using hands because it kept a balance of cohesion and adhesion strength. Anti - corrosive performance of AeACF is better than anti-corrosive oil by corrosion rate test, which was measured $54.3mg/dm^2$ day(MDD) and $142.9mg/dm^2$ day, respectively. Anti-corrosive film consisting of acryl monomers and inorganic anti-corrosive ingredients did not emit any toxic pollutants by gas chromatography. Thus it is estimated that acryl based anti-corrosion film can substitute toxic corrosion inhibitors.

Study on the Physical Properties by Combining Epoxy and Acryl Electrodeposition Paints (에폭시와 아크릴 전착도료의 혼용성에 따른 물성 변화 연구)

  • Jung, Sung Soo;Yi, Dong Uk;Kim, Dong Won;Kim, Myung Hwan;Kwag, Sam Tag;Moon, Myung Jun
    • Journal of the Korean institute of surface engineering
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    • v.47 no.3
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    • pp.137-146
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    • 2014
  • The important drawback of epoxy electrodeposition(ED) coatings is the lack of the weathering resistance caused by the structure of bisphenol A. To improve this yellowing phenomena, acryl ED coatings have been developed. Compared with the epoxy ED coatings, however, acryl ED coatings are relatively weak in the corrosion resistance and mechanical properties. The purpose of this study is complemented their drawbacks by mixing epoxy and acryl ED paints. The salt spray, accelerated weathering test(QUV) and cupping, bending, impact test were employed to investigate the corrosion resistance, weathering resistance, and mechanical properties of ED coatings. When the ratio of acryl to epoxy resin of ED coating is 0.33, the weathering resistances are appropriately improved in condition maintaining the corrosion resistance. It was shown that the weathering resistance for epoxy ED coating was adjusted by optimally mixing acryl ED paint.

Effect of polymerization temperature on the mechanical properties of provisional prosthesis resins (중합 온도가 임시 보철용 수지의 기계적 성질에 미치는 영향)

  • Hong, Min-Ho;Ha, Jung-Yun;Kwon, Tae-Yub
    • Korean Journal of Dental Materials
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    • v.44 no.4
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    • pp.311-318
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    • 2017
  • The purpose of this study was to examine the effects of the curing sequence and polymerization temperature on the flexural strength and microhardness of two provisional resins (Bis-acryl resin composite and polymethyl methacrylate (PMMA)). Polymerization was carried out under various conditions, in air at $25^{\circ}C$ (control) and in hot water (40, 50, 60, 70, and $80^{\circ}C$). The flexural strength test was conducted according to ISO-4049. The Knoop hardness was measured. For the Bis-acryl resin, the temperature up to $50^{\circ}C$ did not increase the flexural strength nor the hardness of the bis-acryl resin composite (p>0.05) but higher temperatures increased the strengths. For the PMMA resin, flexural strength increased with temperatures up to $70^{\circ}C$ and then decreased slightly. Bis-acryl resin composite had higher mechanical properties than the PMMA resin. The effect of heat was more pronounced in the bis-acryl resin composite than in the PMMA resin (p<0.05).

Effect of light-curing, pressure, oxygen inhibition, and heat on shear bond strength between bis-acryl provisional restoration and bis-acryl repair materials

  • Shim, Ji-Suk;Lee, Jeong-Yol;Choi, Yeon-Jo;Shin, Sang-Wan;Ryu, Jae-Jun
    • The Journal of Advanced Prosthodontics
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    • v.7 no.1
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    • pp.47-50
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    • 2015
  • PURPOSE. This study aimed to discover a way to increase the bond strength between bis-acryl resins, using a comparison of the shear bond strengths attained from bis-acryl resins treated with light curing, pressure, oxygen inhibition, and heat. MATERIALS AND METHODS. Self-cured bis-acryl resin was used as both a base material and as a repair material. Seventy specimens were distributed into seven groups according to treatment methods: pressure - stored in a pressure cooker at 0.2 Mpa; oxygen inhibition- applied an oxygen inhibitor around the repaired material,; heat treatment - performed heat treatment in a dry oven at $60^{\circ}C$, $100^{\circ}C$, or $140^{\circ}C$. The shear bond strength was measured with a universal testing machine, and the shear bond strength (MPa) was calculated from the peak load of failure. A comparison of the bond strength between the repaired specimens was conducted using one-way ANOVA and Tukey multiple comparison tests (${\alpha}$=.05). RESULTS. There were no statistically significant differences in the shear bond strength between the control group and the light curing, pressure, and oxygen inhibition groups. However, the heat treatment groups showed statistically higher bond strengths than the groups treated without heat, and the groups treated at a higher temperature resulted in higher bond strengths. Statistically significant differences were seen between groups after different degrees of heat treatment, except in groups heated at $100^{\circ}C$ and $140^{\circ}C$. CONCLUSION. Strong bonding can be achieved between a bis-acryl base and bis-acryl repair material after heat treatment.

Fabrication and characterization of photocurable inorganic-organic hybrid materials using organically modified colloidal-silica nanoparticles and acryl resin

  • Kang, Dong-Jun;Han, Dong-Hee;Kang, Young-Taec;Kang, Dong-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.422-422
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    • 2009
  • Photocurable inorganic-organic hybrid materials were prepared from colloidal-silica nanoparticles synthesized through the solgel process and using acryl resin. The synthesized colloidal-silica nanoparticles had uniform diameters of around 20 nm, and they were organically modified, using methyl and methacryl functional silanes, for efficient hybridization with acryl resin. The organically modified and stabilized colloidal-silica nanoparticles could be homogeneously hybridized with aeryl resin without phase separation. The successfully fabricated hybrid materials exhibit efficient photocurability and simple film formation due to the photopolymerization of the organically modified colloidal-silica nanoparticles and acryl resin upon UV exposure. The fabricated hybrid films exhibit an excellent optical transmission of above 90% in the visible region as well as an enhanced surface smoothness of around 1 nm RMS roughness. In addition, the hybrid films exhibit improved thermal and mechanical characteristics, much better than those of acryl resin. More importantly, these photocurable hybrid materials fabricated through the synergistic combination of colloidal-silica nanoparticles with acryl resin are candidates for optical and electrical applications.

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A Study on Texture Suited for the Acryl Knitted Jacket of Women in the Middle Age (중년 여성용 아크릴 니트 재킷에 적합한 조직에 관한 연구)

  • Choi, Jin-Hee
    • The Research Journal of the Costume Culture
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    • v.17 no.1
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    • pp.15-27
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    • 2009
  • The purpose of this study was to find texture which suitable for the acryl knitted jacket of women in the middle age. The study was carried out 2 parts. The first part was to choose the pattern fitted in the body shape of women in the middle age, and the second part was wearing test with 3 different textured acryl knitted jacket(half milano, milano, jacquard). The usable data of the test were coded for further statistical analysis including descriptive statistics (frequency and one way-ANOVA test, Student-Newman-Keuls Multiple Range Test) by using SPSSWIN 12.0. The results were as follows: It was found that first evaluation for the appearance test on fitness, pattern B(Brand: Morado) were better than the rest of them(pattern A: Trieste, pattern C: Escalier). It was found that second evaluation for the test, jacket with jacquard were better than the rest of them. Acryl knitted Jacket of women in the middle age should made of jacquard. Therefore it should be designed as possible as considering the physical characteristics of knitted materials. It was found that third evaluation for the test, it was opposite results that a general knitted fabric pattern was made smaller than a woven jacket. So, it was necessary that the acryl knitted jacket of women in the middle age follow a similar site tolerance such as a woven jacket. This result was due to a radical change of a middle age women's body shape.

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Implementation of a BLU system for advertisements using a LED and Acryl (LED와 아크릴을 이용한 광고용 BLU 시스템 구현)

  • Kim, Han-Na;Lee, Hyuek-Jae
    • Journal of the Institute of Convergence Signal Processing
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    • v.11 no.4
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    • pp.326-331
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    • 2010
  • This paper has proposed and experimentally demonstrated a new BLU using an LED and an acryl, which is specially focused on the implementation about the guiding effect of an acryl luminous by the LED. While the conventional BLU using a fluorescent lamp is generally and widely used, it shows big power consumption with a short life even more too thick to hold on the wall. To solve such demerits, we propose a new method for a BLU using an LED and an acryl in this paper. This BLU system has various scratches on the surface of acryl to get diffusion effect of light, and has been included an embedded board that can dynamically control the colors and the intensity of the BLU through the Internet. We have conducted computer simulations to find out the optimal scratch pattern on the surface of the acryl for the backlight system. Based on the resulted out simulation. The the optimal scratch pattern signs has been developed. The simulation result shows 2,673Lux an average for a luminous intensity test, and the other hand, experiential result shows 2,554Lux. From the experiments, it is possible for the proposed BLU system to be used for real advertisements.

Evaluation of MTF Image by Target/Filter Combined of X-ray Tube Using Mammography (유방촬영용 X선관 target/filter 조합에 따른 MTF영상평가에 관한 고찰)

  • Yang, Han-Jun;Joo, Mi-Hwa;Ko, Sin-Kwan
    • Journal of radiological science and technology
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    • v.30 no.2
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    • pp.113-119
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    • 2007
  • It is important to consider the contrast of object in Mammography because an absorption gap between tissues of body and breast in breast is low. This study is to evaluate MTF image with resolution chart according to change of combination of target and filter. The results were as follows : 1. There were significant differences in X-ray energy according to combination of filter(Mo/Mo, Mo/Rh. Mo/Al, Rh/Rh, Rh/Al) and acrylic thickness(2 cm, 3 cm, 4 cm). 2. The value of lp/mm on MTF to 0.5 showed that the sharpness in MTF curve was 2.4 compared to Mo/Mo and 2cm acryl, 2.63 in Mo/Rh and 4 cm acryl, and 2.9 in Rh/Rh and 6cm acryl. 3. The value of lp/mm on MTF showed that the resolution in MTF curve was 6.0 compared to Mo/Mo and 2 cm acryl, 4.60 in Rh/Al and 4cm acryl, and 6.03 in Rh/Al and 6 cm acryl. 4. The value of MTF on 2.5 lp/mm distinguishable visually was 0.48 compared to Mo/Mo and 2 cm acryl, 0.53 in Mo/Rh and 4cm acryl, and 0.59 in Rh/Rh and 6cm acryl. 5. For the evaluation of an image of the mammo-phantom, the score of Mo/Mo was 12 points, Mo/Rh 11, Rh/Rh 10.5, Mo/Al 10, Rh/Al 9.0, respectively.

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A Study on the Physical Characteristics of Acryl Concretes for Thin Bridge Deck Pavements (박층 교면포장용 아크릴 콘크리트의 물리적 특성 연구)

  • Kim, Tae-Woo;Kim, Dae-Young;Nguyen, Manh Tuan;Lee, Hyun-Jong
    • International Journal of Highway Engineering
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    • v.11 no.3
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    • pp.1-11
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    • 2009
  • This study focuses on evaluating the applicability of an acryl based polymer concrete to the thin bridge deck pavements. The acryl concrete developed in this study is composed of Methyl Methacrylate(MMA) resin, benzol peroxide and fillers. To study the effects of the types and amounts of the components on the physical characteristics of the acryl concrete, viscosity, compressive strength and bending tests were conducted. The optimum mixture design was then determined based on the testing results. Several different types of laboratory tests, such as water and chlorine ion penetration tests, shrinkage and thermal coefficients tests, and tensile bonding strength tests were performed for the optimum acryl concrete and conventional cement concrete. The testing results show that water and chroline ion resistance, bonding strength between acryl and cement concrete and crack resistance of the acryl concrete is better than those of the conventional cement concrete. There are shortcomings that the conventional acryl concrete has a higher shrinkage and thermal coefficients. However, it was confirmed that to use newly developed rubberized MMA resin in this study reduces the crack resistance with substantially increased ductility.

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Preparation of Acryl Binder with Silane Type Chain Transfer Agent (실란계 사슬 이동제를 사용한 아크릴 바인더의 제조)

  • Kim, Jin-Gon;Shin, Min-Jae;Shin, Jae-Sup
    • Polymer(Korea)
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    • v.36 no.3
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    • pp.351-356
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    • 2012
  • Acryl binder is a representative organic additive for the manufacture of the display electronic equipment. Acryl binder is usually synthesized by radical copolymerization. Glycidyl methacrylate (GMA), methyl methacrylate (MMA), and methacrylic acid (MAA) were used in this copolymerization of acryl binder. In this study the silane type mercaptane compound was used as a chain transfer agent (CTA) to enhance the adhesion property of the acrylic binder. The CTA used in this experiment was (3-mercaptopropyl) trimethoxysilane (MPTMS). Molecular weight of the copolymer, thickness of the coating, transmittance, and adhesion property were measured. The molecular weight was controlled and the adhesion property was improved by using this silane type chain transfer agent.