• Title/Summary/Keyword: acid washing

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Heavy Metal Removal Efficiency in Accordance with Changes in Acid Concentrations in a Micro-nano Bubble Soil Washing System and Pickling Process (마이크로나노버블 토양세척시스템 및 산세척 복합공정의 산 농도변화에 따른 중금속 제거효율에 관한 연구)

  • Jung, Jin-Hee;Choi, Ho-Eun;Jung, Byung-Gil;Sung, Nak-Chang;Yi, Gi-Chul;Choi, Young-Ik
    • Journal of Environmental Science International
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    • v.26 no.1
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    • pp.23-28
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    • 2017
  • This study was aimed at determining the changes in heavy metal removal efficiency at different acid concentrations in a micro-nanobubble soil washing system and pickling process that is used to dispose of heavy metals. For this purpose, the initial and final heavy metal concentrations were measured to calculate the heavy metal removal efficiency 5, 10, 20, 30, 60, and 120 min into the experiment. Soil contaminated by heavy metals and extracted from 0~15 cm below the surface of a vehicle junkyard in the city of U was used in the experiment. The extracted soil was air-dried for 24 h, after which a No. 10 (2 mm) was used as a filter to remove large particles and other substances from the soil as well as to even out the samples. As for the operating conditions, the air inflow rate in the micro-nano bubble soil washing system was fixed at 2 L/min,; with the concentration of hydrogen peroxide being adjusted to 5%, 10%, or 15%. The treatment lasted 120 min. The results showed that when the concentration of hydrogen peroxide was 5%, the efficiency of Zn removal was 27.4%, whereas those of Ni and Pb were 28.7% and 22.8%, respectively. When the concentration of hydrogen peroxide was 10%, the efficiency of Zn removal was 38.7%, whereas those of Ni and Pb were 42.6% and 28.6%, respectively. When the concentration of hydrogen peroxide was 15%, the efficiency of Zn removal was 49.7%, whereas those of Ni and Pb were 57.1% and 42.6%, respectively. Therefore, the efficiency of removal of all three heavy metals was the highest when the hydrogen peroxide concentration was 15%.

Feasibility of Present Soil Remediation Technologies in KOREA for the Control of Contaminated Marine Sediment: Heavy Metals (우리나라 현존 토양정화 기술의 해양오염퇴적물 정화사업 적용 가능성 검토: 중금속)

  • Kim, Kyoung-Rean;Choi, Ki-Young;Kim, Suk-Hyun;Hong, Gi-Hoon
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.12
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    • pp.1076-1086
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    • 2010
  • Soil remediation technologies were experimented to evaluate whether the technologies could be used to apply remediation of contaminated marine sediment. In this research, marine sediments were sampled at "Ulsan" and "Jinhae" where remediation projects are considered, and then the possibility of heavy metal removal was evaluated throughout the technologies. Heavy metal concentration of silt and clay fraction was higher than that of sand fraction at "Ulsan". Heavy metal removal of the silt and clay fraction was arsenic (As) 81.5%, mercury (Hg) 93.8% by particle separation, cadmium (Cd) 72.2%, mercury (Hg) 93.8% by soil washing technology, cadmium (Cd) 70.8%, lead (Pb) 65.6% by another soil washing technology. Based on experimental results, tested particle separation and soil washing technologies could be used to remove heavy metals of sand fraction and silt and clay fraction. Heavy metal removal by soil washing technology which was composed of separation, washing and physical or chemical reaction by additives such as acid, organic solvents was more effective comparing to that of particle separation. Since heavy metal concentration of all treated samples was suitable for national soil standards, all the tested technologies were could be used not only to remove heavy metals of marine contaminated sediment but also to reuse treated samples in land.

Cleaning Effects of Environmental-Friendly Washing Detergent on Milking Installation in Dairy Farms (젖소농가의 착유시설에 따른 친환경세제의 세척에 미치는 영향)

  • Kim, Chang-Hyun;Park, Joong-Kook
    • Journal of Food Hygiene and Safety
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    • v.25 no.4
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    • pp.346-353
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    • 2010
  • This study was conducted to determine cleaning effects of environmental-friendly washing detergent on milking installation in dairy farms. Milking machine, cooling machine and milking liner were washed by alkaline detergent and acid detergent for first three weeks and alkaline detergent and environmental~friendly detergent for next three weeks and the results get through microorganism and physico-chemistry analysis at the five district dairy farms different from environment. E-coli, coliform, fecal coliform, staphylococcus aureus, fecal streptococcus, prsudomonas aeruginosa and yersinia were not found in all of the dairy farms, and total colony counts were no difference compared with chemical detergent. The water for washing exceeded the determining acceptable level of nitrate nitrogen in the Anseong, Onyang and Cheonan and the remaining substance of washed water was also high levels. The cause of the result was that the level of nitrate nitrogen of water is basically high. Therefore, this study indicated that washing effect is no differences between environmental-friendly detergent and chemical detergent by washing for milking machine and cooling machine. Above all, producing high quality milk is to manage the water quality as well as using detergent.

A Study on the Chrome Mordant with Dyed Silk Fabric (염색견직물의 크롬매염에 관한 연구)

  • 정인모;장병호
    • Journal of Sericultural and Entomological Science
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    • v.26 no.2
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    • pp.26-31
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    • 1984
  • In general, acid dyes been used for silk dyeing, but acid dyed silk shows weakness in color fastess, To improve this defect, the silk dyed with Acid Mordant Blue 13 was treated with chromes salts solution. Some mechanical properties and dyeing behaviors of the chrome mordant with dyed silk fabric were tested in this work. The tensile strength of silk fabric treated with chrome salts solution was decreased as the duration of treatment was increased. The mean rate constant (K) of photo-degradation was 1.019, and 1.047 after treated with Cr (III) and Cr (Ⅵ), respectively, whereas it was 1.304 in untreatment. The washing fastness of silk fabric also was improved by treatment with mordant and it was 3rd-4th grade and 4th grade when silk was treated with Cr (III) and Cr (Ⅵ), respectively, while untreatment gave 1st grade. The colour of dyed silk fabric was 2.5RP.3/10, but it was 5PB.4/3 and 5PB. 4/4 when the silk fabric was treated with Cr (III) for two hours and with Cr (Ⅵ) for one hour at 90$^{\circ}C$, respectively.

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The Application of Heterobifunctional Reactive Dyes on Polyamide Fibers and Their Dyeing Properties (Heterobifunctional 반응성염료의 폴리아마이드 섬유에의 염착특성)

  • 손영아;홍진표;김태경
    • Textile Coloration and Finishing
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    • v.15 no.5
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    • pp.301-309
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    • 2003
  • Of the various types of dye that can be used to apply polyamide fibers, acid dyes and pre-metallised acid dyes are great in use so far. However, since these acid dyeings suffer from dye loss during laundering, recourse to an aftertreatment is usually necessary to achieve adequate fastness to washing. In the case of reactive dyes, the characteristically high washfastness of dyeings comes with the concomitant advantages of brightness and low environmental impact. Despite the obvious advantages, the commercialization of reactive dyes for polyamide fibers has not gained widespread success. In this context, the rewards for approach are likely to be considerable. Heterobifunctional reactive dyes were applied to polyamide fibers using various conditions. Optimum conditions and fixation were determined. The forms in which the vinylsulphone and hydrolyzed moieties were examined using HPLC-Mass. In addition, it was found that the extent of the washfastness secured, in terms of both change in color and staining of adjacent multifiber was being acceptable.

The study of the soil removal in cationic cotton fabrics. (양성면직물의 세정성에 관한 연구)

  • Shin Yong Son
    • Journal of the Korean Society of Clothing and Textiles
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    • v.3 no.1
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    • pp.13-18
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    • 1979
  • Many researches have found that the anionic surfactants are effective when the anionic soil is attached to the cotton fabrics. However, this research investigated the relationship of the super soil removal and surfactants when the anionic and cationic soil was attached to the cationic cotton fabrics. The result is that the cationic surfactants are vary effective for soil removal in the cationic cotton fabrics. The processing and nature of cationic cotton fabrics are treated and investigated as follows: Cotton fabrics are heated in the presence of ethylenimine and acetic acid dissolved in benzene to contain a significant amount of fixed nitrogen. Some polymer was formed but removal by washing with benzene and water. The optinium molor ratio of acid-to-ethylenimine seemed to be in the range 1: 10. The treated cotton fabrics dyed with acid Orange II dyes, and nitrogen content in the treated cotton fabrics were determined by the Kjeldahl method.

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Development of Commercially Viable Method of Conjugated Linoleic Acid Synthesis Using Linoleic Acid Fraction Obtained from Pork By-products

  • Yoon, Sung Yeoul;Lee, Da Young;Kim, On You;Lee, Seung Yun;Hur, Sun Jin
    • Food Science of Animal Resources
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    • v.38 no.4
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    • pp.693-702
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    • 2018
  • The purpose of this study was to develop a commercially viable method for synthesis of conjugated linoleic acid (CLA) using the linoleic acid fraction obtained from six pork by-products (liver, lung, heart, stomach, small intestine, and large intestine). The workflow of CLA synthesis from each by-product was as follows: washing${\rightarrow}$crude fat extraction${\rightarrow}$fractionation into saturated and unsaturated fatty acids${\rightarrow}$repeat unsaturated fatty acid fractionation${\rightarrow}$CLA synthesis. Cis-9, trans-11, and trans-10, cis-12 CLA was synthesized from pork by-products. The yield of CLA synthesis of pork by-products ranged from 1.55 to 11.18 g per 100 g of by-products. The amount of synthesized CLA was the highest in the small intestine and large intestine by-products. Fractionation of pork by-products nearly doubled the yield of CLA. We suggest that commercial fractionation methods could increase the yield of CLA at low cost, reduce waste, and improve the efficiency of by-product utilization.

Dyeing Properties of Nylon 66 Nano Fiber with High Molecular Mass Acid Dyes

  • Lee Kwon Sun;Lee Beom Soo;Park Young Hwan;Park Yoon Chul;Kim Yong Min;Jeong Sung Hoon;Kim Sung Dong
    • Fibers and Polymers
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    • v.6 no.1
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    • pp.35-41
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    • 2005
  • Research and development of nano fiber products is very active over the world. Physical characteristics and dyeing properties of nylon 66 nano fiber were investigated in this study. X-ray diffraction, DSC, analysis of amino end group, and water absorption were performed to get information concerning physical properties of nano fiber. Nylon 66 nano fiber was dyed with high molecular mass acid dyes. Effects of dyeing temperature, pH of dyeing solution, and concentration of acid dyes on dyeing properties such as rate of dyeing and the extent of exhaustion, were examined and compared to those of regu­lar fiber. It was found that nano fiber adsorbed acid dyes at lower temperature, got rapidly dyed, and its extents of exhaustion at specific dyeing temperature were higher than regular fiber. It was also observed that nano fiber could adsorb a large amount of acid dye without a significant loss in the extent of exhaustion. Washing fastness of the dyed nano fiber was lower by $1/2\~1$ grade, light fastness by 1 grade than the dyed regular fiber.

Antimicrobial Effects of Oleanolic Acid, Ursolic Acid, and Sophoraflavanone G against Enterococcus faecalis and Propionibacterium acnes

  • Jo, Eojin;Choi, Mi-Hwa;Kim, Hwa-Sook;Park, Soon-Nang;Lim, Yun Kyong;Kang, Christina K.;Kook, Joong-Ki
    • International Journal of Oral Biology
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    • v.39 no.2
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    • pp.75-79
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    • 2014
  • The aim of this study was to investigate antimicrobial effect of oleanolic acid (OA), ursolic acid (UA), and sophoraflavanone G against Enterococcus faecalis and Propionibacterium acnes, which are the major causative bacteria of endodontic infections. The antimicrobial activity was evaluated by the minimal inhibitory concentration (MIC). The data showed that the OA, UA, and sophoraflavanone G had antimicrobial effect on all the strains use in the study with $16-64{\mu}g/ml$, $8-64{\mu}g/ml$, and $1-8{\mu}g/ml$ of MIC values, respectively. These results indicate that OA, UA, and sophoraflavanone G could be useful in the development of antiseptic solution for washing the root canal in endodontic treatments.

A Study on the Hood Performance Improvement of Pickling Tank using CFD (전산유체역학을 이용한 산세조 후드 성능 개선에 관한 연구)

  • Jung, Yu-Jin;Park, Ki-Woo;Shon, Byung-Hyun;Jung, Jong-Hyeon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.1
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    • pp.593-601
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    • 2014
  • In this study, we investigated the methods of improving the capturing ability of acid fume by assessing the performance of slot-type external hood installed on both sides of an open surface tank for acid washing process. A field survey and the results of computational fluid dynamics revealed that capturing performance of existing hoods is very poor. To solve such problem, 'push-pull hood' that pushes from one side of an open surface tank and pulls on the other side was suggested. The initial prediction was that if a push-pull hood is used, the acid fume of an acid-washing tank surface could be moved towards the hood through the push flow. However, this study has confirmed that if the push flow velocity becomes too high, it could spread to other areas due to flooding from the hood. Therefore, if the push air supply is maintained at around 25 $m^3/min$(push 10 m/s), proper control flow is formed on the surface of a tank and acid fume that stayed at the upper part of the tank is smoothly captured toward the hood, significantly enhancing the capturing performance.