• Title/Summary/Keyword: acid strength

Search Result 1,666, Processing Time 0.023 seconds

Physical and Chemical Properties of Red Mud-Added Cement Paste Treated with Sulfuric Acid and Nitric Acid (황산 및 질산 중화 처리 액상레드머드 첨가 시멘트 페이스트의 물리·화학적 특성)

  • Kim, Sang-Jin;Hong, Seok Woo;Park, Kyu Eun;Kang, Suk-Pyo
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2023.05a
    • /
    • pp.139-140
    • /
    • 2023
  • In this study, red mud with low recyclability was manufactured as liquid red mud, neutralized with sulfuric acid and nitric acid, and then added to cement paste to conduct research on physical and chemical properties. As a result, liquid red mud-added cement paste neutralized with sulfuric acid and nitric acid showed higher compressive strength after one day than cement paste with plain and non-neutralized liquid red mud. This indicates that nitric acid and sulfuric acid neutralization can increase initial strength.

  • PDF

Effect of Surface Modification Process Conditions on Properties of Aramid Paper (아라미드 종이의 특성에 대한 표면 개질 과정 조건의 영향)

  • Sha, Lizheng;Zhao, Huifang
    • Polymer(Korea)
    • /
    • v.37 no.2
    • /
    • pp.196-203
    • /
    • 2013
  • Surface modification of meta-aramid fibers was performed by phosphoric acid treatment. Surface morphology and element composition of untreated and treated fibers were analyzed by scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS). Effects of surface modification on the mechanical strength of aramid papers made from meta-aramid fibers and fibrid were investigated. Surface modification conditions were optimized by response surface analysis (RSA). Results show that phosphoric acid treatment increases the surface roughness and oxygen content of aramid fibers. They improve the interface bonding strength between aramid fibers and fibrid, which improves the tensile strength of aramid papers. The results of response surface analysis indicate that the tensile strength of aramid papers increases by 47.5% and reaches the maximum when meta-aramid fibers are treated with 21.1wt% phosphoric acid solution at $39.3^{\circ}C$ for 36.7 min.

Mechanical Properties of Cement Paste according to the amount of Red mud Neutralized with Sulfuric Acid (황산 중화 레드머드 첨가량에 따른 시멘트 페이스트의 역학적 특성)

  • In, Byung-Eun;Kim, Sang-Jin;Kang, Suk-Pyo
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2022.04a
    • /
    • pp.21-22
    • /
    • 2022
  • In order to improve the strength degradation of the cement-based material to which strong alkaline liquid red mud was added, the liquid red mud was neutralized with sulfuric acid and added to the cement paste to examine the mechanical properties according to the amount added. As a result of measuring the compressive strength, the strength was higher when the red mud was neutralized with sulfuric acid and added to the cement paste than the cement paste to which the liquid red mud was added. As a result of hydration heat measurement, when red mud was neutralized with sulfuric acid and added to the cement paste, an initial strength higher than that of liquid red mud was expressed.

  • PDF

Mechanical Properties of Talc-Filled Polypropylene : Coupling Agent Effect (Talc로 충전된 폴리프로필렌의 기계적 물성 : 커플링제 효과)

  • 김주성;최미애;박태욱;김덕준
    • Polymer(Korea)
    • /
    • v.24 no.6
    • /
    • pp.770-776
    • /
    • 2000
  • The effect of unreactive coupling agent on mechanical and thermal properties of talc-filled polypropylene (PP) composites was studied. Stearic and oleic acids were introduced as coupling agents, and tensile, flexural, and impact strength, thermal stability and melting transition temperature were measured and analyzed according to the types and concentration of coupling agents. Tensile and flexural strength were enhanced by introduction of coupling agent and the maximum effect was observed at the concentration of 3 wt% of coupling agent. Tensile and flexural strength of PP treated with oleic acid were higher than those of PP treated with stearic acid. but impact strength vice-versa. The reasons for these results were postulated by analyzing morphologies of talc-filled PP observed by SEM.

  • PDF

A STUDY ON THE SHEAR BOND STRENGTH OF THE COMPOSITE RESIN TO AMALGAM ACCORDING TO AMALGAM SURFACE TREATMENT METHODS (아말감의 표면처리에 따른 복합레진과의 전단결합 강도에 관한 연구)

  • Park, Mun-Hee;Cho, Young-Gon;Hwang, Ho-Keel
    • Restorative Dentistry and Endodontics
    • /
    • v.18 no.1
    • /
    • pp.114-121
    • /
    • 1993
  • The purpose of this study was to evaluate the effect on treatment methods to shear bond strength between composite resin and amalgam when the alloy surface was finished with a diamond wheel or an sandblaster. Forty round acrylic cylinders were fabricated with a diameter of 33mm and a height of 20mm to fit into the device used during shear bond strength testing. A round undercut cavity (diameter, 8mm: depth, 2.5mm) was prepared in the center of the acrylic surface and the cavity was restored using a amalgam. A total of 40 acrylic cylinders with amalgam were divided into 4 groups according to treatment method. The group treatment were as follows : Group 1 : acid etching after finishing the amalgam with diamond wheel Group 2 : no acid etching after finishing the amalgam with diamond wheel Group 3 : acid etching after sandblasting the amalgam Group 4 : no acid etching after sandblasting the amalgam The shear bond strength of composite resin bonded to amalgam of each specimen was tested with a universal testing machine at a crosshead speed of 0.5mm/min and 500kg in full scale. The results were as follow: 1. After diamond finishing, the non-acid etching group had highest shear bond strength with 7.29kg/$cm^2$ and after sandblasting, the acidetching group had lowest shear bond strength with 4.49kg/$cm^2$. 2. In both diamond finishing and sandblasting group, acid etching of the roughened amalgam surface decreased the shear bond strength. 3. The group treated with a diamond wheel had higher shear bond strength those treated with an sandblaster but there was not significanat.

  • PDF

Properties of Slag Cement Mortar with Liquid Red Mud Neutralized with Sulfuric Acid (황산으로 중화시킨 액상레드머드 첨가 슬래그시멘트 모르타르의 특성)

  • Kim, Sang-Jin;Kang, Suk-Pyo
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2022.11a
    • /
    • pp.123-124
    • /
    • 2022
  • In this paper, the characteristics of slag cement mortar added with neutralized liquid red mud with sulfuric acid and reduced pH were reviewed to improve the strength degradation of cement concrete added with liquid red mud. As a result, in the case of compressive strength up to 7 days, the strength of the cement mortar added with liquid red mud tends to increase compared to Plain. This shows that adding liquid red mud to cement mortar tends to increase the initial age strength, and the compressive strength on the 28th shows 74% of Plain when adding non-neutralized liquid red mud and 89% when adding sulfate neutralized red mud. Therefore, it is judged that the compression strength is improved by neutralizing the liquid red mud with sulfuric acid.

  • PDF

A Comparison of shear Bonding Strength with Polyacrylic acid and Phosphoric acid Enamel Surface Conditioning (폴리아크릴산과 인산으로 법랑질표면 처리후 전단결합강도의 비교)

  • Roh, Joung-Sub;Kim, Sang-Cheol
    • The korean journal of orthodontics
    • /
    • v.32 no.1 s.90
    • /
    • pp.51-57
    • /
    • 2002
  • The purpose of this study was to compare in vitro shear bonding strength with three different enamel surface preparations (1) 30% sulfated polyacrylic acid with 0.3M lithium sulfate (2) 40% sulfated polyacrylic acid with 0.3M lithium sulfate (3) 37% phosphoric acid. 105 extracted human premolar teeth were divided into each three groups of 35. Metal brackets were bonded to teeth in the three groups. The same self curing resin was used for all groups. A shearing force was applied to the teeth. After debonding, bases of bracket and enamel surfaces were examined under steroscopic microscope to determine the failure modes. Statistical analysis of the data was carried out with one way ANOVA and Student t- test. The results were as follows. 1. Shear bond strength values for the 30% polyacrylic acid and 40% polyacrylic acid group were approximately two thirds of the phosphoric acid group. It maintains clinically acceptable but not enough bond strength. 2. There was no statistically significant difference in shear bond strengths between 30% and 40% polyacrylic acid group. 3. The failure modes of brackets had some differences. In polyacrylic acid groups, the percentage of adhesive/enamel failure was higher than that of adhesive/ bracket interface failure. On the contrary in phosphoric acid groups, the results were reversed. Further study of bond strength could be required. If polyacrylic acid enamel conditioning is used clinically.

Effect of Ground Granulated Blast Furnace Slag, Pulverized Fuel Ash, Silica Fume on Sulfuric Acid Corrosion Resistance of Cement Matrix

  • Jeon, Joong-Kyu;Moon, Han-Young;Ann, Ki-Yong;Kim, Hong-Sam;Kim, Yang-Bea
    • International Journal of Concrete Structures and Materials
    • /
    • v.18 no.2E
    • /
    • pp.97-102
    • /
    • 2006
  • In this study, the effect of supplementary materials(GGBS, PFA, SF) on sulfuric acid corrosion resistance was assessed by measuring the compressive strength, corroded depth and weight change at 7, 28, 56, 91, 180 and 250 days of immersion in sulfuric acid solution with the pH of 0.5, 1.0, 2.0 and 3.0. Then, it was found that an increase in the duration of immersion and a decrease in the pH, as expected, resulted in a more severe corrosion irrespective of binders: increased corroded depth and weight change, and lowered the compressive strength. 60% GGBS mortar specimen was the most resistant to acid corrosion in terms of the corroded depth, weight change and compressive strength, due to the latent hydraulic characteristics and lower portion of calcium hydroxide. The order of resistance to acid was 60% GGBS>20% PFA>10% SF>OPC. In a microscopic examination, it was found that acid corrosion of cement matrix produced gypsum, as a result of decomposition of hydration products, which may loose the structure of cement matrix, thereby leading to a remarkable decrease of concrete properties.

Physicochemical and Antioxidant Properties of Commercial Vinegars with High Acidity (시판 고산도 식초의 이화학적 품질 및 항산화 특성)

  • Jo, Deokjo;Park, Eun-Joo;Yeo, Soo-Hwan;Jeong, Yong-Jin;Kwon, Joong-Ho
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.42 no.8
    • /
    • pp.1204-1210
    • /
    • 2013
  • Various commercial vinegars of high-strength acidity (10% or more of total acidity) were investigated to compare their physicochemical and antioxidant properties. The total acidity of double-strength vinegars was relatively lower than triple-strength vinegars. Irrespective of the acidity, sugar and reducing sugar content ranged from $7.00{\sim}10.80^{\circ}Bx$ and 1.32~3,885.90 mg%, respectively. Free sugars were mainly composed of fructose and glucose, and were relatively high in double-strength vinegars. The content of acetic acid (a principal organic acid in vinegars) increased with acidity, but oxalic acid was not identified in commercial high-strength acidity vinegars. Double-strength vinegars using malt extracts were the highest in free amino acid content, showing 24 kinds of amino acids. The content of total phenolics and flavonoids was highest in apple vinegars of double-strength acidity, which affected the scavenging ability of DPPH and ABTS radicals. Overall, the quality of high-strength acidity vinegars was affected by its content and production methods, and double-strength acidity vinegar using apples showed the best antioxidant activities.

Effect of Hydrofluoric Acid Etching on Shear Bond Strength between Resin Cement and Zirconia cores (표면 불산처리가 레진시멘트와 지르코니아 하부구조물의 전단결합강도에 미치는 영향)

  • Kim, Sa-Hak;Kim, Sun-Moon;Kim, Chong-Kyen
    • The Journal of the Korea Contents Association
    • /
    • v.18 no.10
    • /
    • pp.361-367
    • /
    • 2018
  • The purpose of this study was to evaluate the influence of hydrofluoric acid etching treatment on the bonding strength of yttria-stabilized tetragonal zirconia polycrystal(Y-TZP). Four groups of zirconia-resin cement specimens were prepared; 1) ZGS group (zirconia, no treatment), 2) ZGSH group (zirconia, hydrofluoric acid etching treatment) 3) H-ZGS group (Hybrid zirconia, no treatment) 4) H-ZGSH group (Hybrid zirconia, hydrofluoric acid etching treatment). The shear bond strength between zirconia and porcelain was measured using a Instron Universal Testing Machine(Model DBBP-500, Instron Corporation, Kyonggi, Korea). Data were statistically analyzed using independent t-test and two-way ANOVA(${\alpha}=0.05$). The ceramic-resin cement bonding strength was affected by hydrofluoric acid etching treatment(p<0.05). Digital microscope examination of the fracture surface showed mixed failures with adhesive and cohesive types in hydrofluoric acid etching treatment with treated zirconia and hybrid zirconia groups.