• 제목/요약/키워드: acid strength

검색결과 1,666건 처리시간 0.03초

휴믹산 함유량에 따른 유동화 처리토의 공학적 특성 (Engineering Properties of Liquefied Stabilized Soil by Contents of Humic Acid)

  • 한상재;안동욱;박재만;김수삼
    • 대한토목학회논문집
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    • 제29권5C호
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    • pp.229-237
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    • 2009
  • 전통적인 되메우기 방법은 모래 또는 현장발생토를 다짐하는 공법이 주로 사용되어 왔으나 이는 시간과 비용이 많이 든다. 특히 관의 하부 및 작은 틈새와 같은 부분은 전통적인 다짐 공법으로는 다지기가 난해하기 때문에, 이러한 문제점을 보완하기 위해 현장토를 재활용함으로써 모래 수급 문제를 해결하고 배합설계를 통해 유동성 및 강도를 임의로 조절할 수 있는 유동화 처리토 공법이 제안되었다. 본 연구에서는 현장토의 유기물 함유량에 따른 유동화 처리토의 배합 특성을 파악하고자, 휴믹산 함유량에 따른 재료분리특성, 유동성, 강도특성, 투수특성을 실내실험을 통해 측정하여, 비교 분석하였다. 그 결과, 휴믹산 함유량이 증가할수록 재료분리 특성과 유동성은 크게 나타났고, 강도는 유기물 함유량과 반비례하는 것으로 나타났다. 또한 유기물 함유량은 유동화 처리토의 투수특성에는 영향을 미치지 않는다는 것을 알 수 있었다.

Bonding effects of cleaning protocols and time-point of acid etching on dentin impregnated with endodontic sealer

  • Tatiane Miranda Manzoli;Joissi Ferrari Zaniboni;Joao Felipe Besegato;Flavia Angelica Guiotti;Andrea Abi Rached Dantas;Milton Carlos Kuga
    • Restorative Dentistry and Endodontics
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    • 제47권2호
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    • pp.21.1-21.11
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    • 2022
  • Objectives: This study aimed to investigate the bonding effects of cleaning protocols on dentin impregnated with endodontic sealer residues using ethanol (E) or xylol (X). The effects of dentin acid etching immediately (I) or 7 days (P) after cleaning were also evaluated. For bonding to dentin, universal adhesive (Scotchbond Universal; 3M ESPE) was used. The persistence of sealer residues, hybrid layer formation and microshear bond strength were the performed analysis. Materials and Methods: One hundred and twenty bovine dentin specimens were allocated into 4 groups (n = 10): G1 (E+I); G2 (X+I); G3 (E+P); and G4 (X+P). The persistence of sealer residues was evaluated by SEM. Confocal laser scanning microscopy images were taken to measure the formed hybrid layer using the Image J program. For microshear bond strength, 4 resin composite cylinders were placed over the dentin after the cleaning protocols. ANOVA followed by Tukey test and Kruskal-Wallis followed by Dunn test were used for parametric and non-parametric data, respectively (α = 5%). Results: G2 and G4 groups showed a lower persistence of residues (p < 0.05) and thicker hybrid layer than the other groups (p < 0.05). No bond strength differences among all groups were observed (p > 0.05). Conclusions: Dentin cleaning using xylol, regardless of the time-point of acid etching, provided lower persistence of residues over the surface and thicker hybrid layer. However, the bond strength of the universal adhesive system in etch-and-rinse strategy was not influenced by the cleaning protocols or time-point of acid etching.

Evaluation of tensile strength of surgical synthetic absorbable suture materials: an in vitro study

  • Khiste, Sujeet Vinayak;Ranganath, V.;Nichani, Ashish Sham
    • Journal of Periodontal and Implant Science
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    • 제43권3호
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    • pp.130-135
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    • 2013
  • Purpose: The purpose of this study was to evaluate the tensile strength of surgical synthetic absorbable sutures over a period of 14 days under simulated oral conditions. Methods: Three suture materials (polyglycolic acid [PGA], polyglactin [PG] 910, and poly (glycolide-co-${\epsilon}$-caprolactone) [PGC]) were used in 4-0 and 5-0 gauges. 210 suture samples (35 of each material and gauge) were used. All of the samples were tested preimmersion and 1 hour and 1, 3, 7, 10, and 14 days postimmersion. The tensile strength of each suture material and gauge was assessed. The point of breakage and the resorption pattern of the sutures were also assessed. Results: During the first 24 hours of immersion, all 4-0 and 5-0 samples of PGA, PG 910, and PGC maintained their initial tensile strength. At baseline (preimmersion), there was a statistically significant (P<0.001) difference in the tensile strengths between the 4-0 and 5-0 gauge of PGA, PG 910, and PGC. PGA 4-0 showed the highest tensile strength until day 10. At 7 days, all the 4-0 sutures of the three materials had maintained their tensile strength with PGA 4-0 having significantly greater (P=0.003) tensile strength compared to PG. Conclusions: 4-0 sutures are stronger and have greater tensile strength than 5-0 sutures. The PGA 4-0 suture showed the highest tensile strength at the end of day 10.

황토 콘크리트의 배합조건에 따른 강도성상 및 내구성 (Characteristics of Strength and Durability of Hwangto-Concrete according to its Mixing Condition)

  • 황혜주;노태학;김진일
    • KIEAE Journal
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    • 제8권5호
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    • pp.55-60
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    • 2008
  • The purpose of this study is to increase the use of Hwangto and examine the strength according to what it is compounded with. Hwangto-concrete containing Hwanto without cement nor organic chemical products were compared to the traditional cement concrete through some durability experiments. We expect to gain more knowledge on the potentials of Hwangto-concrete as an architectural source. 1) As Hwangto binder amount rises, the value of slump increases too. The reason is that the increase of the quantity of cement causes the increase of the amount of material and the decrease of the amount of aggregate. 2) When the mixed component into Hwangto-concrete remains at 2%, the compress strength is generally dispersed high along the per unit fission, in case the amount of which is at $400(g/m^3)$. The highest compress strength is 39MPa. It means that it can be applied to common structures and we need to conduct a basic property test to ensure the strength and fluidness. 3) Hwangto-concrete is expected to be highly used in the ocean structure and chemical industry because it has better resistance to sulfuric acid and to hydrochloric acid than the cement-concrete has. The result of this study is as follows. It is expected that Hwangto-concrete will be widely applied and further research on its durability and tests for its basic substantial characteristics based on future component added to it.

아세트산처리 황다랑어(Thunnus albacares) 껍질 유래 젤라틴으로 제조한 바이오필름의 생체 접착 특성 (Bioadhesive Characteristics of Biofilm Manufactured from Gelatin Derived from Acetic Acid-treated Skin of the Yellowfin Tuna Thunnus albacares)

  • 김주연;김도형;문창권;김선봉
    • 한국수산과학회지
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    • 제44권6호
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    • pp.584-590
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    • 2011
  • This study aimed to demonstrate the bioadhesive characteristics of gelatin biofilm to rat skin. The biofilm was manufactured from gelatin extracted from the acetic acid treated-skin of the yellowfin tuna Thunnus albacares. The bioadhesive strength of tuna gelatin biofilm was compared to that of porcine gelatin biofilm. The tuna gelatin biofilm exhibited a higher bioadhesive strength than the porcine gelatin biofilm. Gelatin biofilm was subjected to glutaraldehyde treatment at different concentrations, temperatures and pH in order to improve its bioadhesive strength. Glutaraldehyde treatment improved the bioadhesive strength of gelatin biofilm up to three-fold. The bioadhesive strength of glutaraldehyde treated-biofilm was significantly decreased by application of sodium borohydride.

굴 패각 분말을 충전재로 활용한 폴리머 콘크리트의 강도 및 내구 특성 (Strength and Durability Properties of Polymer Concrete Utilizing Oyster Shell Powder as a Filler)

  • 성찬용;김영익
    • 한국농공학회논문집
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    • 제52권6호
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    • pp.125-134
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    • 2010
  • This study was performed to evaluate the workability, strengths and durability of polymer concrete using oyster shell that are reclaimed at public shore illegally or leaved on the surroundings of shore to prevent the environmental pollution. We investigated the effect of oyster shell powder (OSP) and $CaCO_3$. on the slump, compressive strength, flexural strength, acid sulfuric and freezing and thawing resistance as a filler of polymer concrete. Modified OSP obtained by crushing oyster shell (less than 0.15 mm size) consists of 60.47 wt% of $SiO_2$ and 39.5 wt% of $CaCO_3$. As a result of slump test by OSP and $CaCO_3$. contents, it is found that slump of specimen used OSP is lower than that used $CaCO_3$. and the more OSP contents are, its slump is increased. Compressive and flexural strength of polymer concrete using OSP are similar or slightly lower than that using $CaCO_3$. In acid sulfuric test for 5 % $H_2SO_4$ and freezing thawing test, regardless of kinds of fillers and contents are not found fatal defects in weight change, falling-off in surface and durability factor.

용융방사에 의한 생분해성 고강도 PLA 섬유 제조 공정 상 주요 공정 변수에 관한 연구 (Preparation and Physical Properties of Biodegradable High Performance PLA Fiber using Process Parameters)

  • 정우창;김삼수;이상오;이재웅
    • 한국염색가공학회지
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    • 제34권3호
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    • pp.197-206
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    • 2022
  • The purpose of this study was to confirm the optimal spinning conditions for PLA (Polylactic acid) as a fiber forming polymer. According to the melt spinning test results of PLA, the optimal spinning temperature was 258℃. However, it needs to note that relatively high pack pressure was required for spinning at 258℃. At an elevated temperature, 262℃, mono filament was broken easily due to hydrolysis of PLA at a higher temperature. In case of fiber strength, it was confirmed that the draw ratios of 2.7 to 3.3 were optimal for maximum strength of melt spun PLA. Above the draw ratio, 3.3, the strength of the PLA fibers was lowered. It was presumed that cleavage of the PLA polymer chain over maximum elongation. The heat setting temperature of GR (Godet roller) showed that the maximum strength of the PLA fibers was revealed around 100℃. The degree of crystallinity and the strength of the PLA fibers were decreased above 100℃. The optimal take-up speed (Spinning speed) was around 4,000m/min. Thermal analysis of PLA showed 170℃ and 57℃ as Tm (melting temperature) and Tg (glass transition temperature), respectively.

Effect of crushed waste glass as partial replacement of natural fine aggregate on performance of high strength cement concrete

  • Ajmal, Paktiawal;Mehtab, Alam
    • Advances in materials Research
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    • 제11권4호
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    • pp.251-277
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    • 2022
  • Disposal of industrial waste in cities where municipal authorities permitting higher floor area ratio coupled with increasing living standards, a lot of demolition waste is being generated. Its disposal is a challenge particularly in megacities where no landfills are available. The ever-increasing cost of building construction materials also necessitates consuming demolition wastes in a useful manner to save fresh natural raw materials. In the present work, the crushed waste glass is used in high-strength concrete as a partial replacement of fine aggregate. The control concrete of grade M60 was proportioned following BIS 10262-2009. The crushed waste glass has been used as a partial replacement with varying percentages of 10, 20, 30, and 40% by weight of fine aggregate. Experimental tests were carried on the fresh and hardened state of the concrete. The effect of crushed waste glass on the workability of the concrete has been investigated. Non-destructive tests, acid attack tests, compressive strength, split tensile strength, and X-ray diffraction analysis was carried out for the control concrete and concrete containing crushed waste glass after 7, 28, and 270 days of normal curing. The results show that for the same w/c ratio, the workability of concrete increases with increasing replaced crushed waste glass content. However, the decrease in compressive strength of the concrete after 28 days of normal curing and further after 28 days of acid attacks, up to 30% replacement level of fine aggregate by the crushed waste glass is insignificant.

세바식 산으로 중합된 폴리에스터 폴리올을 원료로 사용한 폴리우레탄 접착제에 관한 연구 (A Study on Polyurethane Adhesive Based Polyester Polyol Polymerized from Sebacic Acid)

  • 진경호;김민수;조을룡
    • Elastomers and Composites
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    • 제48권3호
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    • pp.190-194
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    • 2013
  • 본 연구에서는 피마자유 유래의 sebacic acid를 isophthalic acid 및 glycol과 병용하여 폴리에스터 폴리올을 중합하고 이어서 폴리우레탄 접착제를 제조하였다. 접착력을 측정한 결과에서 sebacic acid를 병용한 폴리올이 adipic acid를 사용한 폴리올 보다 응집에너지가 커서 접착력이 우수하게 나타났고, glycol은 선형구조 보다 메틸기를 포함하는 가지구조가 더 좋은 접착력을 보였다. 쇄연장제는 1,4-butane diol(BD)를 사용한 것이 가장 접착력이 좋게 나타났다. 또한 TGA 측정결과 내열성은 BD가 가장 높고, 1,2-propylene glycol(PG)가 다음, ethylene glycol(EG)가 가장 낮았다. DMA 측정에서 유리전이온도는 PG, EG, BD의 순서로 높게 나타났다.

고강도 콘크리트의 하절기 적용을 위한 실물모형시험 (The Mock-up Test for the Hot Weathered High Strength Concrete)

  • 손명수;김태준
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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    • pp.442-445
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    • 2004
  • The mock-up test was carried out to solve several problems of the hot weathered high strength concrete. The workability of concrete could be guaranteed by using high range water reducer containing polycarboxylic acid. The compressive strength calculation by rebound value of Schumidt hammer underestimated the actual strength of concrete structure. The temperature of concrete should be lowered by control of raw material temperature and transportation.

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