• Title/Summary/Keyword: acid strength

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Sulfuric acid and Hydrochloric acid resistance properties of Light Weight Matrix Based on Blast furnace slag (고로슬래그 기반 경량 경화체의 황산 및 염산 저항 특성)

  • Kim, Weon-Jeong;Lee, Seung-Ho;Park, Sun-Gyu;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.11a
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    • pp.137-138
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    • 2015
  • The use of the cement and increased with the recent development of the construction industry. If the cement is the environmental problems caused by generating a large quantity of CO2 and the production process. Accordingly, this study is the test to determine the sulfuric acid and hydrochloric acid resistance properties of the Light weight matrix product of blast furnace slag-based light. A result, the compression strength of the sulfuric acid and hydrochloric acid immersion showed alower strength than the Plain.

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Shear bond strength of veneering ceramic to coping materials with different pre-surface treatments

  • Tarib, Natasya Ahmad;Anuar, Norsamihah;Ahmad, Marlynda
    • The Journal of Advanced Prosthodontics
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    • v.8 no.5
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    • pp.339-344
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    • 2016
  • PURPOSE. Pre-surface treatments of coping materials have been recommended to enhance the bonding to the veneering ceramic. Little is known on the effect on shear bond strength, particularly with new coping material. The aim of this study was to investigate the shear bond strength of veneering ceramic to three coping materials: i) metal alloy (MA), ii) zirconia oxide (ZO), and iii) lithium disilicate (LD) after various pre-surface treatments. MATERIALS AND METHODS. Thirty-two (n = 32) discs were prepared for each coping material. Four pre-surface treatments were prepared for each sub-group (n = 8); a) no treatment or control (C), b) sandblast (SB), c) acid etch (AE), and d) sandblast and acid etch (SBAE). Veneering ceramics were applied to all discs. Shear bond strength was measured with a universal testing machine. Data were analyzed with two-way ANOVA and Tukey's multiple comparisons tests. RESULTS. Mean shear bond strengths were obtained for MA ($19.00{\pm}6.39MPa$), ZO ($24.45{\pm}5.14MPa$) and LD ($13.62{\pm}5.12MPa$). There were statistically significant differences in types of coping material and various pre-surface treatments (P<.05). There was a significant correlation between coping materials and pre-surface treatment to the shear bond strength (P<.05). CONCLUSION. Shear bond strength of veneering ceramic to zirconia oxide was higher than metal alloy and lithium disilicate. The highest shear bond strengths were obtained in sandblast and acid etch treatment for zirconia oxide and lithium disilicate groups, and in acid etch treatment for metal alloy group.

Effect of ascorbic acid, ethanol and acetone on adhesion between the treated fiber posts and composite resin cores

  • Zahra, Khamverdi;Reza, Talebian
    • The Journal of Advanced Prosthodontics
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    • v.4 no.4
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    • pp.187-191
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    • 2012
  • PURPOSE. The aim of the present study was to assess the effect of ascorbic acid, ethanol and acetone on microtensile bond strength between fiber posts pre-treated with hydrogen peroxide and composite resin cores. MATERIALS AND METHODS. Twenty four fiber posts were pre-treated with 24% hydrogen peroxide and divided into 4 groups as follows: G1: no treatment, as control group; G2: treatment with10% ascorbic acid solution for 5 minutes; G3: treatment with 70% ethanol solution for 5 minutes; and G4: treatment with 70% acetone solution for 5 minutes. Each fiber post was surrounded by a cylinder-shaped polyglass matrix which was subsequently filled with composite resin. Two sections from each sample were selected for microtensile test at a crosshead with speed of 0.5 mm/min. Statistical analyses were performed using one-way ANOVA and a post hoc Tukey HSD test. Fractured surfaces were observed under a stereomicroscope at ${\times}20$ magnification. The fractured surfaces of the specimens were observed and evaluated under a SEM. RESULTS. Means of microtensile bond strength values (MPa) and standard deviations in the groups were as follows: G1: $9.70{\pm}0.81$; G2: $12.62{\pm}1.80$; G3: $16.60{\pm}1.93$; and G4: $21.24{\pm}1.95$. G4 and G1 had the highest and the lowest bond strength values, respectively. A greater bond strength value was seen in G3 compared to G2. There were significant differences between all the groups (P<.001). All the failures were of the adhesive mode. CONCLUSION. Application of antioxidant agents may increase microtensile bond strength between fiber posts treated with hydrogen peroxide and composite cores. Acetone increased bond strength more than ascorbic acid and ethanol.

An Application Study on Quality Control of Re-Mi-Con for Using the Early Estimating Method of Concrete Strength with the Test of Solution Heat of Hychrochioric Acid (염산용해열법의 콘크리트 강도 조기추정에 의한 레미콘 품질관리의 적용성 연구 -Fc=180Kg/$\textrm{cm}^2$를 중심으로-)

  • 한천구;윤기원
    • Proceedings of the Korea Concrete Institute Conference
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    • 1990.10a
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    • pp.101-106
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    • 1990
  • To estimate the concrete strength at fresh state is very important problem in quality control. So, this study is designed for analyzing the quality control application of practical use Re-Mi-Con with the early estimation method of concrete strength using the test of solution heat of hydrochloric acid.

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Physical and Waterproof Properties of Mortar Using Cement Sludge Treated with Hydrofluosilicic Acid (규불화수소산 처리 시멘트 슬러지를 사용한 모르타르의 물성 및 방수 특성)

  • 김승문;이병기;김도수;노재성
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10c
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    • pp.76-81
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    • 1998
  • The physical properties of cement sludge treated with hydrofluosilicic acid were investigated. The compressive strength of cement mortar substituted cement sludge was decreased than that of OPC(ordinary portland cement) mortar. Cement sludge, for improving its physical properties, was treated with hydrofluosilicic acid. And compressive strength of cement mortar substituted TCS was greatly improved than that of OPC mortar. Particularly, cement mortar substituted TCS had the higher value in water-proofness than of OPC.

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A Simple Approach to the Ionic-Covalent Bond Based on the Electronegativity and Acid Strength of Cations. Part One:Calculation of the Electronegativity and Acid Strength

  • Josik Portier;Guy Campet
    • Journal of the Korean Chemical Society
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    • v.41 no.8
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    • pp.427-436
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    • 1997
  • A simple relation exists between electronegativities of cations and their oxidation states and ionic radii. An empirical law is proposed: X = 0.274 z-0.15 z r - 0.01 r+1+${\alpha}$, z being oxidation number, r ionic radius in $\AA$ and ${\alpha}$ a term related to the atomic number. this relation permits to calculate an electronegativity scale covering a large set of electronic and crystallographic situations. An application to the calculation of acid strengths of cations is presented.

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Orthodontic bonding to acid- or laser-etched prebleached enamel

  • Ozdemir, Fulya;Cakan, Umut;Gonul, Nese;Cakan, Derya Germec
    • The korean journal of orthodontics
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    • v.43 no.3
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    • pp.141-146
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    • 2013
  • Objective: Bonding forces of brackets to enamel surfaces may be affected by the procedures used for bleaching and enamel etching. The aim of this study was to investigate the bonding strength of orthodontic brackets to laser-etched surfaces of bleached teeth. Methods: In a nonbleached control group, acid etching (group A) or Er:YAG laser application (group B) was performed prior to bracket bonding (n = 13 in each group). Similar surface treatments were performed at 1 day (groups C and D; n = 13 in each subgroup) or at 3 weeks (groups E and F; n = 13 in each subgroup) after 38% hydrogen peroxide bleaching in another set of teeth. The specimens were debonded after thermocycling. Results: Laser etching of bleached teeth resulted in clinically unacceptable low bonding strength. In the case of acid-etched teeth, waiting for 3 weeks before attachment of brackets to the bleached surfaces resulted in similar, but not identical, bond strength values as those obtained with nonbleached surfaces. However, in the laser-etched groups, the bonding strength after 3 weeks was the same as that for the nonbleached group. Conclusions: When teeth bleached with 38% hydrogen peroxide are meant to be bonded immediately, acid etching is preferable.

EFFECT OF CUPRIC AND FERRIC IONS ON BONDING OF MMA/TBBO RESIN TO DENTIN (동 및 철이온이 MMA/TBBO레진의 상아질 접착에 미치는 영향)

  • Park, Jin-Hoon
    • Restorative Dentistry and Endodontics
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    • v.18 no.2
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    • pp.423-430
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    • 1993
  • The purpose of this study was to investigate the effect of ferric and ferric ions contained in phosphoric acid solution as a pretreatment solution on bonding of MMA/TBBO resin to dentin. Each of 1 % and 3 % ferric chloride. cupric chloride. cupric sulfate. and cupric nitrate was mixed into 10% phosphoric acid solution and pretreated dentin surface of bovine anterior teeth for 30 seconds followed- by water rinse and dry. Tensile bond strength was determined after bonding of pretreated dentin with MMA/TBBO resin by use of brush-on ;technique and storing for 24 hours in 3it distilled water. The amount of cupric ions adsorbed on pretreated dentin surface was detected by Wave-Dispersion X-ray microanalyzer for different groups of each pretreatment solution containing cupric salts. The pretreatment with cupric ions contained in 10% phosphoric acid solution was effective to increase bonding strength of MMA/TBBO resin to dentin but not in case of ferric ions. The pretreatment with 3 % cupric chloride and cupric nitrate both enhanced significant increase in bonding strength compared to the control group of 10% phosphoric acid solution(p<0.05). Cupric ions measured in pretreated dentin surface was higher in 3 % cupric chloride group than in 1% cupric chloride group, but couldn't find distinct relationship from the results of this experiment between the amount of adsorbed cupric ions according to the kind of cupric salts and the bonding strength value.

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Influence of Chemical Admixture on the Strength Development of Concrete at Early Age (콘크리트의 초기 강도발현에 미치는 혼화제의 영향)

  • 황인성;나운;이승훈;류현기;한천구
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.741-744
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    • 2003
  • In this study, the influence of chemical admixture on early strength development of concrete is discussed. According to the results, fluidity with variation of kinds of chemical admixture is lower in the case of acceleration type than in the case of normal type. Setting time of naphthalene acceleration type is shortened by I hour, and that of melamine is nearly same, but that of polycarbonic acid is somewhat retarded in comparison with that of naphthalene normal type. Early compressive strength gains 5MPa in about 18hours regardless of the kinds of chemical admixture. But as time elapses, compressive strength is higher in order of polycarbonic acid, naphthalene and melamine type. The relativity between compressive strength and the rebound value of P-type schmidt hammer is also favorable at early age, and compressive strength of 5MPa is estimated at the rebound value of 22.

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A STUDY ON THE SHEAR BOND STRENGTH OF LIGHT-CURED GLASS IONOMER CEMENT (광중합형 글래스아이오노머 시멘트의 전단결합강도에 대한 연구)

  • Kim, Hyun-Yang;Tae, Ki-Chul;Kook, Yoon-Ah;Kim, Sang-Cheol
    • The korean journal of orthodontics
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    • v.28 no.5 s.70
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    • pp.689-698
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    • 1998
  • The purpose of this study was to evaluate the shear bond strength of light cured glass ionomer cement to enamel surface which treated with $37\%$ phosphoric acid, $10\%$ polyacrylic acid, $1.23\%$ acidulated phosphate fluoride gel and no etching agent. To compare the shear bond strength of glass ionomer cement, light-cured composite resin and chemically-cured composite resin were empoloyed as controls. Eight experiments groups were composed. 10 specimens of each group were bonded by metal bracket by tested in universal testing machine for shear bond strength, in stereoscope for adhesive remnants index. The data were evaluated statistically by SPSS/PC+. The results were as follows. 1. Among the groups of $37\%$ phosphoric acid treated and dry and bonded with light cured glass ionomer, light cured composite resin, and chemically cured composite resin, the shear bond strength of glass ionomer group showed no significant difference to the others, but the shear bond strength of chemically cured resin showed statistically lower than that of light cured resin (p<0.05). 2. The shear bond strengths of glass ionomer cement to enamel treated group with $1.23\%$ acidulated phosphate fluoride gel and $10\%$ polyacrylic acid and $37\%$ phosphoric acid showed statistically higher than that of no etched enamel group(p<0.U). 3. In the groups of glass ionomer cement, the presence of moisture was not significantly effect to the shear bond strength (p<0.05). 4. After debonding, no etched enamel group showed less residual materials on the enamel surface than the group of enamel etched with $37\%$ Phosphoric acid.

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