• 제목/요약/키워드: acid gas

검색결과 2,060건 처리시간 0.035초

Application of nanoparticles in extending the life of oil and gas transmission pipeline

  • Yunye, Liu;Hai, Zhu;Jianfeng, Niu
    • Structural Engineering and Mechanics
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    • 제84권6호
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    • pp.733-741
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    • 2022
  • The amount of natural gas that is used on a worldwide scale is continuously going up. Natural gas and acidic components, such as hydrogen sulfide and carbon dioxide, cause significant corrosion damage to transmission lines and equipment in various quantities. One of the fundamental processes in natural gas processing is the separation of acid gases, among which the safety and environmental needs due to the high toxicity of hydrogen sulfide and also to prevent wear and corrosion of pipelines and gas transmission and distribution equipment, the necessity of sulfide separation Hydrogen is more essential than carbon dioxide and other compounds. Given this problem's significance, this endeavor aims to extend the lifespan of the transmission lines' pipes for gas and oil. Zinc oxide nanoparticles made from the environmentally friendly source of Allium scabriscapum have been employed to accomplish this crucial purpose. This is a simple, safe and cheap synthesis method compared to other methods, especially chemical methods. The formation of zinc oxide nanoparticles was shown by forming an absorption peak at a wavelength of about 355 nm using a spectrophotometric device and an X-ray diffraction pattern. The size and morphology of synthesized nanoparticles were determined by scanning and transmission electron microscope, and the range of size changes of nanoparticles was determined by dynamic light scattering device.

포화지방산계 LB막의 수평방향에 대한 전기적 특성 비교 (A Comparison to Electrical properties of Fatty Acid System LB Films in Horizontal Direction)

  • 김도균;최용성;장정수;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 춘계학술대회 논문집
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    • pp.194-197
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    • 1997
  • The LB technique is one of the most powerful fabricating methods of organic ultra-thin film, which deposits a monolayer films in molecular level on the surface of the substrate. We have investigated the electrical characteristics of Myristic acid, Stearic acid and Arachidic acid LB films for horizontal direction to develop for the gas sensor. The optimum conditions for a film deposition were obtained by measurement of $\pi$-A isotherm. The status of the deposited film was confirmed by measurement of UV absorbance. We could distingished the difference of I-V characteristics for the fatty acid for the horizontal direction. The conductivity of fatty acid LB films for horizontal direction was 10$^{-7}$ ~ 10$^{-9}$ [S/cm] that mean like semiconductor.

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계면활성제를 이용한 우지지방산을 포화지방산과 불포화 지방산의 분리

  • 이옥섭;김점식
    • 대한화장품학회지
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    • 제10권1호
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    • pp.24-41
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    • 1984
  • Tallow fatty acid consists of mixtures of fatty acids differing in chain length and saturation. In separation of tallow fatty acid, the effects of the type and concentration of detergents and electrolytes were studied. And the changes of acid composition of particular fractions were determined by gas-chromatography. Sodium lauryl sulfate (SLS), sodium lauryl ether sulfate (SLES) and sodium lauryl benzene sulfonate (SLBS) were used as detergents and NaCl, Na2SO4 and MgSO4 were used as electrolytes. At low concentration of detergent, the tallow fatty acid was not fully wetted, and at high concentration, the emulsion was so stable that the tallow fatty acid was not well separated. The addition of proper amount of electrolyte increased the separation efficiency by the decrease of interfacial tension and by the increase of the amount of adsorbed detergent on the surface of solid fatty acid crystals. The optimum range of detergent was 0.4-0.6% (wt.) in SLS, 0.2-0.4% in SLES and 2.0-) .0% in SLBS. And the optimum range of electrolyte was 2.0-2.5% in NaCl, 3.0-4.0% In Na2SO4 and 0.5-1.0% in MgSO4 respectively.

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토마토식물의 독성물질 확인과 생장억제작용 (Identification and Growth Inhibition of Phytotoxic Substances from Tomato Plant)

  • 김영식
    • Journal of Plant Biology
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    • 제32권1호
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    • pp.41-49
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    • 1989
  • Phenolic compounds such as gallic acid, ferulic acid, p-hydroxybenzoic acid, vanillic acid, salicylic acid, tannic acid, and hydroquinone were identified from the aqueous extracts and volatile substances of tomato plant by paper chromatography, high performance liquid chromatography and gas chromatography. The seed germination and seedling growth of the experimental species, lettuce and egg plant, were severely inhibited in 5$\times$10-3M of phenolic reagents identical to those identified from tomato plant. Germination and growth rate of test species in 5$\times$10-4M and 5$\times$10-5M were higher than that of 5$\times$10-3M. Therefore, 5$\times$10-3M of phenolic compounds would be assumed to be threshold concentration for allelopathic effects.

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Polyamic Acid Alkylamine Salts(PAAS) LB 박막의 전기적 특성에 관한 연구 (A study on Electrical Properties of the Polyamic Acid Alkylamine Salts(PAAS) LB films)

  • 이호식;이원재;김태완;강도열
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 추계학술대회 논문집
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    • pp.298-301
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    • 1997
  • This paper describes the thermally stimulated current(TSC) measurements arachidic acid(AA) and polyamic acid alkylamine salts(PAAS) LB film, which is a precursor of polyimide(PI). The measurements were performed from room temperature to about 250$^{\circ}C$ and the temperature was increased at a rate of 0.02 $^{\circ}C$/s linearly[4]. It shows that peaks of TSC are observed at about 80$^{\circ}C$ in the arachidic acid and about 80$^{\circ}C$, 160$^{\circ}C$ in the PAAS LB films. The DSC and TGA of PAAS, arachidic acid are measure. Monolayer phases on the water subphase such as Langmuir(L) films and the phase transitions from gas phase to solid phase via liquid phase are observed using Brewster angle microscopy(BAM). BAM is also used to observe the Langemuir-Blodgett(LB) films.

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용해조건 및 합금원소 첨가에 따른 고규소 내산주철의 기계적 성질 및 부식속도의 변화 (Variations of Mechanical Properties and Corrosion Rate with Melting Conditions and Alloying Elements in High Silicon Cast Irons)

  • 김정철;한동운;백진현;백승한;문병문;신제식;이영국
    • 한국주조공학회지
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    • 제24권4호
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    • pp.209-216
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    • 2004
  • High silicon cast irons(HSCI) with the high acid resistance have been used for the prevention of acid corrosion occurring in various structures under acid conditions. However, the HSCI is only known as one of materials which have high acid resistance, but few work has dealt with this material in domestic. Therefore, in this study, the acid resistance of various cast irons with alloying elements and melting conditions have been examined, and studied the influences of the matrix structures, mechanical properties and morphologies of graphite. The results obtained in this study are as follows : In case of melting temperature, the mechanical properties of specimen manufactured with high temperature of $1650^{\circ}C$ showed higher value because the inclusion and impurity were removed. In case of pouring temperature, the mechanical properties of specimen fabricated below $1350^{\circ}C$ of pouring temperature showed higher value because the amount of gas absorption from atmosphere decreased during the solidification time. The corrosion rate decreased with increase in Si content. On the other hand, Mn addition appeared an opposite trend with Si.

인산처리 유·무에 따른 레이온직물의 열수축과 열안정성에 미치는 안정화 공정 조건의 영향 (Effect of Stabilization Processing Conditions on the Thermal Shrinkage and the Thermal Stability of Rayon Fabrics Untreated and Surface-Treated with Phosphoric Acid)

  • 조동환;이종문;박종규
    • 접착 및 계면
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    • 제5권3호
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    • pp.10-17
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    • 2004
  • 본 연구에서는 레이온직물에 대하여 승온속도, 안정화온도, 분위기가스, 화학적 표면처리 등 여러가지 조건에서 안정화공정을 행한 후, 직물의 열수축과 열안정성, 그리고 미세구조에 미치는 공정 조건의 영향을 조사하였다. 레이온직물의 열수축과 중량변화에 인산처리 유무와 승온속도가 가장 중요한 영향을 미쳤다. 특히, 인산처리를 한 경우가 하지 않은 경우보다 레이온직물의 두께변화는 약 80%, 길이변화는 약 20%, 그리고 중량변화는 약 26%가 줄어드는 열수축 억제 효과를 보여주었다. 안정화 된 레이온직물의 열안정성에는 안정화온도와 인산처리 그리고 분위기가스와 승온속도 등 주어진 안정화공정 조건 모두가 영향을 주었다. 또한 안정화섬유의 표면 상태 및 섬유직경 변화도 공정 전에 행한 인산처리의 유무에 의존하였다.

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전자코와 GC/MS를 이용한 포도 품종별 저장 조건에 따른 휘발성 향기 성분 연구 (Identification of Volatile Compounds of 4 Grape Species by Storage Conditions)

  • 이윤정;이기택
    • 한국식품영양과학회지
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    • 제36권7호
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    • pp.874-880
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    • 2007
  • 품종에 따른 포도를 이용하여 3일 동안 $4^{\circ}C$와 실온에 각각 저장함에 따라 변화하는 전체적인 향의 패턴을 전자코를 통하여 분석하였고 SPME-GC/MS 분석 결과를 통하여 휘발성분을 분리 동정하였다. 대표적인 포도의 주요 휘발 성분은 alcohols, esters, acids, terpenes 등으로 GC/MS 분석 결과 butanoic acid/ethyl ester와 1-hexanol, hexanoic acid/ethyl ester, phenylethyl alcohol 등이 주요 성분으로 동정되었다. 캠벨은 다른 품종에 비해 다양한 휘발 성분이 동정되었고 레드글로브와 머루 품종에서는 1-hexanol, 2-decene, 8-methyl-(z)/1-dodecanol 등을 제외한 나머지 휘발 성분은 거의 나타나지 않았다. 또한 전자코를 이용하여 휘발성 향기성분 패턴 분석결과 $4^{\circ}C$와 실온 저장한 시료의 제 1주성분 값의 기여율은 각각 99.30, 99.36%로 품종에 따라 구분이 가능하였다. $4^{\circ}C$ 저장 시 저장 기간에 따른 제 1주성분 값의 변화 범위는 실온에서 저장한 것에 비해 적었음을 확인할 수 있었다.

Antimicrobial activity of Gynura segetum's leaf extracts and its active fractions

  • Seow, Lay-Jing;Beh, Hooi-Kheng;Ibrahim, Pazilah;Sadikun, Amirin;Asmawi, Mohd Zaini
    • 셀메드
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    • 제2권2호
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    • pp.20.1-20.5
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    • 2012
  • $Gynura$ $segetum$ (Lour.) Merr. ($Compositae$) is a well recognized medicinal plant in Indonesia and Malaysia. It is believed to have an anticoagulant effect and is used in treating snake-bites, inflammations and other skin afflictions. This study was carried out to evaluate the antimicrobial effects of $Gynura$ $segetum$ leaves extracts and its fractions. The chemical compositions of the active extracts were also determined. The antimicrobial activities of different solvent extracts of leaves of $Gynura$ $segetum$ were evaluated using the agar well-diffusion method. The Minimum Inhibitory Concentration (MIC) of the active subfractions was determined by the tube dilution method. Gas Chromatography-mass spectrometry (GC-MS) analysis was carried out to identify the chemical compositions of the active extracts. The ethyl acetate fraction and its subfraction E4 performed potent antimicrobial activities and fifteen known chemical constituents were identified by GCMS analysis as 4-vinylphenol, 1-tetradecene, phenol, 2,4-bis(1,1-dimethylethyl), 1-hexadecene, E-15-heptadecenal, hexadecanoic acid, 1,2-benzenedicarboxylic acid, dibutyl ester, 1-docosene, octadecanoic acid, 1-eicosene, cyclotetracosane, 1,2-benzenedicarboxylic acid, bis(2-ethylhexyl)ester, butanedioic acid, monomethyl ester, niacin and 4-hydroxy-benzoic acid. The results of this study suggested a connection between the antimicrobial activities and the chemical structures. The plant may be used as a potential source for antimicrobial agents.

느타리버섯 자실체의 부위 및 생육시기별 지방산 조성의 변화 (Changes of Fatty Acid Composition by Various Developmental Stage and Fruit Body Section in Pleurotus ostreatus)

  • 류영현;이숙희;조우식;윤재탁
    • 한국균학회지
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    • 제28권2호
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    • pp.109-111
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    • 2000
  • 느타리버섯(원형1호 느타리) 자실체의 부위별로 지방산 조성을 조사한 결과 linoleic acid는 갓부위에서 가장 높았고 대부위로 갈수록 낮아지는 경향이었고 stearic acid와 palmitic acid는 대부위로 갈수록 증가하는 경향이었다. 생육시기별 지방산조성은 oleic acid의 경우 버섯원기형성 후 $11{\sim}12$일 까지는 점차 증가하다가 이후부터는 감소하는 경향을 보였고 linoleic acid와 불포화지방산대비 포화지방산의 비율은 원기형성 후 $3{\sim}4$일까지는 증가하다가 그 후부터는 감소하는 경향을 나타내었다.

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