• Title/Summary/Keyword: acid environment

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Effect of Acid Fog on Rust Formation and Fatigue Strength of Weathering Steel (산성안개가 내후성강재의 녹형성 및 피로강도에 미치는 영향)

  • Kim, Min-Gun;Ku, Eun-hoi
    • Journal of Industrial Technology
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    • v.22 no.B
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    • pp.13-20
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    • 2002
  • The purpose of this study is to investigate the effect of acid fog on the rust formation behavior of weathering steel (SMA50) which is used in uncoated bridges. Weathering steel didn't form the passive film under the environment of acid fog(pH5,6), whereas the environment of distilled water formed the protective oxide film. Therefore, the construction of weathering steel under the environment extremely exposed to SOx and NOx which are the main compositions of acid fog is not adequate. Fatigue limits of weathering steel under acid fog environment are remarkably decreased as compared with environment of distilled water. The corrosive constituents in acid fog has piled up the corrosion products on specimen surface and generated the corrosion pits. Because of the high stress concentration arising at this corrosion pit, relatively low fatigue limits were obtained for acid fog specimens.

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Effect of Acid Fog on Rust Formation and Fatigue Behavior of Weathering Steel Used in Un-Coated Bridge (무도장 교량에 사용되는 내후성강재의 부식 및 피로거동에 미치는 산성안개의 영향)

  • Kim, Min-Gun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.1
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    • pp.13-20
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    • 2008
  • The purpose of this study is to investigate the effect of acid fog on the rust formation behavior of weathering steel (SMA50) which is used in un-coated bridges. Weathering steel didn't form the passive film under the environment of acid fog(pH5,6), whereas the environment of distilled water formed the protective oxide film. Therefore, the construction of weathering steel under the environment extremely exposed to SOx and NOx which are the main compositions of acid fog is not adequate. Fatigue limits of weathering steel under acid fog environment are remarkably decreased as compared with environment of distilled water. The corrosive constituents in acid fog has piled up the corrosion products on specimen surface and generated the corrosion pits. Because of the high stress concentration arising at this corrosion pit, relatively low fatigue limits were obtained for acid fog specimens.

Quantitative Analysis of Acid Value, Iodine Value and Fatty Acids Content in Sesame Oils by NIRS (근적외선분광광도법을 이용한 참기름의 산가, 요오드가, 지방산정량법에 관한 연구)

  • Kim, Jae-Kwan;Lee, Myung-Jin;Kim, Myung-Gill;Kim, Kyung-A;Park, Eun-Mi;Kim, Young-Sug;Ko, Hoan-Uck;Son, Jin-Seok
    • Journal of Food Hygiene and Safety
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    • v.21 no.4
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    • pp.204-212
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    • 2006
  • This study was conducted to investigate the possibility of rapid and non-des tructive evalution of AV (Acid Value), IV (Iodine Value) and fatty acids in sesame oils. The samples were scanned over the range $400\sim2500nm$ using transmittance spectrum of NIRS(Near-infrared spectroscopy). A calibration equation calculated by MPLS regression technique was developed and correlation coefficient of determination for AV, IV, palmitic acid, stearic acid, linoleic acid and linolenic acid content were 0.9907, 0.9677, 0.9527, 0.9210, 0.9829, 0.9736 and 0.9709 respectively. The validation model for measuring the AV content had R of 0.989, SEP of 0.058 and IV content had R of 0.944, SEP of 0.562 and palmitic acid content had R of 0.924, SEP of 0.194 and stearic acid content had R of 0.717, SEP of 0.168 and oleic acid content had R of 0.989, SEP of 0.221 and linoleic acid content had R of 0.967, SEP of 0.297 and linolenic acid content had R of 0.853, SEP of 0.480 by MPLS. The obtained results indicate that the NIRS procedure can potentially be used as a non-destructive analysis method for the purpose of rapid and simple measurement of AV, IV and fatty acids in sesame oils.

Physicochemical Composition of Seaweed Fulvescens (Capsosiphon fulvescens) (매생이(Capsosiphon fulvescens)의 이화학적 성분)

  • Yang, Ho-Cheol;Jung, Kyeong-Mo;Gang, Kwang-Sung;Song, Byeong-Jun;Lim, Hyeon-Cheol;Na, Hwan-Sik;Mun, Hee;Heo, Nam-Chil
    • Korean Journal of Food Science and Technology
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    • v.37 no.6
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    • pp.912-917
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    • 2005
  • Physicochemical components of dried green algae, Seaweed fulvescens (Capsosiphon fulvescens) with $96.02{\pm}0.02%$ moisture content, were investigated. Crude protein, crude lipid, ash and carbohydrate content of C. fulvescens were $31.76{\pm}0.26,\;1.01{\pm}0.21,\;13.58{\pm}0.62\;and\;53.65{\pm}0.73$, respectively. Predominant minerals were Na, Mg, Ca, K and P. Fe $(122.83{\pm}11.19mg/%)\;and\;Se\;(0.90{\pm}0.07mg%)$ contents in were higher than those of other seaweeds. Major free sugars were identified as fructose, glucose, sucrose, maltose and galactose. Organic acid including L-malic acid, citric acid, tartaric acid and d-malic acid were detected. Most abundant amino acids were glutamic acid, aspartic acid and alanine. Main fatty acids were palmitic acid, linolenic acid and stearidonic acid, with 58.37% polyenes.

Changes of Fatty Acid Composition by Various Developmental Stage and Fruit Body Section in Pleurotus ostreatus (느타리버섯 자실체의 부위 및 생육시기별 지방산 조성의 변화)

  • Rew, Young-Hyun;Lee, Sook-Hee;Jo, Woo-Sik;Yoon, Jae-Tak
    • The Korean Journal of Mycology
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    • v.28 no.2
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    • pp.109-111
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    • 2000
  • Composition of fatty acids (FAs) in Pleurotus ostreatus were analyzed by gas chromatography and compositional changes according to cultivar, fruitbody section and developmental stage (days after primordia formation) were investigated. Major FAs in oyster mushroom were linoleic acid, oleic acid and palmitic acid. Unsaturated FAs were higher in pileus portion than upper- or lower-stipe portion. Oleic acid content was increased with developmental days but linoleic acid content was highest at $3{\sim}4$ days after primordia formation and then decreased after that. And ratio of unsaturated FAs/saturated FAs was decreased with basidiocarp maturation.

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Butyric Acid Fermentation of Sodium Hydroxide Pretreated Rice Straw with Undefined Mixed Culture

  • Ai, Binling;Li, Jianzheng;Chi, Xue;Meng, Jia;Liu, Chong;Shi, En
    • Journal of Microbiology and Biotechnology
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    • v.24 no.5
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    • pp.629-638
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    • 2014
  • This study describes an alternative mixed culture fermentation technology to anaerobically convert lignocellulosic biomass into butyric acid, a valuable product with wide application, without supplementary cellulolytic enzymes. Rice straw was soaked in 1% NaOH solution to increase digestibility. Among the tested pretreatment conditions, soaking rice straw at $50^{\circ}C$ for 72 h removed ~66% of the lignin, but retained ~84% of the cellulose and ~71% of the hemicellulose. By using an undefined cellulose-degrading butyrate-producing microbial community as butyric acid producer in batch fermentation, about 6 g/l of butyric acid was produced from the pretreated rice straw, which accounted for ~76% of the total volatile fatty acids. In the repeated-batch operation, the butyric acid production declined batch by batch, which was most possibly caused by the shift of microbial community structure monitored by denaturing gradient gel electrophoresis. In this study, batch operation was observed to be more suitable for butyric acid production.

Oxalic Acid-based Remediation of Arsenic-contaminated Soil (옥살산 기반의 비소오염토양 정화 연구)

  • Lee, Myeong Eun;Jeon, Eun-Ki;Kim, Jong-Gook;Baek, Kitae
    • Journal of Soil and Groundwater Environment
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    • v.23 no.1
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    • pp.85-91
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    • 2018
  • Arsenic (As) usually is bound to amorphous iron oxides in the soils, and it can be removed via dissolution of iron oxides. Inorganic acid and chelating agent are widely used to extract As in the soil washing. However, the overall performance is highly dependent on the state of As fractionation. In this study, oxalic acid and inorganic acids (HCl, $H_2SO_4$, and $H_3PO_4$) were applied to enhance the dissolution of iron oxides for remediation of As-contaminated soils. Oxalic acid was most effective to extract As from soils and removal of As was two times greater than other inorganic acids. Additionally, 75% of As bound to amorphous iron oxides was removed by 0.2 M oxalic acid. Arsenic removal by oxalic acid was directly proportional to the sum of labile fractions of As instead of the total concentration of As. Therefore, the oxalic acid could extract most As bound to amorphous iron oxides.

Effects of Acid Fog Environment on the Corrosion Fatigue Strength of Structural Steel SM55C (기계구조용강 SM55C의 부식피로강도에 미치는 산성안개 분위기의 영향)

  • 김진학;김민건
    • Transactions of the Korean Society of Automotive Engineers
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    • v.8 no.5
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    • pp.181-187
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    • 2000
  • Fatigue tests under acid fog environment were carried out to investigate the effect of acid fog on the corrosion fatigue strength of SM55C in comparison with distilled water. Main results obtained are as follows. The fatigue strength of SM55C under acid fog environment are remarkably decreased as compared with that of distilled water specimen. The corrosive effect of acid fog on fatigue strength are more serious under low stress amplitude level than under high stress amplitude level, and this leads to continuous reduction of fatigue strength. Under acid fog environment in early stage of crack growth. because the corrosive components dissolve the crack face offensively. the unstable fracture surface appears. But, the stable corrosion precipitation and products layer are formed on the fracture surface in accordance with the time pass.

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A Survey on Adulteration and Safety of Sesame oil Circulated in Gwangju (광주지역에서 유통되고 있는 참기름의 진위판별 및 안전성 조사)

  • Yang, Yong-Shik;Kim, Jong-Pil;Seo, Kye-Won;Cho, Bae-Sick;Gang, Gyung-Lee;Kim, Eun-Sun;Park, Jong-Tae
    • Journal of Food Hygiene and Safety
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    • v.23 no.3
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    • pp.212-217
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    • 2008
  • This survey was conducted to monitor the adulteration of sesame oil circulated in Gwangju, 2007. A total of 60 samples was tested by analysis of fatty acid composition. Of these samples, 22 were from large-scale manufacturer, 25 were from small-scale manufacturer and 13 from Bangagan. First of all, in goods manufactured by large-scale company, there are no sesame oils where linolenic acid($C_{18:3}$) exceed regulatory guidance(0.5%). 5 samples from small-scale manufacturer contained linolenic acid from 0.90% to 8.38%, which means that they have other cooking oil, such as com oil, soybean oil and rape seed oil. Among Bangagan goods, only one sample have 1.20% of linolenic acid. On the other hand erucic acid($C_{22:1}$) was not detected in 60 samples at all, which means that they were not adulterated with rape seed oil. And among 6 samples of exceeding 0.5% of linolenic acid and 12 samples from Bangagan, 13 of them had benzo(a)pyrene from $0.2{\mu}g/kg\;to\;0.7{\mu}g/kg$ and the other 5 samples did not.

P-hydroxybenzoic acid positively affect the Fusarium oxysporum to stimulate root rot in Panax notoginseng

  • Jing Zhao;Zhandi Wang;Rong Jiao;Qionglian Wan;Lianchun Wang;Liangxing Li;Yali Yang;Shahzad Munir
    • Journal of Ginseng Research
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    • v.48 no.2
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    • pp.229-235
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    • 2024
  • Background: Plant health is directly related to the change in native microbial diversity and changes in soil health have been implicated as one of the main cause of root rot. However, scarce information is present regarding allelopathic relationship of Panax notoginseng root exudates and pathogenic fungi Fusarium oxysporum in a continuous cropping system. Methods: We analyzed P. notoginseng root exudate in the planting soil for three successive years to determine phenolic acid concentration using GC-MS and HPLC followed by effect on the microbial community assembly. Antioxidant enzymes were checked in the roots to confirm possible resistance in P. notoginseng. Results: Total 29 allelochemicals in the planting soil extract was found with highest concentration (10.54 %) of p-hydroxybenzoic acid. The HPLC showing a year-by-year decrease in p-hydroxybenzoic acid content in soil of different planting years, and an increase in population of F. oxysporum. Moreover, community analysis displayed negative correlation with 2.22 mmol. L-1 of p-hydroxybenzoic acid correspond to an 18.1 % population of F. oxysporum. Furthermore, in vitro plate assay indicates that medium dose of p-hydroxybenzoic acid (2.5-5 mmol. L-1) can stimulate the growth of F. oxysporum colonies and the production of macroconidia, as well as cell wall-degrading enzymes. We found that 2-3 mmol. L-1 of p-hydroxybenzoic acid significantly increased the population of F. oxysporum. Conclusion: In conclusion, our study suggested that p-hydroxybenzoic acid have negative effect on the root system and modified the rhizosphere microbiome so that the host plant became more susceptible to root rot disease.