• Title/Summary/Keyword: acid deposition

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Numerical simulation of wet deposition flux by the deposition model (침적 모형에 의한 습성침적 플럭스 수치모의)

  • 이화운;문난경;임주연
    • Journal of Environmental Science International
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    • v.11 no.12
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    • pp.1235-1242
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    • 2002
  • The purpose of this study is to estimate wet deposition flux and to investigate wet deposition characteristics by using the ADOM model. Wet deposition flux of highly reactive $SO_2$ is estimated by applying observed meteorological parameters and concentrations of chemical species to the ADOM model. Wet deposition is largely dependent on large scale precipitation and cloud thickness. Wet deposition flux of sulfate depends on $SO_2$ oxidation in clouds. When large amount of $SO_2$ is converted to sulfate, deposition flux of sulfate increases, but wet deposition flux of $SO_2$ is small. On the whole, the pattern of sulfate wet deposition flux agrees with the typical pattern of sulfate wet deposition that is high in the summer(July) and low in the winter(January).

Evaluation of Fatty Acid System LB Films by using a Quartz Crystal (수정진동자에 의한 지방산계 LB막의 누적평가)

  • Park, Man-Chul;Choi, Yong-Sung;Chang, Sang-Mok;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 1992.07a
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    • pp.498-500
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    • 1992
  • In this paper, we described a evaluating technique of deposition status of LB films by quartz crystal. As a deposited material for this experiments, arachidic acid and stearic acid were used. We observed the deposition status of LB films on the surface of quartz crystal. The experimental results showed that Y type H films are deposited according to frequency shift, deposition ratio, and SEM photographs etc.

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Organic Gas Response Characteristics for Horizontal Direction of Fatty Acid LB Ultra-thin Films (지방산 LB초박막의 수평방향에 대한 유기가스 반응특성)

  • Lee, Jun-Ho;Choe, Yong-Seong;Kim, Do-Gyun;Gwon, Yeong-Su
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.5
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    • pp.379-384
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    • 1999
  • Langmuir-Blodgett(LB) films which have high ordered orientation and ordering structure are fabricated by LB method which deposit the ultra-thin films of organic materials at a molecular level. The electrical characteristics of stearic acid LB ultra-thin films for the horizontal direction were investigated to develop the gas sensor using LB ultra-thin films. The optimal deposition condition to deposit the LB ultra-thin films was obtained from $\pi-A$ isotherms and the deposition status of stearic acid LB ultra-thin films was verified by the measurement of deposition ratio, UV-absorbance, and electrical properties for LB ultra-thin films. The conductivity of stearic acid LB ultra-thin films for horizontal direction was about $10_{-8}[S/cm]$. The activation energy for LB ultra-thin films with respect to variation of temperature was about 1.0[eV], which was correspond to semiconductor material. The response characteristics for organic gas were confirmed by measuring the response time, recovery time, and reproducibility of the LB ultra-thin to each organic gas. Also, the penetration and adsorption behavior of gas molecule were confirmed through the organic gas response characteristics of LB ultra-thin films with respect to temperature.

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Estimation of Dry Deposition in Urban Area, 2005 (2005년 도시지역의 건성침적량 산정에 관한 연구)

  • Shin S.A.;Han J.S.;Lee S.D.;Choi J.S.
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.4
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    • pp.477-486
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    • 2006
  • Dry deposition fluxes for $SO_2$, particulate sulfate, nitrate, ammonium and $HNO_3$ were estimated in urban area for the time period January$\sim$ October 2005. Fluxes were generated using atmospheric concentration data collected both in Acid Deposition and Air Quality Monitoring Networks, and deposition velocities computed by combining land-use data with meteorological information. The resulting annually averaged $SO_2$, $NO_3$, and aerosol deposition velocities were found to be 0.4 cm/s, 4.3 cm/s and 0.1 cm/s, respectively, and thus deposition rates were 4.4 mg/$m^2$. day for $SO_2$, and 5.4 mg/$m^2$ . day for $NHO_3$, and particulate sulfate, ammonium and nitrate recorded 1.0 mg/$m^2$ . day, 0.4 mg/$m^2$ . day and 0.4 mg/$m^2$ day, respectively. Maximum for in seasonal variation of monthly averaged deposition velocities occurred in summer in contrast to $HNO_3$ showing peak in spring. There was no significant variation for aerosol. The dry to total (wet and dry) deposition contributed about 40% for sulfur and 28% for nitrogen species in this study.

A Study on Electrical Characteristics for Horizontal Direction of Stearic Acid LB Films (Stearic Acid LB막의 수평방향에 대한 전기적 특성 연구)

  • 김도균;최용성;장정수;권영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.393-396
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    • 1996
  • The electrical characteristics of stearic acid LB films far the horizontal direction were investigated to develop the gab sensor using LB films. $\pi$ -A isotherm was measured to transfer stearic acid on slide glass substrate and surface pressure for optimal deposition was 25[dyne/cm]. The deposition status of stearic acid LB films was verified by the measurement of capacitance which was increased with the number of layers. The thickness of electrode was estimated about 1000 by the I-V characteristics far the horizontal direction. The Conductivity of stearic acid LB films for horizontal direction was 10$^{-8}$ [S/cm] that mean like semiconductor.

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Chemical Composition and Seasonal Variation of Acid Deposition in Chiang Mai, Thailand

  • Sillapapiromsuk, S.;Chantara, S.
    • Environmental Engineering Research
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    • v.15 no.2
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    • pp.93-98
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    • 2010
  • This study aims to determine the chemical composition and seasonal variation of atmospheric acid deposition in order to identify possible sources contributing to precipitation. Sampling and analysis of 132 wet deposition samples were carried out from January to December 2008 at Mae Hia Research Center, Chiang Mai University, Chiang Mai Province. Total precipitation was 1,286.7 mm. Mean electro-conductivity and pH values were 0.94 mS/m and 6.27, respectively. Major cations ($Na^+$, ${NH_4}^+$, $K^+$, $Ca^{2+}$, and $Mg^{2+}$) and major anions ($HCOO^-$, $CH_3COO^-$, $Cl^-$, ${NO_3}^-$, and ${SO_4}^{2-}$) were determined by Ion Chromatography. The relative volume weight mean concentrations of anions, in descending order, were ${SO_4}^{2-}$ > ${NO_3}^-$ > $Cl^-$ > $CH_3COO^-$ > $HCOO^-$ and those of cations were $NH_4^+$ > $Ca^{2+}$ > $Mg^{2+}$ > $K^{+}$ > $Na^+$. Results of a principle component analysis highlighted the influence of various possible sources of ions such as agricultural activity, fuel combustion, marine sources, soil resuspension, and biomass burning.

Palladium Layers on an Au(111) Nanoparticle and Their Catalytic Activity to Formic Acid Oxidation

  • Kim, Byeong-Gwon;Seo, Dae-Ha;Song, Hyeon-Jun;Gwak, Ju-Hyeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.206-206
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    • 2011
  • Nanoparticles have been received great attention from many researchers for several decades because of their good and unique properties. In particular, researches in the field of synthesis of bimetallic nanoparticles showed good results for the past ten years. In this research, Pd thinlayer on Au nanoparticles were synthesized by electrochemical deposition method. Well-defined Au(111) nanoparticles were synthesized by solution based reduction method. Electrochemical deposition conditions for Pd thinlayer on Au(111) nanoparticles surface were carefully regulated by controlling parameters of cyclic voltammetry. To calculate exact mass and surface area catalytic activities of deposited Pd thinlayer on Au(111) nanoparticle, electrochemically active surface area (ECSA) and mass of the deposited Pd thinlayer were measured by cyclic voltammetry in 0.1 M HClO4 solution. Afterward, catalytic activities of the deposited Pd thinlayer were measured in 0.1 M HClO4 + 0.2 M formic acid solution. In case of less negative deposition potential, the amounts of deposited Pd mass and surface area were small. However, mass and ECSA activity of the deposited Pd to oxidize formic acid were increased.

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Determination of Ag(I) at a Chemically Modified Electrode Based on 2-Imino-cyclopentane-dithiocarboxylic Acid

  • Jeong-Sik Yeom;Mi-Sook Won;Sung-Nak Choi;Yoon-Bo Shim
    • Bulletin of the Korean Chemical Society
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    • v.11 no.3
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    • pp.200-205
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    • 1990
  • Chemically modified electrodes(CMEs), based on 2-imino-1-cyclopentane-dithiocarboxylic acid (icdc) containing carbon paste, have been characterized using cyclic voltammetric techniques. Ag(I) was chemically deposited on the CMEs, and voltammograms were obtained with the electrode in a separate buffer solution. The CME surface can be regenerated with exposure to acid and reused for deposition. In 10 deposition/measurement/regenerate cycles, the linear response have been reproduced up to $1{\times}10^{-6}$ M in linear sweep voltammetry and 1${\times}$10-8 M in differential pulse voltammetry with relative standard deviation of 5.2% and 12.4%, respectiveiy. The sensitivity increased with deposition time and scanning rate, and detection limit was $1{\times}10^{-7}M\;and\;1{\times}10^{-9}M$ at 20 minutes deposition in the linear sweep voltammetry and differential pulse voltammetry, respectively. The presence of some metal ions does not influence the silver ion response. Satisfactory results were obtained for the analysis of the silver ion for a variety of reference materials without interference of Hg ion at the condition of pH = 5-6.

Study on fatty acids composition by latent fingerprint deposition (유류된 잠재지문의 지방산조성에 관한 연구)

  • Choi, Mi Jung;Ha, Jaeho;Park, Sung Woo
    • Analytical Science and Technology
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    • v.21 no.3
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    • pp.212-221
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    • 2008
  • In order to investigate the information for effective detection and developing of latent fingerprints, we identified fatty acids composition of latent fingerprints on non-porous evidence surface and the chemical changes of latent fingerprint residue after print deposition during 7 months. Fingerprints from eight Korean male donors (aged 29-50 years) and one female donor (aged 36 years) were collected. All fingerprints were found to contain lauric acid (C12:0), myristic acid (C14:0), palmitic acid (C16:0), stearic acid (C18:0), elaidic acid (C18:1n9t), oleic acid (C18:1n9c), linoleic acid (C18:2n6c), arachidic acid (C20:0), linolenic acid (C18:3n3), erucic acid (C22:1n9) and docosadienoic acid (C22:2) and primarily palmitic acid (35.45-48.37%), oleic acid (14.84-28.49%), stearic acid (9.71-24.96%) and linoleic acid (7.68-18.8%) occupied 75% of total fatty acids. When the fingerprints were deposited at dark room for 7 months, total fatty acids components decreased about 12-25%. It can be explained that significant degradation of long-chain fatty acids such as elaidic acid (C18:1n9t), arachidic acid (C20:0), linolenic acid (C18:3n3), erucic acid (C22:1n9), and docosadienoic acid (C22:2) resulted in the generation of myristic acid (C14:0), myristoleic acid (C14:1) and pentadecanoic acid (C15:0).

Meat Quality, Digestibility and Deposition of Fatty Acids in Growing-finishing Pigs Fed Restricted, Iso-energetic Amounts of Diets Containing either Beef Tallow or Sunflower Oil

  • Mitchaothai, J.;Everts, H.;Yuangklang, C.;Wittayakun, S.;Vasupen, K.;Wongsuthavas, S.;Srenanul, R.;Hovenier, R.;Beynen, A.C.
    • Asian-Australasian Journal of Animal Sciences
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    • v.21 no.7
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    • pp.1015-1026
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    • 2008
  • The influence of dietary beef tallow (BT) versus sunflower oil (SO) on meat quality and apparent digestibility and deposition of individual fatty acids in the whole carcass was investigated in pigs fed diets containing either BT or SO. The diets contained equal amounts of energy in the form of the variable fats and were fed on an iso-energetic, restricted basis. Crude fat in the SO diet was better digested (p<0.001) than in the BT diet. The dietary fat type had no effect on growth performance, physical properties of the carcass and meat quality. The pigs fed the BT diet showed lower (p<0.001) apparent digestibilities for palmitic and linoleic acid, but those of oleic and ${\alpha}$-linolenic acid were not affected. The ratio of deposition in the carcass to intake of digestible fatty acids for the whole feeding period was decreased (p<0.01) for oleic and linoleic acid in pigs fed the SO diet. The pigs fed the SO diet instead of the BT diet had a lower (p<0.05) deposition:intake ratio for mono-unsaturated fatty acids. The calculated minimum de novo synthesis of saturated fatty acids was increased for the SO diet, but that of mono-unsaturated fatty acids was not different. In conclusion, the iso-energetic replacement of BT by SO had a marked impact on the fatty acid composition of tissues, but did not affect carcass and meat quality traits in spite of the marked difference in the deposition of linoleic acid in adipose tissues, loin muscle and the whole body. In addition, it became clear that the type of dietary fat had marked, specific effects on the synthesis and oxidation of fatty acids.