• Title/Summary/Keyword: acetaldehyde concentration

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Comparison of recovery rates of DNPH-Cartridge sampler in the analysis of odorous carbonyl compounds (DNPH Cartridge를 이용한 악취성 카르보닐화합물의 분석회수율 비교)

  • Hong, One-Feel;Lim, Sung-Min;Kim, Ki-Hyun
    • Analytical Science and Technology
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    • v.23 no.5
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    • pp.446-456
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    • 2010
  • In this study, the performance characteristics of DNPH sampling were investigated in the collection and analysis of 5 carbonyl compounds (CC) in air using the cartridge products produced by three different makers. For these experiments, gaseous standards of 5 CCs were prepared to cover 9 concentration levels for each compound (33~2600 nmol). Some cartridge products exhibited relatively high blank values of acetaldehyde (AA) and propionaldehyde (PA). The recovery rates of all three cartridges showed moderate reduction as the molecular weight of CC increased. In addition, when the recovery rate was compared by percent error (%), the most stable patterns were achieved in the intermediate concentration range of 263~1312 nmol (in case of AA). The overall results of our study suggest that the optimal range of recovery for a given concentration range should be considered to obtain the most reliable data for the DNPH cartridge method.

Natural herbal extract complex induces the degradation of alcohol and acetaldehyde and reduces the breath alcohol concentration (천연소재복합물의 알코올 및 아세트알데히드 분해활성 및 호기중 알코올 농도 감소)

  • Hwang, Ji Hong;Kim, Mi-Yeon
    • The Journal of the Convergence on Culture Technology
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    • v.6 no.3
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    • pp.381-392
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    • 2020
  • This study is purposed to check up the natural 12 kinds of herbal extracts suitable for hangover and based on the results of contents of phenolic compounds, ABTS radical scavenging activity, alcohol dehydrogenase (ADH), and acetaldehyde dehydrogenase (ALDH). Selected 8 kinds of herbal extracts are blended according to the efficacy and the pearson's correlation between each content and activity. C. sinensis var. sinensis, P. densiflora Gnarl and P. lobata Ohwi showed excellent ADH activity, P. lobata Ohwi had a strong correlation between the content and efficacy, and C. sinensis var. sinensis, P. densiflora Gnarl had a negative correlation. Through the ADH and ALDH activity test of F.1 to F.7, the F.7 showed the highest synergic effect and selected as an optimal formulation. F.7 intake-group, the breath alcohol concentration was significantly reduced to 58% after 30 minutes and 27% after 120 minutes, compared to right after alcohol consumption. After alcohol consumption, there was a significant improvement effect (p<0.05) in tired and thirst in the intake group compared to the non-intake group.

Photocatalytic Activities of Titania Deposited Beads by FB-CVD as Operation Variables (유동층 화학기상증착(FB-CVD)으로 제조한 광촉매 박막증착 비드의 조업변수에 따른 반응성)

  • Lim, Nam-Yun;Lee, Seung Yong;Park, Jaehyeon;Kwak, Jini;Park, Hai Woong
    • Korean Chemical Engineering Research
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    • v.44 no.3
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    • pp.300-306
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    • 2006
  • Photocatalyst deposited beads were prepared by fluidized bed chemical vapor deposition (FB-CVD) under various operating conditions of substrates, bed temperature, pressure, and oxygen concentration. Photocatalytic degradation of acetaldehyde was carried out to determine the optimum operating condition of prepared photocatalysts. They were characterized by using FE-SEM, XRD, and XPS. From the FE-SEM photographs, it was found that the surfaces of titania-coated beads were covered with crystal form, particle form, and slick form of titania on alumina, silica-gel, and glass beads, respectively. From the result of photocatalytic degradation of acetaldehyde, it was found that prepared titania/ alumina beads at $600^{\circ}C$, 5 torr showed superior performance to others, and oxygen flow rate has no significant effect.

Emission Characteristics of Carbonyl Compounds from Major Industrial Sectors in the Ban-Wall Industrial Complex, Korea (카보닐 계열의 배출 특성과 그에 따른 악취 발생 기여도 비교 연구: 반월공단내 주요 산업시설물들을 중심으로)

  • Hong, Y.J.;Jeon, E.C.;Kim, K.H.
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.5
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    • pp.679-692
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    • 2006
  • The carbonyl compounds in the atmosphere belong to one of the regulatory pollutants for the malodor control designated by the Korean Ministry of Environment(KMOE). In the present study, the emission concentration levels of carbonyl compounds were measured along with a number of criteria odor pollutants from a total of 47 individual companies(June 2004 to January 2005). The results of our study showed that a number of carbonyl compounds(such as formaldehyde, acetaldehyde, acetone, and butyraldehyde) maintained significantly high mean concentrations of 298 to 372 ppb. In contrast, other carbonyl compounds were low enough with the mean valves of 0.54 to 19.1 ppb. It was found that except for such industries as metal production or leather processing, their emissions were generally quite significant. If the measured values were evaluated in terms of malodor intensity, butyraldehyde appeared to be the most significant contributor to the malodor release. According to the measurements made in strong source areas, it can be concluded that several carbonyl compounds(acetaldehyde, propionaldehyde, butyraldehyde, isovaleraldehyde, and valeraldehyde) are useful enough to diagnose malodor release from those source areas. It should also be addressed that a number of carbonyl compounds added newly as the result of malodor control legislation were not sensitive enough to diagnose malodor release from such sources.

1,4-Dioxane Decomposition by Catalytic Wet Peroxide Oxidation using Cu Wire Catalysts (Cu wire 촉매를 이용한 촉매습식과산화공정에 의한 1,4-다이옥산의 분해)

  • Lee, Dong-Keun;Kim, Dul Sun
    • Clean Technology
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    • v.22 no.4
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    • pp.281-285
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    • 2016
  • Cu wire catalyst was highly reactive toward catalytic wet peroxide oxidation of the highly refractory 1,4-dioxane. While complete removal of 1,4-dioxane could be achieved with the catalyst, the removed 1,4-dioxane could not totally mineralized into $CO_2$ and $H_2O$. In accordance with the disappearance of 1,4-dioxane, formaldehyde and oxalic acid were formed gradually with reaction time and they went through maxima. At around the time of maximum concentrations of these two intermediates acetaldehyde concentration was increased drastically and showed maximum value. With the disappearance of these three intermediates, formic acid together with ethylene glycol diformate began to increase gradually. The Cu wire catalyst was proved also to be highly stable against deactivation during the reaction.

A Study on the Emission Characteristics and Impact of Aldehydes from the Printing Industry (인쇄시설의 알데하이드류 배출특성 및 영향 평가)

  • Hwang, Cheol-Won;Song, Il-Seok;Kim, Se-Kwang;Oh, Cheon-Hwan;Kim, Tae-Hyun;Jeong, Byeong-Hwan;Park, Eun-Hye;Kim, Jong-Soo;Choi, Kum-Chan
    • Journal of Environmental Health Sciences
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    • v.45 no.5
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    • pp.474-486
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    • 2019
  • Objectives: This study was performed to investigate the emission characteristics of aldehydes emitted by the printing industry and to evaluate their impact on adjacent residential areas. Methods: Aldehydes and THC were measured from the front of the control device in the printing and coating process. Aldehydes and ketones were measured by workplace area, residential area, and background area to evaluate their impact. Results: The concentrations of formaldehyde (<0.047 ppm) and acetaldehyde (<0.068 ppm) in the printing and coating process were relatively low, and the methyl ethyl ketone used as the primary solvent was the main carbonyl compound in the printing process. The daily mean concentrations of formaldehyde and acetaldehyde were not significantly different by workplace area, residential area, or background area. However, the concentration of methyl ethyl ketone was high in the order of workplace area, residential area, and background area. Conclusions: The concentrations of formaldehyde and acetaldehyde in the adjacent residential areas are considered to be more influenced by secondary sources of photochemical reactions than by primary sources. Methyl ethyl ketone is considered to be highly influenced by the primary source, which is printing facilities.

Evaluation of Clinical Usefulness of Herbal Mixture HO-Series for Improving Hangover (복합생약 HO-Series의 숙취개선 임상적 유용성 평가)

  • Chang, Bo Yoon;Bae, Jin Hye;Kim, Da Eun;Kim, Dae Sung;Cho, Hyoung Kwon;Kim, Sung Yeon
    • Korean Journal of Pharmacognosy
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    • v.51 no.4
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    • pp.278-290
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    • 2020
  • The purpose of this study is to investigate the hangover relieving effect of HO-series. HO-S1 is an herbal mixture, which consists of extracts from Flower of Pueraria lobata Ohwi, Glycyrrhiza glabra Linné, Fruit of Lycium chinense Miller, Poria cocos Wolf, Acanthopanax sessiliflorum Seeman, Scutellaria baicalensis Georgi, Atractylodes lancea De Candlle and Zingiber officinale Roscoe. HO-S2 is a candidate that has been performed to ultra filtration based on HO-S1. HO-S3 is a mixture of amino acids and vitamins based on HO-S2. HO-01 is the final beverage base produced based on HO-S3. The antioxidant activity of HO-series was similar to that of vitamin C or trolox. The production of t-BHP induced reactive oxygen species(ROS) was significantly blocked in the presence of HO-series. In vivo study, AUC of alcohol and acetaldehyde concentrations in HO-S2 and HO-S3 treated groups significantly decreased. Hepatic alcohol dehydrogenase(ADH) and acetaldehyde dehydrogenase(ALDH) activity were significantly higher in HO-S2 and HO-S3 treated groups. And 2E1 activity and glutathione were significantly elevated, while the malondialdehyde level was not significantly in liver tissue. After alcohol exposure, the sensitivity scores of blood alcohol and acetaldehyde concentration and hangover symptoms were significantly decreased in the HO-01 intake group compared with the non-intake group. ALDH activity was significantly increased in the HO-01 intake group. HO-series have antioxidant activity and a protective effect from ROS. HO-S2, HO-S3 and HO-01 are potentially highly beneficial in relieving hangover, as it scavenges reactive free radicals and boosts the endogenous antioxidant system.

Effect of Ginseng Extract Residue Roasted on Alcohol Detoxification (홍삼박 볶음처리 추출액이 알콜해독에 미치는 효과)

  • Ko, Ji-Hun;Park, Myong-Han;Lee, Chun-Bae
    • Journal of Ginseng Research
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    • v.18 no.2
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    • pp.118-121
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    • 1994
  • Alcohol and acetaldehyde concentrations were measured in the blood and brain of rats which were treated with 20% alcohol (control group) or co-administered 20% alcohol with ginseng extract residue roasted (test group). There was no change in blood alcohol concentration between control and test group. However, the brain alcohol concentration was lowered in the test group which was treated for seven days. The concentration of aldehyde in the brain and blood was lowered in the test group. The activities of monoamine oxidase b in various regions of brain were recovered to normal group in the test groups. However, the Quantities of naloxone binding receptors were not changed by ginseng extract residue roasted.

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A Study on the Ethanol Concentration by Osmotic Sink Reverse Osmosis Process (Osmotic Sink Reverse Osmosis Process를 이용한 에탄올의 농축특성에 관한 연구)

  • 이광현
    • Proceedings of the Membrane Society of Korea Conference
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    • 1992.04a
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    • pp.1-4
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    • 1992
  • 기존의 일반적인 에탄올 제조법으로는 1) ethylene의 가수분해, 2)전분이나 당분의 발효, 3)acetylene으로부터 얻은 acetaldehyde의 환원반응이 있다. 기존의 화석연로에 의존하지 않고 에탄올을 생성하는 방법은 발효에 의한 방법이다. 발효에 의해 생성되는 에탄올의 농도는 batch식 발효에서 13-14%, 고정화 발효방법에서 5-10%정도이다. 이를 고순도의 에탄올로 농축하기 위한 방법으로는 증류법, 투과증발법, 역삼투법등이 있으며 증류를 이용하여 농축하는 경우에는 상당히 큰 열에너지를 필요로 한다.

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Effects of Polygoni multiflori radix Liquors on the Memory Impairment of Rat (하수오 침출술이 흰쥐의 기억력 손상에 미치는 영향)

  • Kong, Hyun-Joo;Shin, Seung-Ryeul;Hwang, Su-Jung;Lee, Kyung Eun;Jang, Jung-Hyeon;Yang, Kyung-Mi
    • Culinary science and hospitality research
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    • v.22 no.4
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    • pp.128-142
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    • 2016
  • This study was carried out to investigate the effect of memory impairment in rats fed alcohol liquid diets. The rats were randomly divided into 4 groups. While the control(C) group received a diet containing 12% of the daily calories with isocarbohydrate, the other groups received a diet containing 12% of the daily total calories with 36% Soju (A), 25% Cynanchi wilfordii radix liquors (WA), and 25% Polygoni multiflori radix liquors (RA) for 6 weeks. After 6 weeks, ADH activity in the brain tissue of the Group A was found to be significantly lower than Group C but significantly higher than both Groups WA and RA(p<0.05). ADLH activity was revealed to be the highest in the Group WA (p<0.05). The concentration of acetaldehyde, a highly toxic metabolite, was the highest in the Group A, but its concentration decreased significantly if fed a liquid diet containing WA. The concentration of acetylcholine, which has a high correlation with memory impairment, was significantly lower in Group A, although Group RA group was the highest compared to the other groups (p<0.05). AChE activity of the Group A was higher than Group C but lower in Groups WA and RA (p<0.05).