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Separation Processes of Biologically Produced 1,3-Propanediol (1,3-프로판디올의 생물학적 생산을 위한 분리공정)

  • Hong, Yeon-Ki
    • Korean Chemical Engineering Research
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    • v.50 no.5
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    • pp.759-765
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    • 2012
  • As the biodiesel production is increasing rapidly, the crude glycerol, which is principal by-product of biodiesel production, has also been generated in a large amount. Many research studies on value-added utilization of glycerol are under investigation. 1,3-Propandiol is a promising chemical which can be produced from fermentation of glycerol because the application of 1,3-propanediol is mainly in the production of bio-PTT (Poly(trimethylene terephthalate). However, the cost of downstream processes in the biological production of 1,3-propanediol can make a high portion in the total production cost. This review summarizes the present state of separation processes in each step studied for the removal of impurities and the recovery of 1,3-propanediol from its fermentation broth. Furthermore, ATPE (Aqueous Two Phases Extraction) process is suggested as an attractive alternative for the primary separation process of 1,3-propanediol because ATPE is convenient for the simultaneous removal of microbial cells and impurities such as salts of organic acids and the separation of 1,3-propanediol from fermentation broth.

Computer Simulation of Viscoelastic Flow in a Capillary Die for Rubber Compounds (모세관 다이에서 고무 복합체의 점탄성 거동에 대한 컴퓨터 모사)

  • Park, Dong-Myung;Kim, Hok-Joo;Yoon, Jae-Ryong;Lyu, Min-Young
    • Elastomers and Composites
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    • v.41 no.4
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    • pp.223-230
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    • 2006
  • Rubber compounds have a high viscoelastic property. One of the viscoelastic behaviors during profile extrusion is the swelling of extrudate, and the amount of swelling varies with operational conditions in extrusion. It is well recognized that the elastic portion in the viscoelastic property plays an important role in the extrudate swell. In this study computer simulation of the die swell at the capillary die for several rubber compounds has been performed using commercial CFD code, Polyflow. A non-linear differential viscoelastic model, Phan-Thien-Tanner (PTT) model, was used in the computer simulation. Non-isothermal behavior was considered in the calculation. Distribution of pressure, velocity and temperature in the reservoir and capillary die, and extrudate profiles were predicted through the simulation. The amount of the die swell fur the different rubber compounds was investigated for various flow rates and three types of length to diameter of the capillary die. It is concluded that the PTT model successfully represented viscoelastic behavior of rubber compounds.

Synthesis and Characterization of Poly(trimethylene terephthalate) via TPA Process Using Titanium Catalyst

  • Kim, Kap-Jin;Park, Jung-Il;Pio Sifuentes;Lee, Jong-Soon
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.92-92
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    • 2003
  • poly(trimethylene terephthalate) (PTT) was synthesized via condensation polymerization using different molar ratios of 1,3-propane diol (PDO)/terephthalic acid (TPA) in the presence of tetraisopropyl titanate (TiPT) as a polyesterifi-cation catalyst. The effect of reaction conditions on the characteristics of as-polymerized PTT was investigated.

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A Study on the ICS Algorithm by Multi-processing (멀티-프로쎄싱에 의한 ICS 알고리즘의 연구)

  • 조학현;송면규;최조천;김기문
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 1998.11a
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    • pp.389-393
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    • 1998
  • SSB, VHF 등의 장비에 의한 무선통신은 아직도 중요한 정보전달의 수단으로 사용되고 있으며, 무선국으로부터 원거리에 설치되는 장비에 대해서는 전용회선을 사용하여 원격제어로 송ㆍ수신을 행하고 있다. 그러나 무선국에서 다수의 사용자가 다수의 장비에 임으로 접속하고 운용을 해야하는 환경에서는 ICS(Intergrated Communication System:통합통신시스템)의 회선접속 제어기가 요구된다. 본 논문에서는 ICS의 개발을 위하여 ASK(Amplitude Shift Keying) 변조방식에 의한 PTT(Press To Talk) 제어와 신호의 전송회로를 구성하여 실험하였고, 멀티-프로쎄싱에 의한 회선접속 제어기를 설계하여 통합 통신운용에 대한 알고리즘을 연구하였다. Keying에 의하여 m 신호를 단속하였고 지속되는 PTT 신호에 음성신호를 합성시켜 전송시키는 형태의 ASK 변조방식을 취하여 전송되도록 하였고, 회선접속 제어기는 master와 다수의 slave 프로쎄서를 멀티-프로쎄싱의 직렬데이터 전송방식으로 프로쎄서 상호간에 데이타가 전달되도록 구성하였다. 이에 따른 S/W 는 멀티-프로쎄싱의 인터럽트기법을 최대한 활용하여 원하는 회선에 정확히 접속되어 통신이 이루어지도록 설계하였다. 따라서 이 연구는 주파수 자원의 고갈과 통신량의 증가에 대한 대책의 일환으로 저비용의 시설로 재래식 장비의 운용 효율을 증대시키는 기술의 개발에 목적이 있다.

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On the congruence of some network and pom-pom models

  • Tanner, Roger I.
    • Korea-Australia Rheology Journal
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    • v.18 no.1
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    • pp.9-14
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    • 2006
  • We show that some network and pom-pom constitutive models are essentially the same. Instead of the usual confrontation, we suggest that the two approaches can offer useful mutual support: vital information about network destruction rates found from detailed pom-pom calculations can be used to improve the network models, while deductions about network creation rates can pinpoint areas needing further attention in the tube modelling area. A new form of the PTT model, the PTT-X model, results in improved shear and elongational flow descriptions, plus an improved recoil behaviour. The remaining problems of strain-time separation, second normal stress difference description, and reduction of parameters are also discussed and some suggestions for progress are offered.

An Application of Non-linear Viscoelastic Model to Capillary Extrusion of Rubber Compounds (고무복합체의 모세관 압출에서 비선형 점탄성 모델의 적용)

  • Choi, S.H.;Lyu, M.Y.
    • Transactions of Materials Processing
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    • v.16 no.4 s.94
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    • pp.260-265
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    • 2007
  • Rubber compounds have high viscoelastic property. One of the viscoelastic behaviors during profile extrusion is the swelling of extrudate. In this study, die swells of rubber compounds at the capillary die have been investigated through experiment and computer simulation. Experiments and simulations have been performed using fluidity tester and commercial CFD code, Polyflow respectively. Die swells of rubber compounds in a capillary die were predicted using non-linear differential viscoelastic model, Phan-Thien-Tanner(PTT) model for various relaxation times and relaxation modes. The results of simulation were compared with the experiments. Pressure and velocity distribution, and circulation flows at the comer of capillary die have been investigated through computer simulation. It is concluded that the PTT model successfully represented the amount of the die swell of rubber compounds for various relaxation times at different modes.

Estimation of the Variation of Quantity in PWV in Accordance with the Changes of Position in Human (자세변화에 따른 PWV 변화량의 평가)

  • Jun, Suk-Hwan;Jeong, In-Cheol;Jung, Sang-O;Yoon, Hyung-Ro
    • Journal of Biomedical Engineering Research
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    • v.30 no.2
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    • pp.129-134
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    • 2009
  • The ideal method which measures a blood vessel of senility and degree of arteriosclerosis is to measure compliance of arterial and condition of blood circulation at the periphery. In these days vascular stiffness have been assessed by analyzing PTT (pulse transit time) from ECG and PPG. PTT is that between toe and finger each subject estimated through ECG and PPG signals. Two parameters, which are related to PWV, were tested with the time delay between the finger and toe. PWV is a variation of quantity which is associated with vascular stiffness. These researches which use PTT and PWV don't consider the blood vessel characteristic of an individual. In this current research, we have used with the blood vessel characteristic of an individual. That is an assessment of vascular stiffness using the variation of quantity in PWV with the changes of position in the subject. PWV variation increased as functions of the subject's age. The increase of the PWV variation parameters with age is attributed to the direct decrease of the blood vessel compliance with different position. The quantity of variation estimated by experimental results is that old age's (75.78${\pm}$7.75) case is 113.68% and young age's (26.47${\pm}$2.04) case is 85.69%. We proved and presented about estimation of vascular stiffness of possibility by this result.

Development of "Bt-Plus" Biopesticide Using Entomopathogenic Bacterial (Xenorhabdus nematophila, Photorhabdus temperata ssp. temperata) Metabolites (곤충병원세균(Xenorhabdus nematophila, Photorhabdus temperata ssp. temperata)의 대사물질을 이용한 "비티플러스" 생물농약 개발)

  • Seo, Sam-Yeol;Kim, Yong-Gyun
    • Korean journal of applied entomology
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    • v.50 no.3
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    • pp.171-178
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    • 2011
  • Bacillus thuringiensis (Bt) is a bacterial biopesticide against insect pests, mainly lepidopterans. Spodoptera exigua and Plutella xylostella exhibit significant decreases in Bt susceptibility in late larval instars. To enhance Bt pathogenicity, we used a mixture treatment of Bt and other bacterial metabolites which possessed significant immunosuppressive activities. Mixtures of Bt with culture broths of Xenorhabdus nematophila (Xn) or Photorhabdus temperata ssp. temperata (Ptt) significantly enhanced the Bt pathogenicity against late larval instars. Different ratios of Bt to bacterial culture broth had significant pathogenicities against last instar P. xylostella and S. exigua. Five compounds identified from the bacterial culture broth also enhanced Bt pathogenicity. After determining the optimal ratios, the mixture was applied to cabbage infested by late instar P. xylostella or S. exigua in greenhouse conditions. A mixture of Bt and Xn culture broth killed 100% of both insect pests when it was sprayed twice, while Bt alone killed less than 80% or 60% of P. xylostella and S. exigua, respectively. Other Bt mixtures, including Ptt culture broth or bacterial metabolites, also significantly increased pathogenicity in the semi-field assays. These results demonstrated that the Bt mixtures collectively names "Bt-Plus" can be developed into potent biopesticides to increase the efficacy of Bt.

Occurrence of the Onion Moth, Acrolepiopsis sapporensis, in the Welsh Onion Farms and its Treatment Using 'BtPlus' (대파 재배지 파좀나방(Acrolepiopsis sapporensis) 발생 현황과 '비티플러스' 처리 효과)

  • Md Tafim Hossain Hrithik;Gahyeon Jin;Yonggyun Kim
    • Korean journal of applied entomology
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    • v.62 no.4
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    • pp.277-285
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    • 2023
  • The onion moth, Acrolepiopsis sapporensis, was monitored in the farms cultivating the welsh onion, Allium fistulosum, using sex pheromone from transplantation to harvest. Two occurrence peaks were observed at early June and late July after the overwintering population. However, the population sizes were varied among different years and the cultivating environments. To effectively control A. sapporensis with microbial pesticides, different Bacillus thuringiensis strains were screened to select B. thuringiensis kurstaki (BtK). To enhance the insecticidal virulence of BtK, the culture broth of Photorhabdus temperata temperata (Ptt) was added to the BtK. This mixture of two entomopathogenic bacteria was called 'BtPlus', which was superior to BtK alone in the insecticidal virulence. The enhanced virulence was explained by the immunosuppressive activity of the secondary metabolites contained in the Ptt extract. The metabolites inhibited both cellular and humoral immune responses of A. sapporensis, resulting in the enhanced virulence of BtK. These results suggest that A. sapporensis occurs in the welsh onion fields and the resulting economic damage would be effectively prevented by BtPlus application.

Effect of Nd:YAG Laser Irradiation to Mental Region for Sensory Nerve Conduction Change (하악 이공부에 조사된 Nd:YAG 레이저가 감각신경전도변화에 미치는 영향)

  • Jeon, Jae-Woo;Kim, Kyoung-Hee;Ko, Myong-Yun;Ahn, Yong-Woo;Park, Jun-Sang
    • Journal of Oral Medicine and Pain
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    • v.30 no.4
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    • pp.447-455
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    • 2005
  • The purpose of this study was to examine the effect of Nd:YAG laser irradiation for sensory nerve conduction change. Nd:YAG laser was irradiated to mental region for 5 minutes with the parameters that 10 Hz and 20 Hz of 100 mJ/pulse. Target size of irradiation was 30 mm diameter of circle and target-tip distance was about 10 mm. Therefore, the power density were 212 $mW/cm^2$ and 424 $mW/cm^2$. Sensory nerve conduction was evaluated with $Neurometer^{\circled}$ CPT/C before and after Nd:YAG laser irradiation. As an outcomes, the current perception threshold(CPT) and pain tolerance threshold(PTT) were obtained. We made a comparison of these two values and the results were as follows. 1. There was no significant difference in CPT at 1W, 10 Hz and 2 W, 20 Hz Nd:YAG laser irradiation. 2. There was no significant difference in PTT at 10 Hz, 20 Hz of 100 mJ/pulse Nd:YAG laser. 3. There were no significant differences in CPT and PTT between 1 W, 10 Hz group and 2 W, 20 Hz group. Therefore, We can make a conclusion that Nd:YAG laser irradiation to mental region have no effect on mental nerve conduction in our study model.