• Title/Summary/Keyword: a two-layer structure

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Binder-free and Full Electrical-Addressing Free-standing Nanosheets with Carbon Nanotube Fabrics for Electrochemical Applications

  • Lee, Tae-Il;JeGal, Jong-Pil;Choe, Ji-Hyeok;Choe, Won-Jin;Lee, Min-Jeong;O, Jin-Yeong;Kim, Gwang-Beom;Baek, Hong-Gu;Xia, Younan;Myeong, Jae-Min
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.40.2-40.2
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    • 2011
  • As the old saying 'nothing is complete unless you put it in final shape', although nanosheets (NSs) are a promising functional building block for various electrochemical applications, their true value cannot be realized until they are well woven into electrical conducting materials. As an effort to determine their ideal shape, in this study, a unique manufacturing route to build a layer-by-layer (LBL) structure of two-dimensionally ordered, free-standing ${\beta}$-nickel hydroxide nanosheets (${\beta}$-NHNSs) that are fully electrically addressed with single-wall carbon nanotube fabrics was demonstrated, and its capabilities were verified through a comparative study on the differences between a simple bulky and LBL-structured electrochemical cathode, representing two extreme cases. The LBL-structured cathode showed a discharging current peak that was 25 times larger than the bulky structured one measured in cyclic voltammetry, which implies that the LBL structure is near an ideal electrode configuration for NS-based electrochemical applications.

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Efficient Organic Light-emitting Diodes using Hole-injection Buffer Layer

  • Chung, Dong-Hoe;Kim, Sang-Keol;Lee, Joon-Yng;Hong, Jin-Woong;Cho, Hyun-Nam;Kim, Young-Sik;Kim, Tae-Wan
    • Journal of Information Display
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    • v.4 no.1
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    • pp.29-33
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    • 2003
  • We have investigated the effects of hole-injection buffer layer in organic light-emitting diodes using copper phthalocyanine (CuPc), poly(vinylcarbazole)(PVK), and Poly(3,4-ethylene dioxythiophene):poly(styrenesulfonate) (PEDOT: PSS) in a device structure of $ITO/bufferr/TPD/Alq_3/Al$. Polymer PVK and PEDOT:PSS buffer layer were produced using the spin casting method where as the CuPc layer was produced using thermal evaporation. Current-voltage characteristics, luminance-voltage characteristics and efficiency of device were measured at room temperature at various a thickness of the buffer layer. We observed an improvement in the external quantum efficiency by a factor of two, four, and two and half when the CuPc, PVK, and PEDOT:PSS buffer layer were used, respectively. The enhancement of the efficiency is assumed to be attributed to the improved balance of holes and elelctrons resulting from the use of hole-injection buffer layer. The CuPc and PEDOT:PSS layer function as a hole-injection supporter and the PVK layer as a hole-blocking one.

Dual - Drive & - Emission Panel

  • Miyashita, Takuya;Naka, Shigeki;Okada, Hiroyuki;Onnagawa, Hiroyoshi
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.707-710
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    • 2004
  • We have proposed on dual-drive & -emission (DDE) panel based on organic light-emitting diodes (OLEDs). The device is composed on independent operation of two OLED structures with two transparent electrodes for data signals and an intermediate reflective electrode for common scan signal. Typical device structure is ITO / organic electroluminescent layer (1) /intermediate reflective electrode / organic electroluminescent layer (2) /transparent electrode. Symmetric bright emission could be obtained by applying AlNd as the intermediate reflective electrode and $MoO_3$ as a hole injection layer for upper device structure. The proposed panel is useful for emissive face-to-face panel exhibited for different images.

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Modified AES having same structure in encryption and decryption (암호와 복호가 동일한 변형 AES)

  • Cho, Gyeong-Yeon;Song, Hong-Bok
    • Journal of Korea Society of Industrial Information Systems
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    • v.15 no.2
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    • pp.1-9
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    • 2010
  • Feistel and SPN are the two main structures in a block cipher. Feistel is a symmetric structure which has the same structure in encryption and decryption, but SPN is not a symmetric structure. In this paper, we propose a SPN which has a symmetric structure in encryption and decryption. The whole operations of proposed algorithm are composed of the even numbers of N rounds where the first half of them, 1 to N/2 round, applies a right function and the last half of them, (N+1)/2 to N round, employs an inverse function. And a symmetry layer is located in between the right function layer and the inverse function layer. In this paper, AES encryption and decryption function are selected for the right function and the inverse function, respectively. The symmetric layer is composed with simple matrix and round key addition. Due to the simplicity of the symmetric SPN structure in hardware implementation, the proposed modified AES is believed to construct a safe and efficient cipher in Smart Card and RFID environments where electronic chips are built in.

Comparisons of smart damping treatments based on FEM modeling of electromechanical impedance

  • Providakis, C.P.;Kontoni, D.P.N.;Voutetaki, M.E.;Stavroulaki, M.E.
    • Smart Structures and Systems
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    • v.4 no.1
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    • pp.35-46
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    • 2008
  • In this paper the authors address the problem of comparing two different smart damping techniques using the numerical modelling of the electro-mechanical impedance for plate structures partially treated with active constrained layer damping treatments. The paper summarizes the modelling procedures including a finite element formulation capable of accounting for the observed behaviour. The example used is a smart cantilever plate structure containing a viscoelastic material (VEM) layer sandwiched between a piezoelectric constrained layer and the host vibrating plate. Comparisons are made between active constrained layer and active damping only and based on the resonance frequency amplitudes of the electrical admittance numerically evaluated at the surface of the piezoelectric model of the vibrating structure.

Effect of External Acoustic Excitation on Wake behind a Circular Cylinder (외부 음향여기가 원주 후류 유동에 미치는 효과에 관한 연구)

  • Choi, Jae-Ho;Lee, Sang-Joon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.5
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    • pp.603-609
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    • 1999
  • The effect of an external acoustic excitation on the wake structure behind a circular cylinder was experimentally investigated. The sound wave was excited in the frequency range of the shear layer instability and two sound pressure levels of 114 and 120dB were used in this study. As a result, the acoustic excitation modified the wake structure by increasing the velocity fluctuation energy without changing the vortex shedding frequency. The acoustic excitation enhanced the vortex shedding process and promoted the shear layer instability. Consequently, the acoustic excitation reduced the length of the vortex formation region and decreased the base pressure. In addition, the vortex strength of vortices was increased and the width of the wake was spread out due to the acoustic excitation. When the excitation frequency was identical to the shear layer instability frequency, the effect of the external flow control on the cylinder wake was maximized. In addition, with increasing the sound pressure level, the effect of the external acoustic excitation on the wake structure increased.

Effect of organic solvents on catalyst structure of PEM fuel cell electrode fabricated via electrospray deposition

  • Koh, Bum-Soo;Yi, Sung-Chul
    • Journal of Ceramic Processing Research
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    • v.18 no.11
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    • pp.810-814
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    • 2017
  • Proton exchange membrane fuel cells (PEMFCs) are some of the most efficient electrochemical energy sources for transportation applications because of their clean, green, and high efficiency characteristics. The optimization of catalyst layer morphology is considered a feasible approach to achieve high performance of PEMFC membrane electrode assembly (MEA). In this work, we studied the effect of the solvent on the catalyst layer of PEMFC MEAs fabricated using the electrostatic spray deposition method. The catalyst ink comprised of Pt/C, a Nafion ionomer, and a solvent. Two types of solvent were used: isopropyl alcohol (IPA) and dimethylformamide (DMF). Compared with the catalyst layer prepared using IPA-based ink, the catalyst layer prepared with DMF-based ink had a dense structure because the DMF dispersed the Pt/C-Nafion agglomerates smaller and more homogeneously. The size distribution of the agglomerates in catalyst ink was confirmed through Dynamic Light Scattering (DLS) and the microstructure of the catalyst layer was compared using field emission scanning electron microscopy (FE-SEM). In addition, the electrochemical investigation was performed to evaluate the solvent effect on the fuel cell performance. The catalyst layer prepared with DMF-based ink significantly enhanced the cell performance (1.2 A cm-2 at 0.5 V) compared with that fabricated using IPA-based ink (0.5 A cm-2 at 0.5 V) due to the better dispersion and uniform agglomeration on the catalyst layer.

A Study on The Bending Characteristic of Sandwich Sheet Metal with Dimple Type-Inner-Structure (딤플형 내부구조재를 갖는 접합판재의 굽힘 특성연구)

  • Kim, H.G.;Oh, S.K.;Yoo, J.S.;Seong, D.Y.;Chung, W.J.;Kim, J.H.
    • 한국금형공학회:학술대회논문집
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    • 2008.06a
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    • pp.31-34
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    • 2008
  • The L-bending of inner-structure bonded sandwich sheet metal is examined to reduce springback and defects of bent parts. The specimen is composed of top and bottom layers and a middle layer with dimple type-inner-structure and each layer is bonded by resistance welding. This specimen with hollow type-inner-structure shows different bending characteristics from the conventional sandwich sheet metals with solid type-inner-structure. The experiments were conducted for two kinds of working conditions, that is, clearance and movement of first bent specimen for second bending. The deformed profile, bend angle and springback were investigated and compared and then the proper working conditions for L-bending of sandwich sheet metal were prosed.

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Microstructure and wear performance of WC-6.5%Co cladding layer by electric resistance welding (저항 클래딩법에 의해 형성된 내마모성 WC-6.5Co 클래딩층의 미크로조직 및 내마모성능)

  • Lee, Jin-U;Bae, Myeong-Il;Kim, Sang-Jin;Lee, Yeong-Ho
    • Proceedings of the KWS Conference
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    • 2006.10a
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    • pp.120-122
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    • 2006
  • This study deals with characterizations of microstructure and wear performance of a cladding layer, product on 1.9 mm-thick mild steel plate by the electric resistance welding, of composite metal powder of Coarse WC-6.5%Co and high carbon alloy(SHA). The cladding layer was examined and tested fur microstructural features, chemical composition, hardness, wear performance and wear mechanism. The cladding layer have two different matrix were observed by an optical microscope and EPMA. The one was the coarse WC-6.5Co structure. The other was the melted SHA with surrounding the WC-6.5Co structure. The hardness of WC-6.5Co was 1210HV. The hardness of SHA was 640HV. In comparison by wear rate, the cladding layer showed the remarkable wear performance that was 15 times of SM490 and about 62% of D2.

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A Study on the Optical and Electrical Properties of the White-light-emitting Organic LED with Two-wavelength using DPVBi/Rubrene Structure (DPVBi/Rubrene 구조를 사용한 2-파장 방식의 백색유기발광소자의 광학적ㆍ전기적 특성에 관한 연구)

  • 오환술;조재영;최성진;강명구;윤석범
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.2
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    • pp.217-222
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    • 2004
  • The white-light-emitting organic LED(OLED) with two-wavelength was fabricated using the DPVBi of blue emitting material and a series of orange color fluorescent dye(Rubrene) by vacuum evaporation processes. The basic structure of white-light-emitting OLED was ITO/NPB(150$\AA$)/DPVBi/Rubrene/BCP(100$\AA$)/Alq$_3$(150$\AA$)/Al(600$\AA$). We analyzed the fabricated device through the changes of the DPVBi and Rubrene layer's thickness. We obtained the white-light-emitting OLED with white color light and the CIE coordinate of the device was (0.29, 0.33) at applied voltage of 13V when the thickness of DPVBi layer was 210$\AA$ and the thickness of Rubrene layer was 180$\AA$. At a current of 100㎃/$\textrm{cm}^2$, the quantum efficiency was 0.35% and at a voltage of 20V, it was 0.405%.