• 한국재료학회:학술대회논문집
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• 한국재료학회 2007년도 추계학술발표대회 및
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• pp.75.1-75.1
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• 2007

• 한국세라믹학회지
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• 제28권2호
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• pp.146-152
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• 1991

Ultra fine and homogeneous (Ni0.4Zn0.6)Fe2O4 ferrite powders were prepared by direct-wet, Hydrothermal and coprecipitation methods. In case that specific surface areas of Ni-Zn ferrite powders were over 220㎡/g, 100㎡/g, 30㎡/g individually direct-wet, hydrothermal and coprecipitation methods. The Ni-Zn ferrite magnetic fluids of which Solvents were benzene or kerosene was prepared by making cation surfactant adsorbed on the surface of the (Ni0.4Zn0.6)Fe2O4. The results that measured dispersion and viscosity by making cation surfactant adsorbed were as follows. 1. The adsorption amount of Oleric acid be proportioned the specific surface area of powders. 2. The maximum amount of Oleric acid was 36wt% of dried powders which has 220㎡/g of specific surface area. 3. The stability of fluid by direct-wet synthesis emthod in benzene or kerosene solvent excellent.

• 한국세라믹학회지
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• 제35권8호
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• pp.843-849
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• 1998

Fine powders of Mn-Zn ferrite were prepared by the alcoholic dehydration method and densification beha-vior of synthesized powder was investigated. The concentration and pH of solution for optimal precipitation was 0.4M and 2.5 respectively. The spinel single phase metastable state was formed by thermal decom-position of precipitate and then spinel phase was disintegrated into hematite and spinel {{{{ { { ZnFe}_{2 }O }_{4 } }} at 600$^{\circ}C$ With increase of temperature reaction of solid solution between hematite and spinel was proceeded and resulted in the spinel single phase (Mn, Zn Fe){{{{ { {Fe }_{2 }O }_{4 } }} On account of high reactivity of uncalcined powders densification started at 200$^{\circ}C$ lower and completed at 50$^{\circ}C$ lower in comparison with calcined powders.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1993년도 정기총회 및 추계학술대회 논문집 학회본부
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• pp.222-224
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• 1993

In this paper, The optimum oxidation conditions for the formation of Cu-Zn ferrite were investigated using precipitates obtained by the mixture of $CuCl_2{\cdot}2H_2O$, $ ZnCl_2$, $FeCl_3{\cdot}6H_2O$ and NaOH. The precipitates were prepared by coprecipitation method on various temperatures and oxidation conditions. The oxidation products were examined by SEM, XRD, and VSM. The particles obtained at 70($^{\circ}C$) were more spherical and fine than that of prepared at 25($^{\circ}C$), 50($^{\circ}C$), 60($^{\circ}C$), respectively. By $H_2O_2$ oxidation, the saturation magnetization of the powders was little influenced, But, by air oxidation the saturation magnetization of the powders was influenced intricately. According to our experimental data, the saturation magnetization of the powders increased with reaction time and was saturated at 9 hours.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.971-972
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• 2006

Mechanochemical synthesis of zinc ferrite, $ZnFe_2O_4$, was attempted from a powder mixture of iron (III) oxide, alpha-$Fe_2O_3$ and zinc (II) oxide, ZnO. Nanocrystalline zinc ferrite, $ZnFe_2O_4$ powders were successfully synthesized only bymilling for 30 hours. Evidence of the $ZnFe_2O_4$ formation was absent for the powders milled for 10 and 20 hours; the milling lowered the crystallinity of the starting materials. Heating after milling enhanced the formation of $ZnFe_2O_4$, crystal growth of $ZnFe_2O_4$ and the unreacted starting materials. The unreacted starting materials decreased their amounts by heating at higher temperatures.

• 한국재료학회지
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• 제22권11호
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• pp.575-580
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• 2012

The purpose of this study is to investigate the crystalline structure and optical properties of (GaZn)(NO) powders prepared by solid-state reaction between GaOOH and ZnO mixture under $NH_3$ gas flow. While ammoniation of the GaOOH and ZnO mixture successfully produces the single phase of (GaZn)(NO) solid solution within a GaOOH rich composition of under 50 mol% of ZnO content, this process also produces a powder with coexisting (GaZn)(NO) and ZnO in a ZnO rich composition over 50 mol%. The GaOOH in the starting material was phase-transformed to ${\alpha}$-, ${\beta}-Ga_2O_3$ in the $NH_3$ environment; it was then reacted with ZnO to produce $ZnGa_2O_4$. Finally, the exchange reaction between nitrogen and oxygen atoms at the $ZnGa_2O_4$ powder surface forms a (GaZn)(NO) solid solution. Photoluminescence spectra from the (GaZn)(NO) solid solution consisted of oxygen-related red-emission bands and yellow-, green- and blue-emission bands from the Zn acceptor energy levels in the energy bandgap of the (GaZn)(NO) solid solutions.

• 한국세라믹학회지
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• 제40권5호
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• pp.441-446
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• 2003

ZnO 미세 분말을 sol-gel법으로 제조하였다. Gel분말의 형상은 하소 열 처리 온도에 따라 판상, 침상,그리고 구형으로 변화하였고, $700^{\circ}C$ 이하 하소 온도에서는 온도에 따른 입자 성장 속도가 낮았지만, $700^{\circ}C$ 이상의 온도부터 급격한 입자 성장 속도를 나타내었다. 입자 사이즈가 커질수록 결정화 정도는 더 커졌고, gel분말의 유기 화합물들은 30$0^{\circ}C$ 이하 온도에서 휘발되었다. 열 처리 온도에 따른 ZnO 분말은 S자형(sigmoidal shape)의 전기전도성 거동을 보였고, gel분말의 열처리 온도가 감소할수록 일정한 전도성이 일정한 온도 구간이 좁게(narrow) 나타났다. 최적의 CO 기체 센싱 특성은 50$0^{\circ}C$의 하소 열처리한 시편에서 나타났고, 열처리 온도가 올라갈수록 센싱 특성은 감소하였다.

• Journal of Magnetics
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• 제10권3호
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• pp.84-88
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• 2005

Nanoparticles $Ni_{0.7}Zn_{0.3}Fe_2O_4$ is fabricated by a sol-gel method. The magnetic and structural properties of powders were investigated with XRD, SEM, $M\ddot{o}ssbauer$ spectroscopy, and VSM. $Ni_{0.7}Zn_{0.3}Fe_2O_4$ powders annealed at $300^{\circ}C$ have a spinel structure and behaved superparamagnetically. The estimated size of $Ni_{0.7}Zn_{0.3}Fe_2O_4$ nanoparticle is about 11 nm. $Ni_{0.7}Zn_{0.3}Fe_2O_4$ annealed at 400 and $500^{\circ}C$ has a typical spinel structure and is ferrimagnetic in nature. The isomer shifts indicate that the iron ions were ferric at the tetrahedral (A) and the octahedral (B). Blocking temperature $(T_B)\;of\;Ni_{0.7}Zn_{0.3}Fe_2O_4$ nanoparticle is about 260 K. The magnetic anisotropy constant of $Ni_{0.7}Zn_{0.3}Fe_2O_4$ annealed $300^{\circ}C$ were calculated to be $1.7X10^6\;ergs/cm^3$. Also, temperature of the sample increased up to $43^{\circ}C$ within 7 minutes under AC magnetic field of 7 MHz.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2002년도 추계학술대회 논문집 전기물성,응용부문
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• pp.97-98
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• 2002

$Ga_2O_3$ nanobelts were synthesized from mechanically ground GaN powders with a thermal annealing in a nitrogen atmosphere. The nanobelts are with the range of about $10{\sim}200nm$ width and $10{\sim}50nm$ thickness. Three different ZnO nanomaterials (nanobelts, nanorods, and nanowires) were synthesized at three different substrate temperatures from the thermal evaporation of ball-milled ZnO powders at $1380^{\circ}C$. In cathodoluminescence(CL), the peak energy of near band-edge(NBE) emission was determined for nanobelts, nanorods, and nanowires.

• 한국재료학회지
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• 제23권4호
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• pp.211-214
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• 2013

The effects of a Ni coating on the sensing properties of nano ZnO:Ni based gas sensors were studied for $CH_4$ and $CH_3CH_2CH_3$ gases. Nano ZnO sensing materials were prepared by the hydrothermal reaction method. The Ni coatings on the nano ZnO surface were deposited by the hydrolysis of zinc chloride with $NH_4OH$. The weight % of Ni coating on the ZnO surface ranged from 0 to 10 %. The nano ZnO:Ni gas sensors were fabricated by a screen printing method on alumina substrates. The structural and morphological properties of the nano ZnO : Ni sensing materials were investigated by XRD, EDS, and SEM. The XRD patterns showed that nano ZnO : Ni powders with a wurtzite structure were grown with (1 0 0), (0 0 2), and (1 0 1) dominant peaks. The particle size of nano ZnO powders was about 250 nm. The sensitivity of nano ZnO:Ni based sensors for 5 ppm $CH_4$ gas and $CH_3CH_2CH_3$ gas was measured at room temperature by comparing the resistance in air with that in target gases. The highest sensitivity of the ZnO:Ni sensor to $CH_4$ gas and $CH_3CH_2CH_3$ gas was observed at Ni 4 wt%. The response and recovery times of 4 wt% Ni coated ZnO:Ni gas sensors were 14 s and 15 s, respectively.