• Title/Summary/Keyword: ZnO Nanoparticles

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Bioassessment of Heavy Metals, Nanoparticles, and Soils Contaminated with Metals using Various Bioassays (다양한 독성법을 이용한 중금속, 나노입자 및 금속오염 토양 평가)

  • Kong, In Chul;Shi, Yu Tal;Lee, Min Kyung;Kang, Il Mo
    • Economic and Environmental Geology
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    • v.48 no.3
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    • pp.261-271
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    • 2015
  • Toxicity results of metals, nanoparticles (NPs), and soils contaminated with metals were introduced on this review. Following methods were used: seed germination, bioluminescence, enzyme activity, and mutation. In general, different sensitivities were observed, depending on types of bioassays and pollutants. Among tested seeds, sensitivities of Lactucus and Raphanus were greater than others. Of single metal exposure, effect by As(III) was greater than others, and high revertant mutation ratio (5.1) was observed at 1 mg/L arsenite, indicating high mutagenicity. No general pattern was observed on the effect of metal mixture, but synergistic effect was observed with seeds. In case of soils, no correlation was observed between total metal contents and toxicity. Toxicity of NPs was observed as follows: CuO > ZnO > NiO > $TiO_2$, $Fe_2O_3$, $Co_3O_4$. Especially, no considerable effects were observed by $TiO_2$, $Fe_2O_3$, and $Co_3O_4$ under tested concentration (max. 1,000 mg/L). The evaluation results of interactive toxic effects using various bioassays may comprise a useful tool for the bioassessment of various environmental pollutants.

Preparation of Nitrogen-doped Carbon Nanowire Arrays by Carbonization of Mussel-inspired Polydopamine

  • Oh, Youngseok;Lee, Jea Uk;Lee, Wonoh
    • Composites Research
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    • v.29 no.4
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    • pp.132-137
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    • 2016
  • Based on mussel-inspired polydopamine (PDA), a novel technique to fabricate carbon nanowire (CNW) arrays is presented for a possible use of porous carbon electrode in electrochemical energy storage applications. PDA can give more porosity and nitrogen-doping effect to carbon electrodes, since it has high graphitic carbon yield characteristic and rich amine functionalities. Using such outstanding properties, the applicability of PDA for electrochemical energy storage devices was investigated. To achieve this, the decoration of the CNW arrays on carbon fiber surface was performed to increase the surface area for storage of electrical charge and the chemical active sites. Here, zinc oxide (ZnO) nanowire (NW) arrays were hydrothermally grown on the carbon fiber surface and then, PDA was coated on ZnO NWs. Finally, high temperature annealing was performed to carbonize PDA coating layers. For higher energy density, manganese oxide ($MnO_x$) nanoparticles (NPs), were deposited on the carbonized PDA NW arrays. The enlarged surface area induced by carbon nanowire arrays led to a 4.7-fold enhancement in areal capacitance compared to that of bare carbon fibers. The capacitance of nanowire-decorated electrodes reached up to $105.7mF/cm^2$, which is 59 times higher than that of pristine carbon fibers.

Anti-parasitic activity of zinc oxide nanoparticles against Eimeria tenella in broilers experimentally infected

  • Sadiya Aziz Anah;Saad Aziz Anah;Khadeeja Abees Hmood Al-Khalidy
    • Korean Journal of Veterinary Research
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    • v.62 no.4
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    • pp.30.1-30.6
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    • 2022
  • In the study, zinc oxide nanoparticles (ZNOPs) at concentrations of 20, 40, and 60 mg/kg were tested for their antimicrobial action against the oocysts of Eimeria tenella. The oocysts of E. tenella were isolated from the feces of broilers received at the veterinary hospital in Diwaniyah Province and initially diagnosed by compound optical microscopy. The oocysts were confirmed molecularly by polymerase chain reaction targeting the ITS1 gene with a molecular weight of 409 bp. The results in the first week showed that ZNOP concentrations of 20 and 40 mg/kg possess various activities against E. tenella, while 60 mg/kg was the most effective in reducing excreted oocysts compared to the positive control and amprolium group, along with the appearance of mild symptoms and a mortality rate of 0.8%. In the second week of infection, excreted oocysts and mortality rates generally decreased in all treated groups. A comparison of all groups showed that the 60 mg/kg ZNOP-treated group had a significantly lower number of excreted oocysts, and all birds in this group recovered during the second week of infection. These findings revealed the prospect of using ZNOPs against E. tenella in challenging situations of the appearance of resistance to anticoccidial agents.

Gas phase synthesis of Ga2O3 nanoparticles from gallium metal (기상합성법을 이용한 산화갈륨 나노분말의 제조)

  • Park, Jung Won;Won, Chang Min;Kwon, Jun Beom;Lee, Hyukjae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.6
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    • pp.220-225
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    • 2020
  • Gallium oxide nano-powder, the key starting material for IGZO target, is fabricated by gas phase synthesis using a new apparatus consist of reaction, transportation, and collection parts. As a result of gallium metal evaporation above 1150℃, Ga2O3 nano-powders, are successfully synthesized. The SEM images of the synthesized powders displace the spherical shaped powders without severe agglomeration. X-ray diffraction and PSA analysis show that the higher temperature at the reaction part results in the better crystallinity and larger powder size of the synthesized Ga2O3. To see the applicability to IGZO target, Ga2O3 nano-powders synthesized at 1250℃ are mixed with indium oxide and zinc oxide (In2O3 : Ga2O3 : ZnO = 1 : 1 : 1), and then sintered at 1400~1500℃. The highest sintered density of 5.83 g/㎤ (= 91 % of relative density) is achieved when sintered at 1450℃, showing better sinterability compared to the commercially available Ga2O3 powder, which has 5.61 g/㎤ of sintered density at the same condition.

FA/Mel@ZnO nanoparticles as drug self-delivery systems for RPE protection against oxidative stress

  • Yi, Caixia;Yu, Zhihai;Sun, Xin;Zheng, Xi;Yang, Shuangya;Liu, Hengchuan;Song, Yi;Huang, Xiao
    • Advances in nano research
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    • v.13 no.1
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    • pp.87-96
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    • 2022
  • Drug self-delivery systems can easily realize combination drug therapy and avoid carrier-induced toxicity and immunogenicity because they do not need non-therapeutic carrier materials. So, designing appropriate drug self-delivery systems for specific diseases can settle most of the problems existing in traditional drug delivery systems. Retinal pigment epithelium is very important for the homeostasis of retina. However, it is vulnerable to oxidative damage and difficult to repair. Worse still, the antioxidants can hardly reach the retina by non-invasive administration routes due to the ocular barriers. Herein, the targeted group (folic acid) and antioxidant (melatonin) have been grafted on the surface of ZnO quantum dots to fabricate a new kind of drug self-delivery systems as a protectant via eyedrops. In this study, the negative nanoparticles with size ranging in 4~6 nm were successfully synthesized. They could easily and precisely deliver drugs to retinal pigment epithelium via eyedrops. And they realized acid degradation to controlled release of melatonin and zinc in retinal pigment epithelium cells. Consequently, the structure of retinal pigment epithelium cells were stabilized according to the expression of ZO-1 and β-catenin. Moreover, the antioxidant capacity of retinal pigment epithelium were enhanced both in health mice and photic injury mice. Therefore, such new drug self-delivery systems have great potential both in prevention and treatment of oxidative damage induced retinal diseases.

A Study on the Fire Resistance Performance of Mortars Using Mesoporous Silica Nanoparticles(MSNs) and PVA Fibers (다공성 나노실리카 입자(MSNs)와 PVA섬유를 혼입한 모르타르의 내화성능에 관한 연구)

  • Cheonpyo Park;Jakyung Lee;Taehyung Kim
    • Journal of the Korean Geosynthetics Society
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    • v.22 no.4
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    • pp.51-61
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    • 2023
  • In this study, in order to improve the fire resistance performance of structures in case of fire in buildings and structures, PVA fibers and the ZnO particles combined with mesoporous nano silica (MSNs) were mixed with cement mortar, and the specimen was exposed to a temperature range of 20~1100℃. Then the residual compressive strength and weight change rate were measured to determine whether the fire resistance performance changed. As a result of the study, it was found that mixing mesoporous nano silica and PVA fiber together did not contribute to improving the fire resistance performance of cement mortar. On the other hand, mixing 0.5% of mesoporous nano silica and 0.1 vol% of PVA fiber showed the best improvement test results, showing that it was advantageous for fire resistance performance.

The Magnetic Properties with the Variation of Sintering Temperature and Microwave Absorbing Characteristics of NiCoZn Ferrite Composite Prepared by Co-precipitation Method (공침법으로 제조한 NiCoZn Ferrite의 조성 및 소결온도에 따른 자기적 특성 및 전파흡수특성)

  • Kim, Moon-Suk;Min, Eui-Hong;Koh, Jae-Gui
    • Journal of the Korean Magnetics Society
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    • v.18 no.3
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    • pp.120-125
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    • 2008
  • In this study, NiCoZn ferrites with the variation of sintering temperature and chemical composition were prepared by the coprecipitation. Microstructures Crystal structure of NiCoZn ferrites were analyzed by XRD and their electric magnetic characteristics were analyzed by LCR meter and their morphology observed by SEM. We identified that these powders have a typical NiCoZn spinel structure and nanoparticles average size of 40 nm. The impurity, the initial permeability and the Q factor value are the lowest of sintered NiCoZn ferrite at $1250^{\circ}C$. Also, we measured S-parameter for $(Ni_{0.4}Co_{0.1}Zn_{0.5})Fe_2O_4$ which showed a maximum reflection loss of -3.1 dB at 6 GHz for the 2 mm thick sample. From this result, we found that the NiCoZn ferrite can be used in ferrite microwave-absorbing application at a higher frequency region (> 6 GHz).