• Title/Summary/Keyword: Zn-Cr

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Effects of Heavy Metals Cr, Ni, Cd, Cu, Zn on Growth of Radish and Chinese Cabbage in Soils (토양중(土壤中)에 있어서 무우와 배추의 생육(生育)에 미치는 중금속(重金屬) Cr, Ni, Cd, Cu, Zn의 영향(影響))

  • Moon, Young-Hee;Kim, Yong-Hwi;Ryang, Hwan-Seung
    • Korean Journal of Environmental Agriculture
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    • v.9 no.2
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    • pp.113-119
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    • 1990
  • The germination and growth of radish and chiness cabbage in soils treated with Cr, Ni, Cd, Cu, and Zn at 20, 50, 100 and 200 ppm were determined. The germination of radish and chiness cabbage in soils was greatly affected by addition of Ni and Cr at 200 ppm, but almost not at all by treatment with Cd, Cu, and Zn even 200 ppm. The injury to the growth of crops was generally the highest with Cr, followed by Ni, Cd, Cu, and Zn, and more with chiness cabbage with radish. Serious crop injury appeared at 20 ppm of Cr, 50 ppm of Ni, Cd and Cu, and 200 ppm of Zn on radish, and at 20 ppm of Cr, Ni, Cd and Cu, and 200ppm of Zn of chiness cabbage. However, crop inhibition decreased greatly with addition of compost and lime.

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A Study on the Properties of the Zn-Cr Alloy Films by Evaporation (진공증착법으로 제조된 Zn-Cr박막의 특성에 관한 연구)

  • Ju, Bong-Hwan;Lee, Gyu-Hwan;Gwon, Sik-Cheol;Baek, Un-Seung
    • 연구논문집
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    • s.23
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    • pp.109-120
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    • 1993
  • A study on corrosion and adhesion properties of evaporated Zn-Cr films were conducted on steel strip by two-source evaporater. Corrosion resistance of Zn-Cr coated steel was evaluated by salt spray test in 5% NaCl. Adhesion property of Zn-Cr films on steel substrate was evaluated by tape test after $180^\circC$ bending. Adhesion was improved with increasing the Cr content and reached the maximum at the Cr content of 6 to 8wt%. Corrosion resistance was enhanced with increasing the Cr content and improved by rolling Zn-Cr coated specimen, as a post-treatment.

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Zn-Cr Alloy Plating from Acidic Chloride Bath: Effect of Temperature and Current Densities on Composition of Electrodeposits (산성염화욕에서의 Zn-Cr합금도금 : 합금화에 미치는 전류밀도와 온도의 영향)

  • Kang, Soo Young
    • Journal of the Korea Convergence Society
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    • v.9 no.11
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    • pp.285-290
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    • 2018
  • The steel has been used in modern industry, car maker and electric appliance. The steel have some problem, specially corrosion problem. To solve corrosion problem, Zn electrodeposit on steel have been adapted. Recently, The modern industry asks to increase corrosion resistance. Naturally, Increasing corrosion resistance increases the thickness of Zn electrodeposit. But increasing thickness of Zn electrodeposit has some problems. In making part, There are some crack. This crack cause to decrease corrosion resistance. To solve this problem, it is interested in Zn Based alloy electrodeposit such as Zn-Cr. Here, the influence of the electrolytic conditions on the composition of the alloy plating in the chloride bath was investigated. The results are explained by the cathode overvoltage curve of Cr and Zn. As the current density of the cathode increases, Zn content of electrodeposit decrease and Cr content of electrodeposit increase. As the temperature of the electrolyte increases, Zn content of electrodeposit decrease and Cr content of electrodeposit increase.

Humidity-Sensitive Characteristics of MgO and $TiO_2$ Addition on $ZnCr_2O_4$ Ceramic Thick-Film Humidity Sensors (MgO 및 $TiO_2$가 첨가된 $ZnCr_2O_4$ 세라믹 후막 습도센서의 감습 특성)

  • Yoon, Sang-Ok;Kim, Kwan-Soo;Jo, Tae-Hyun;Shim, Sang-Heung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.898-901
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    • 2004
  • [ $ZnCr_2O_4$ ]를 모물질로 하고 MgO, $TiO_2$를 몰비로 2:1, 4:1, 6:1, 및 8:1이 되게 정량적으로 조합한 후, 조사하였다. $ZnCr_2O_4$-MgO와 $ZnCr_2O_4-TiO_2$를 X-선 분석한 결과 Spinel 결정구조를 형성하였으며, 또한 SEM과 EDX 분석결과 각각 $Li_2CrO_4$$Li_3VO_4$의 형성으로 인하여 저항 특성이 나타나는 것을 알 수 있었다. $ZnCr_2O_4-MgO$, $ZnCr_2O_4-TiO_2$에서 MgO의 양이 증가할수록 저항값은 약간 감소하는 반면, $TiO_2$의 양이 증가할수록 저항값이 급격히 증가하는 특성을 나타내었고, 감습 특성에서도 M??보다 TiO2가 더 높게 나타내었다. 습에 따른 복원 특성의 경우 $700^{\circ}C$에서 소결한 ($ZnCr_2O_4:MgO=4:1$)과 ($ZnCr_2O_4:TiO_2=6:1$) 조성의 센서가 가장 양호하였다.

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The Characteristics of Distribution on the Heavy Metals in Soil of Kumho River Basin (금호강안의 토양중 중금속 분포특성)

  • 양성호;강선태;권오억
    • Journal of Environmental Health Sciences
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    • v.16 no.2
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    • pp.83-87
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    • 1990
  • This study was carried out to investigate the pollution of heavy metals in soil of seven stations from the upper spot (Yeungchun Dam) of Kumho River to the downstream(Gangchang Bridge). The results obtained were as follows: 1. The content of heavy metals in soil of Kumho River basin was highest at Gangchang Bridge [expresed in $\mu$g/g : Mn(246.0), Cd(1.90), Fe(551.2), Cu(108.2), Zn(86.4), Cr(80.2), respectively]. Whereas, the content of heavy metals expect for Mn, Cu was lowest at Yeungchun Dam [Cd(0.40), Fe(548.0), Zn(30.7), Cr(6.2), respectively] Also, the content of Cr, Zn was increased when the sampling areas are changed from upstream to downstream except for Hayang Bridge, and Hayang Bridge was the diverging point of the heavy metals content. 2. There were relatively correlated between Mn : FE, Cu, Zn, Cr, Fe : Cu, Zn, Cr(0.40 < $\left$\mid${r}\right$\mid$$ < 0.70), and were high correlated between Cd : Mn, Fe, Cu, Zn, Cu : Zn, Zn : Cr(0.70 < $\left$\mid${r}\right$\mid$$ < 0.90). Particularly, there was higest correlated between Cd : Cr, Cu : Cr(0.90< $\left$\mid${r}\right$\mid$$ < 1.0)

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A Study of Electroplating Conditions and Corrosion Resistance for Al2O3 Dispersed Zn-Co-Cr Electroplated Steel Sheets (Al2O3 분산 Zn-Co-Cr 전기도금강판의 제조조건 및 내식성에 관한 연구)

  • Kim, S.B.;Suh, S.J.;Park, H.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.6 no.2
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    • pp.89-97
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    • 1993
  • An improvement in corrosion resistance of various types of Zn-coated steel sheets is thought to be possible with the addition of fine oxide powder to the coating. In this study the corrosion resistance of the $Al_2O_3$ dispersed Zn-Co-Cr electroplated steel sheet has been investigated and the results were as follows : The corrosion resistance of $Al_2O_3$ dispersed Zn-Co-Cr electroplated steel sheets was improved by increasing the contents of Co and Cr ions, and also $Al_2O_3$ powders in the bath because of the increased amount of Co, Cr and $Al_2O_3$ in deposits. In the $Al_2O_3$ dispersed Zn-Co-Cr electroplated steels sheet, the structure of deposits was changed from fine microstructure as observed in high Co containing deposits to coarse microstructure as in high Cr and $Al_2O_3$ containing deposits. By cold rolling of the $Al_2O_3$ dispersed Zn-Co-Cr electroplated steel sheets to about 2 percent, thr corrosion resistance was improved further.

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Effects of Spinel on the Formation Process of Nonohmic ZnO Ceramics (비오옴 ZnO 세라믹스의 형성과정에서 스피넬의 영향)

  • 김경남;한상목
    • Journal of the Korean Ceramic Society
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    • v.29 no.2
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    • pp.101-106
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    • 1992
  • Sintering behavior, distribution of dopant oxides and electrical properties in the ZnO-Bi2O3-CoO-Sb2O3 and ZnO-Bi2O3-CoO-Sb2O3-Cr2O3 systems were studied. The linear shrinkage of ZnO varistors from 850 to 950$^{\circ}C$ was related to the decomposition reaction (py\longrightarrowsp+Bi2O3) of the pyrochlore phase. In the distribution of the dopant oxides (CoO, Sb2O3, Cr2O3), Co distribute uniformly throughout the sample, the distribution of Sb coincided with small particles (spinel phase, Zn7Sb2O12), and Cr distributed very consistently with Sb. The increase in breakdown voltage, due to the addition of Cr2O3, was not only attributed to the decrease in the ZnO grain size but also to the solution of Cr2O3 in the spinel phase. The leakage current (80% V60 ${\mu}\textrm{A}$) was increased by the addition of Cr2O3.

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Heavy Metal Contents and Food Safety Assessment of Processed Seaweeds and Cultured Lavers (국내 가공 해조류와 미가공 김의 중금속 함량 및 식품 안전성평가)

  • Yang, Won Ho;Lee, Hyo Jin;Lee, Sang Yong;Kim, Seong Gil;Kim, Gi Beum
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.19 no.3
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    • pp.203-210
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    • 2016
  • In this study, nine heavy metals were analyzed in seaweeds collected from market and laver culture farm of Korea and a food safety assessment were also carried out for these heavy metals. The level of heavy metal concentrations in seaweeds was in the following order: Fe>As>Zn>Cu>Cd>Pb>Cr>Ni>Hg. Except for zinc and cadmium, seven heavy metals were significantly higher in cultured laver than in processed laver. Significant correlation was observed Cr-Fe in cultured laver and Cu-Zn, Cd-Cu, Cd-Zn and Pb-Ni in processed laver and Cu-Cr, Cu-Zn, Cd-Cr and Ni-Fe in sea tangle and Zn-Fe, Cr-Fe, Cr-Zn, Cd-Ni, Cu-Cd and Cu-Pb in processed sea mustard. Considering differences in heavy metal concentration between processed laver and cultured laver and in correlation among heavy metals, removal efficiency of heavy metals may be attributed to seaweed treatment process. The average weekly intakes of Cu, Cd, Zn, Fe and Hg via seaweeds consumption were about 0.1~7.6% of PTWI (Provisional Tolerable Weekly Intakes). Therefore, it was found that heavy metals in the seaweeds were very safe for consumption.

Stabilization Behavior of Heavy Metal ions by Treatment Conditions (처리조건에 따른 중금속 이온의 안정화 거동)

  • 엄태호;김유택
    • Journal of the Korean Ceramic Society
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    • v.40 no.6
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    • pp.583-588
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    • 2003
  • Cation exchange capacity of clay, white clay and zeolite was measured by the adsorption test for 3 different heavy metal (Cd, Cr, Zn) standard solutions whose concentrations were varied by 10, 20, 30 ppm and pH were varied by 3, 5, 7, 9, respectively. The adsorption rate of Cd and Zn increased with increasing pH and slowly increased with increasing pH above pH 5. However, adsorption rate of Cr did not increase with increasing pH. Especially, Cr adsorption rate of the mixture of clay and white clay at pH 5 showed an half decrease compared to that at pH 3. The adsorption rate of mixed heavy metal solutions was in the order of Cd, Zn > Cr; however, the order was changed by Fe>Pb, Cu>Cr>Zn>Cd in case of Cu, Fe and Pb addition.

Carrier-enhanced Ferromagnetism in Cr-doped ZnO (Cr이 치환된 ZnO에서 나르개에 의한 강자성의 향상)

  • Sim, Jae-Ho;Kim, Hyo-Jin;Kim, Do-Jin;Ihm, Young-Eon;Yoon, Soon-Kil;Kim, Hyun-Jung;Choo, Woong-Kil
    • Journal of the Korean Magnetics Society
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    • v.15 no.3
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    • pp.181-185
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    • 2005
  • We have investigated the effects of Al codoping on the structural, electrical transport, and magnetic properties of oxide diluted magnetic semiconductor $Zn_{1-x}Cr_xO$ thin films prepared by reactive sputtering. Nondoped $Zn_{0.99}Cr_{0.01}O$ thin films show semiconducting transport behavior and weak ferromagnetic characteristic. The Al doping increases the carrier concentration and results in an decrease of resistivity and metal-insulator transition behavior. With increasing carrier concentration, the magnetic properties drastically change, exhibiting a remarkable increase of the saturation magnetization. These results show carrier-enhanced ferromagnetic order in Cr-doped ZnO.