• 제목/요약/키워드: Zinc ion

검색결과 275건 처리시간 0.024초

구리-아연 합금사의 산화-환원 반응을 통한 Microcystis aeruginosa의 사멸 특성에 관한 연구 (A Study on the Antimicrobial Activity of Microcystis aeruginosa by Redox Reaction of Cu-Zn Alloy Metal Fiber)

  • 송주영;김희선;이상호;김종화;박근호
    • 한국응용과학기술학회지
    • /
    • 제25권2호
    • /
    • pp.168-174
    • /
    • 2008
  • This study is focused on the antimicrobial activity of cyanobacteria Microcystis aeruginosa by the reduction and oxidation reaction of copper and zinc alloy metal fiber filter. Cu/Zn ion is easily makes radicals with molecular hydroperoxide. Especially, hydroperoxide radical shows strong toxicity to the strains. Plasma membrane causes conformational change when hydroperoxide radical binds to plasma membrane. Elution of copper ion from copper and zinc alloy metal fiber is detected in the cyanobacteria solution as 0.5 ppm, and that of zinc ion is 0 ppm respectively. Zinc ion is figured to form a hydroxide in the cyanobacteria solution and precipitated to form a sludge. The concentration of chlorophyll-a in the cyanobacteria solution was proved to be the index of antimicrobial level of Microcystis aeruginosa.

이온빔 조사된 용액 공정 기반 LaZnO 박막 위 액정 분자의 수평 배향 특성 (Homogeneous Alignment Characteristics of Liquid Crystal Molecules on Solution-Derived Lanthanum Zinc Oxide Film with Ion-Beam Irradiation)

  • 오병윤
    • 한국전기전자재료학회논문지
    • /
    • 제32권5호
    • /
    • pp.382-386
    • /
    • 2019
  • The alignment characteristics of liquid crystal (LC) molecules on a solution-derived lanthanum zinc oxide (LZO) film under ion-beam irradiation were demonstrated. Using the solution process, an LZO film was fabricated on the glass substrate and cured at $100^{\circ}C$. Afterwards, ion-beam irradiation was performed following the LC alignment method. Using this film, an LC cell was fabricated and the characteristics of the LC alignment were verified. Cross polarizing microscopy and the crystal rotation method were used to investigate the alignment state of the LC molecules on the LZO films. Furthermore, field emission scanning electron microscopy and X-ray photoelectron spectroscopy were used to explore the effect of the ion-beam irradiation on the LZO film. Through these, it was confirmed that the ion-beam irradiation induced surface modification, which demonstrated anisotropic physical and chemical surface characteristics. Due to this, uniform LC alignment was achieved. Finally, the residual DC and anchoring energy of the LC cell based on the LZO films were measured using a capacitance-voltage curve.

Removal of Zn(II) ion from aqueous solutions by using scoria as a sorbent

  • Kwon, Jang-Soon;Yun, Seong-Taek;Kim, Soon-Oh;So, Chil-Sup
    • 대한자원환경지질학회:학술대회논문집
    • /
    • 대한자원환경지질학회 2003년도 춘계 학술발표회 논문집
    • /
    • pp.61-65
    • /
    • 2003
  • Zinc occurs in the nature as sulfide, carbonate, silicate, and oxide. In natural water, zinc is generally in the form of the divalent cation $Zn^{2+}$ as well as in the form of fairly weakly bound complexes. Human activities introduce zinc ion to the hydrosphere in many ways. The zinc complexes in the aqueous environment are accumulated not only in aquatic organisms but also in human body ultimately through physico-chemical and/or biological processes. (omitted)

  • PDF

Mn-Zn 페라이트 다결정의 조성에 따른 투자율의 변화 기구 (Origin of the Initial Permeability of Manganese-Zinc Ferrite Polycrytals)

  • 변순천;제해준;고경현;홍국선
    • 한국세라믹학회지
    • /
    • 제34권4호
    • /
    • pp.351-356
    • /
    • 1997
  • The origin of the variation of initial permeability in manganese-zinc ferrite polycrystals with a content of hematite was investigated. Initial permeability showed maximum with hematite content while there was no significant change in microstructure. Saturation magnetization increased with hematite content. So the variation of initial permeability was not explained on the basis of microstructural change or saturation magnetization. Temperature dependence of initial permeability revealed magnetocrystalline anisotropy was the origin of the variation of initial permeability. The change in magnetocrystalline anisotropy was ascribed to the variation in ferrous ion concentration. Therefore the variation of initial permeability in manganese-zinc ferrite polycrystals with a content of hematite was due to ferrous ion concentration via magnetocrystalline anisotropy.

  • PDF

구강내 세균과 휘발성 황화합물에 대한 아연의 영향 (Effects of Zinc on Oral Bacteria and Volatile Sulfur Compound (VSC) in Oral Cavity)

  • 김영준
    • Journal of Oral Medicine and Pain
    • /
    • 제32권3호
    • /
    • pp.273-281
    • /
    • 2007
  • 아연 화합물은 의학적 효용이 뛰어나서 예전부터 화장품, 의약품 및 치과용 제제 등으로 널리 사용되어 왔다. 특히, 아연의 구강내 생물학적 작용에 대해서는 널리 알려져 있는데, 아연은 구강내 미생물에 다양한 기전으로 영향을 가해서 항균 작용, 항치태 작용, 항우식 작용을 갖게 된다. 또한, 아연은 구취를 유발하는 구강내 혐기성 세균과 구강내 휘발성 황화합물에 영향을 주어서 구취 치료제로서도 널리 애용되고 있다. 이에 저자는 아연의 개괄적인 물성과 독성 및 상용되고 있는 아연 제제들을 요약하여 제시한 후, 구강내 세균과 휘발성 황화합물에 대한 아연의 생물학적 영향에 대하여 항균 효과, 항치태 효과, 항우식 효과 및 구취감소 효과 등으로 나누어 고찰해보았다. 아연은 다른 금속에 비하여 독성이 적고 치아 착색을 거의 유발하지 않으며, 가격 또한 저렴하여 구강내 감염, 치아우식증, 치주질환 및 구취 등의 예방 및 치료제로서 많은 장점을 지니고 있다. 향후 이러한 장점을 바탕으로, 치과 임상에서의 아연제제의 적용은 증가할 것으로 사료되며, 이에 대한 전망은 밝다고 할 수 있다.

Nanofiller as Vulcanizing Aid for Styrene-Butadiene Elastomer

  • Sahoo, N.G.;Das, C.K.;Panda, A.B.;Pramanik, P.
    • Macromolecular Research
    • /
    • 제10권6호
    • /
    • pp.369-372
    • /
    • 2002
  • The use of ZnO and stearic acid is very well known in sulfenamide accelerated sulfur vulcanization of diene elastomers. Zn-ion coated nano filler has been developed and tested, in styrene-butadiene rubber (SBR) as sulfur vulcanizing activator cum reinforcing filler. In this study Zinc oxide has been replaced by the Zn-ion coated nano silica filler with an aim to study the dual role of this nanofiller in SBR. The presence of Zn-ion on the nano silica filler surface activates the sulfur vulcanization by involving Zn++ in to the sulfurating complex formed with thiazole from sulfenamide. The increase of Zn-ion, on the nanofiller, decrease the scorch safety of the elastomer compound but increase the tensile strength, state of cure and tear strength and attain maximum at its 10% level. The presence of stearic acid increases the rate of vulcanization. Replacement of stearic acid with mono-stearate, however, increases the vulcanization rate but decrease the ultimate state of cure. A mechanistic scheme involving dual function of this nanofiller has been suggested.

Membrane을 이용한 도금폐수 중 아연이온의 분리에 관한 연구 (Separation of Zinc Ion from Metal Plating Wastewaters by Reverse Osmosis Membrane)

  • 장자순;이효숙;정헌생;이원권
    • 멤브레인
    • /
    • 제4권2호
    • /
    • pp.106-112
    • /
    • 1994
  • $ZnSo_4{\cdot}7H_2O$에 의한 모델폐수에서 Zn 농도 및 pH를 변화하여 역삼투 실험하였고, Zn용액의 pH에 따라 아연의 제거율은 상당히 변화하였고, pH 3.0~11.5 범위에서 실험한 바 pH 8.3일 때가 아연제거율은 99.9% 이상, 투과 속도는 $1.49 {\times} 10^{-3}cm/sec$로 가장 큰 값을 보였다. 아연모델폐수에 Cyanide를 아연농도와 동량으로 첨가하였을 때, 아연은 99%, Cyanide는 93% 정도 제거가 가능하였다. 또한 첨가제로 음이온계면활성제 등을 첨가하여 실험한 결과, Membrane에서의 투과속도가 $0.76 {\times} 10^{-3}cm/sec$로 현저히 감소하였다.

  • PDF

차세대 이차전지용 아연 이온 이차전지 소재 연구 개발 동향 (Recent Research Trend of Zinc-ion Secondary Battery Materials for Next Generation Batterie)

  • 조정근;김재국
    • 세라미스트
    • /
    • 제21권4호
    • /
    • pp.312-330
    • /
    • 2018
  • Energy storage/conversion has become crucial not only to meet the present energy demand but also more importantly to sustain the modern society. Particularly, electrical energy storage is critical not only to support electronic, vehicular and load-levelling applications but also to efficiently commercialize renewable energy resources such as solar and wind. While Li-ion batteries are being intensely researched for electric vehicle applications, there is a pressing need to seek for new battery chemistries aimed at stationary storage systems. In this aspect, Zn-ion batteries offer a viable option to be utilized for high energy and power density applications since every intercalated Zn-ion yields a concurrent charge transfer of two electrons and thereby high theoretical capacities can be realized. Furthermore, the simplicity of fabrication under open-air conditions combined with the abundant and less toxic zinc element makes aqueous Zn-ion batteries one of the most economical, safe and green energy storage technologies with prospective use for stationary grid storage applications. Also, Zn-ion batteries are very safe for next-generation technologies based on flexible, roll-up, wearable implantable devices the portable electronics market. Following this advantages, a wide range of approaches and materials, namely, cathodes, anodes and electrolytes have been investigated for Zn-ion batteries applications to date. Herein, we review the progresses and major advancements related to aqueous. Zn-ion batteries, facilitating energy storage/conversion via $Zn^{2+}$ (de)intercalation mechanism.

고성능 아연-이온 전지의 고품질 집전체를 위한 그래핀 필름의 결함 제어 (Controlling Defects in Graphene Film for Enhanced-Quality Current Collector of Zinc-Ion Batteries with High Performance)

  • 이영근;안건형
    • 한국재료학회지
    • /
    • 제33권4호
    • /
    • pp.159-163
    • /
    • 2023
  • Zinc-ion Batteries (ZIBs) are currently considered to be effective energy storage devices for wearable electronics because of their low cost and high safety. Indeed, ZIBs show high power density and safety compared with conventional lithium ion batteries (LIBs) and exhibit high energy density in comparison with supercapacitors (SCs). However, in spite of their advantages, further current collector development is needed to enhance the electrochemical performance of ZIBs. To design the optimized current collector for high performance ZIBs, a high quality graphene film is suggested here, with improved electrical conductivity by controlling the defects in the graphene film. The graphene film showed improved electrical conductivity and good electron transfer between the current collector and active material, which led to a high specific capacity of 346.3 mAh g-1 at a current density of 100 mA g-1, a high-rate performance with 116.3 mAh g-1 at a current density of 2,000 mA g-1, and good cycling stability (68.0 % after 100 cycles at a current density of 1,000 mA g-1). The improved electrochemical performance is firmly because of the defects-controlled graphene film, leading to improved electrical conductivity and thus more efficient electron transfer between the current collector and active material.

Precipitation Stripping법에 의한 고순도 Oxalate 분말의 제조 (Preparation of High-purity Zinc Oxalate Powder by the Precipitation Stripping Method)

  • 이재천;이강인;유효신
    • 한국세라믹학회지
    • /
    • 제29권12호
    • /
    • pp.963-969
    • /
    • 1992
  • This paper describes the feasibility for a direct production of zinc oxalate powders from zinc-loaded D2EHPA solutions combining the purification and the precipitation in one operation unit. This process has the potential as an alternative to conventional method for the synthesis of zinc oxide precursor particles from the hydrometal-lurgical processes. Zinc was extracted into D2EHPA in kerosene and then zinc-loaded D2EHPA solution was emulsified with oxalic acid-HCl solution to precipitate zinc oxalate powder, which was readily calcined to zinc oxide. The precipitation kinetics and yield were sensitive to experimental conditions. The morphology, size and size distribution of the zinc oxalate powders varied with zinc/oxalate ion riatio, temperature, and the presence of SPAN 60, which affected nucleation, growth, and the emulsion characteristics.

  • PDF