• Title/Summary/Keyword: Zinc air battery

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A Study on the Electrochemical Properties of the Cathode upon Different Kinds of Activated carbon in Zinc/Air Battery (활성탄 종류에 따른 아연공기전지용 Cathode의 전기화학적 특성 연구)

  • 김지훈;엄승욱;문성인;윤문수;김주용;박정식;박정후
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.4
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    • pp.415-421
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    • 2004
  • The voltage profile of Zinc/Air battery during discharge has very flat pattern in a given voltage range, But, if not enough the porosity in cathode, as a result of that capacity, energy and discharge voltage of batteries become low. Therefore, we focused the pore effects in activated carbon for cathode. We examined discharge voltage, specific capacity, specific energy, resistance and characteristics during the GSM pulse discharge upon different kinds of activated carbon in Zinc/Air battery, Also we measured porosity of the air cathode according to the ASTM. So we achieved improvement of specific capacity, specific energy and discharge voltage according to increase meso pores of activated carbon. We found the optimized activated carbon material for Zinc/Air battery.

Development of Zinc Air Battery for Cellular Phone (휴대전화기용 아연공기전지 개발)

  • 엄승욱;김지훈;문성인;윤문수;김주용;박정식
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.9
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    • pp.936-941
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    • 2004
  • In recent years, the rapid growth of portable electronic devices requires the high-energy density characteristics of batteries. Zinc air batteries have specific capacity as high as 820mAh/g. However, Zinc air batteries used for hearing aid applications only so far, because the atmosphere could affect it, and it has weakness in the rate capability. However, recent developments of electrode manufacturing technologies made us to overcome that weakness. And the efforts of applying zinc air batteries to portable electronic devices, especially in cellular phone application have been increased. In this paper, the effects of conducting material and polymer binder in cathode on the electrochemical characteristics were investigated. Our research team succeeded in producing 2.4Ah class zinc air battery for cellular phone application. Its volumetric energy density was 920 wh/l, and gravimetric energy density was 308 wh/kg. The volumetric energy density of our zinc air battery is two times higher than one of lithium secondary battery, and three times higher than that of alkaline manganese battery.

Size Effects of the Catalyst on Characteristics of Zn/Air Batteries ($MnO_2$입자 크기에 따른 아연공기전지의 특성연구)

  • Kim, Jee-Hoon;Eom, Seung-Wook;Moon, Seong-In;Yun, Mun-Soo;Kim, Ju-Yong;Yug, Gyeong-Chang;Park, Jeong-Hoo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.1129-1131
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    • 2002
  • Zinc Air battery obtain their energy density advantage over the other batteries by utilizing ambient oxygen as the cathode materials, and reusing cathode as recycled form. And specific capacity of zinc powder is as high as 820mAh/g. When Zinc Air battery discharged by low rate current discharge voltage profile has very flat pattern until end of voltage. But, when Zinc Air battery discharged by high rate current discharge voltage and capacity become lower. Therefore, we focused on effects of catalyst size in cathode. So we examined performance of zinc air batteries, average discharge voltage, capacity, energy, resistance. And we also obtained resistance by the GSM pulse discharge. So we have got optimum size of catalyst for Zinc Air battery.

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Components in Zn Air Secondary Batteries (Zinc Air 이차전지의 구성요소)

  • Lee, Junghye;Kim, Ketack
    • Journal of the Korean Electrochemical Society
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    • v.16 no.1
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    • pp.9-18
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    • 2013
  • Components of zinc-air battery and their problems are explained. Energy density of zinc air battery is superior to other commercial ones including Li-ion batteries. Cycle life of the zinc air batteries is poor because of irreversible redox reactions on both electrodes. In order to improve the performance of the zinc air battery, catalysts, passivation, and the new structure of electrodes should be developed to optimize several reactions in an electrode. Multidisciplinary efforts, such as mechanics, corrosion science, composite materials are necessary from the beginning of the research to obtain a meaningful product.

Development of Zinc Air Battery for Cellular Phone (휴대전화기용 아연공기전지 개발)

  • Eom, Seung-Wook;Kim, Jee-Hoon;Moon, Seong-In;Yun, Mun-Soo;Kim, Ju-Yong;Park, Jeong-Sik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1083-1088
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    • 2004
  • Zinc air batteries obtain their energy density advantage over the other batteries by utilizing ambient oxygen as the cathode materials, and reusing cathode as recycled form. And specific capacity of zinc powder is as high as 820mAh/g. Our research team succeeded in producing 2.4 Ah class zinc air battery for cellular phone application. In this paper we had studied performance of cathode according to various factors and demonstrated the performance of 2.4 Ah class zinc air battery for cellular phone application.

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Effects of PTFE Contents on Characteristics of Cathode for Zn Air Batteries (PTFE함량에 따른 아연공기전지의 Cathode 특성연구)

  • Kim, Jee-Hoon;Eom, Seung-Wook;Moon, Seong-In;Yun, Mun-Soo;Kim, Ju-Yong;Yug, Gyeong-Chang;Park, Jeong-Hoo
    • Journal of the Korean Electrochemical Society
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    • v.6 no.3
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    • pp.203-207
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    • 2003
  • Zinc Air batteries obtain their energy density by utilizing ambient oxygen as the cathode materials. And specific capacity of zinc powder is as high as 820 mAh/g. When Zinc Air battery discharged at low current, then discharge voltage profile has very flat pattern until reach to end of voltage. But, when Zinc Air battery discharged at high current, then discharge voltage and energy becomes very low. So we focused on resistance and porosity of cathode with contents of PTFE. Wf studied on the effects of PTFE on performance of Zinc Air batteries. So we have got optimum contents of PTFE binder.

Size Effects of the Catalyst on Characteristics of Zn/Air Batteries (MnO2입자 크기에 따른 아연공기전지의 특성연구)

  • 김지훈;엄승욱;문성인;윤문수;김주용;박정식;박정후
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.12
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    • pp.1150-1154
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    • 2003
  • The voltage profile during discharge of the zinc air battery has very flat pattern until reach to end of discharge voltage. But, when zinc air battery is discharged by high current, the discharge voltage and energy becomes low. Therefore, we focused on effects of catalyst size to solve this problems by increasing active sites of oxygen reduction reaction. The size of catalyst was reduced from 27 to l${\mu}{\textrm}{m}$ and we examined average discharge voltage, capacity, energy, resistance and characteristics during GSM pulse discharge of zinc air battery with change of current density. And we also measured porosity of the cathode according to the ASTM. So we have got improvement of average discharge voltage and energy when catalyst was minimized and we have got optimum size of catalyst at 5${\mu}{\textrm}{m}$.

Effect of Temperature Conditions on Electrochemical Properties for Zinc-Air Batteries (온도조건에 따른 아연-공기 전지의 전기화학적 특성)

  • Lee, Ju Kwang;Jo, Yong Nam
    • Korean Journal of Materials Research
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    • v.30 no.12
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    • pp.687-692
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    • 2020
  • A zinc-air battery consists of a zinc anode, an air cathode, an electrolyte, and a separator. The active material of the positive electrode is oxygen contained in the ambient air. Therefore, zinc-air batteries have an open cell configuration. The external condition is one of the main factors for zinc-air batteries. One of the most important external conditions is temperature. To confirm the effect of temperature on the electrochemical properties of zinc-air batteries, we perform various analyses under different temperatures. Under 60 ℃ condition, the zinc-air cell shows an 84.98 % self-discharge rate. In addition, high corrosion rate and electrolyte evaporation rate are achieved at 60 ℃. Among the cells stored at various temperature conditions, the cell stored at 50 ℃ delivers the highest discharge capacity; it also shows the highest self-discharge rate (65.33 %). On the other hand, the cell stored at 30 ℃ shows only 2.28 % self-discharge rate.

A Study on Optimizing Zinc-Air Batteries Using M&S (M&S를 이용한 아연-공기전지 최적화 연구)

  • Lee, Jae-In
    • Journal of the Korea Institute of Military Science and Technology
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    • v.17 no.5
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    • pp.688-693
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    • 2014
  • Zinc-air batteries which has various merits in the aspect of energy density, power density and price relative to lithium based second batteries were extensively investigated recently. To develope and optimize these zinc-air batteries, the method of M&S is so efficient solution to reduce price and time. Therefore, in this paper, after executing mathematical modeling, I optimized the zinc-air battery through the simulation and make bolt-cell and discharge it to compare with simulation result. As a result, predictions are well agreed with experimental results.

Effect of the Conducting Agent on Characteristics of Cathode for Zn/Air Batteries (도전재 종류 및 함량에 따른 아연공기전지의 cathode특성연구)

  • Kim, Jee-Hoon;Eom, Seung-Wook;Moon, Seong-In;Yun, Mun-Soo;Kim, Ju-Yong;Yug, Gyeong-Chang;Park, Jeong-Hoo
    • Journal of the Korean Electrochemical Society
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    • v.5 no.2
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    • pp.74-78
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    • 2002
  • Zinc Air battery obtain their energy density advantage over the other batteries by utilizing ambient oxygen as the cathode materials, and reusing cathode as recycled form. And specific capacity of zinc powder is as high as 820 mAh/g. However, if the pore size in cathode is small then the flow rate of air decreased, and as a result of that discharge voltage of batteries becomes low. We focused on resistance and porosity of cathode. So we studied the effects of conducting agents to zinc air batteries performance, capacity, power density, average discharge voltage, resistance. And we also measured porosity of cathode by the ASTM. So we have got optimum contents of conducting agent.