• 제목/요약/키워드: Zinc Salt

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Effect of Retained Pre-construction Primer on the Corrosion Protection Properties of Epoxy Coatings

  • Lee, Chul-Hwan;Shin, Chil-Seok;Lee, Ho-Il;Chung, Mong-Kyu;Baek, Kwang-Ki
    • Corrosion Science and Technology
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    • v.6 no.5
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    • pp.219-226
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    • 2007
  • Pre-construction primer (PCP), or shopprimer, have been applied to steel plates to control temporary corrosion during ship fabrication. For surface preparation at ship block stage, in common shipyard practices, welding beads, burnt and rusted areas shall be blasted or power tool cleaned and the contamination such as zinc salt shall be removed with blasting or power tool. Whereas, the sound film of PCP needs not to be removed or roughened as the paint having good compatibility with PCP is used for the first coat. In many cases, however, full blasting or sweep blasting on the sound PCP treated block assemblies was requested. There still has been argument about the legitimacy of this practice, thus, it is critical to evaluate the quality of the coating system applied on the sound PCP retained condition, comparing with the one applied on the full blasted or sweep blasted condition. In this study, two different epoxy systems for water ballast tank were applied on the surfaces with sound PCP condition, full blasted condition, and sweep blasted condition. Coating performances such as durability, anti-corrosion, cathodic disbondment resistance were evaluated. The test results clearly indicated that the sound film of PCP needed not to be removed or roughened as the paint having good compatibility with PCP based on inorganic zinc silicate.

Helicobacter pylori Infection and Dietary Factors Act Synergistically to Promote Gastric Cancer

  • Raei, Negin;Behrouz, Bahador;Zahri, Saber;Latifi-Navid, Saeid
    • Asian Pacific Journal of Cancer Prevention
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    • v.17 no.3
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    • pp.917-921
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    • 2016
  • However, the incidence of gastric cancer (GC) has been decreased in past decades; GC is the second cause of cancer related death in the world. Evidence has illustrated that several factors including Helicobacter pylori (H. pylori) infection, host genetics, and environmental factors (smoking and particularly diet) may play a crucial role in gastric carcinogenesis. It has been demonstrated that high consumption of fresh fruits, vegetables, high level of selenium and zinc in drinking water, sufficient iron, and cholesterol protect against GC, while; smoked, pickled, and preserved foods in salt, and nitrites increase the risk of GC. Epidemiological studies have also proved that H. pylori infection and a high salt diet could independently induce atrophic gastritis and intestinal metaplasia. Recently, studies have been demonstrated that dietary factors directly influence H. pylori virulence. The use of appropriate diet could reduce levels of H. pylori colonization or virulence and prevent or delay development of peptic ulcers or gastric carcinoma. This is attractive from a number of perspectives including those of cost, treatment tolerability, and cultural acceptability. This review will describe new insights into the pathogenesis of H. pylori in relation to environmental factors, especially dietary, not only to find the developed means for preventing and treating GC, but also for understanding the role of chronic inflammation in the development of other malignancies.

Corrosion Resistance of Non-Chrome Magni 565 Coating and Characteristics of Its Coating Film (Non-Chrome Magni 565 코팅 피막의 특성과 내식성)

  • Kim, Sang-Su;Jeong, Byeong-Ho;Mun, Myeong-Jun;Kim, Mu-Gil
    • Journal of the Korean Society for Heat Treatment
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    • v.19 no.4
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    • pp.200-207
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    • 2006
  • In addition to the basic properties of the base and top coating agents, corrosion resistance of non-chrome magni 565 coating and characteristics of coating film when coated to steel substrate were studied. The system had a good wettability at room temperature. Moreover, both the contact angle and surface tension were affected little by the viscosity of coating agent and surface roughness of the steel substrate. And the samples coated with optimal conditions showed a great corrosion resistance in salt spray test with 1500 hours or longer of initial appearance time of rust. The coating film was composed of overlapping layer of zinc and aluminium flakes, and the thickness of base coat increased with an increase of base coat viscosity. Based on the C-F peaks of 1,1-Difluoroethaen homo-polymer, it was thought that the base coat was an inorganic polymer bond layer. Meanwhile, the top coat showed C-F peaks of polytetrafluoroethylene with C-H peaks of phenol in FT-IR analysis. From the lower weight loss of base coat in TG analysis, it was thought that cross linking density of base coat was larger than that of top coat. It was thought that the small exothermic reactions observed in DSC curves were due to the thermosetting resins contained in the coating agents. Compared to the non-coated specimen, the coated sample showed more higher polarization resistance and corrosion potential with lower corrosion current density.

Catalytic Performance of Ionic Liquids in the Synthesis of Glycerol Carbonate from Glycerol and Urea (글리세롤과 요소로부터 글리세롤카보네이트 합성에서 이온성액체의 촉매 특성)

  • Kim, Dong-Woo;Park, Kyung-Ah;Kim, Min-Ji;Park, Dae-Won
    • Korean Chemical Engineering Research
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    • v.51 no.3
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    • pp.347-351
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    • 2013
  • The preparation of glycerol carbonate (GC) from urea through carbonylation with renewable glycerol was investigated by using ionic liquid catalysts. It was found that quaternary ammonium salt and imidazolium salt ionic liquids with a shorter alkyl chain length and higher nucleophilic anion showed better catalytic performance. The effects of reaction temperature, reaction time and degree of vacuum on the reactivity of TBAC catalyst ware discussed. Zinc chloride ($ZnCl_2$) was used as co-catalyst with the ionic liquid catalyst. The mixed catalyst showed a synergy effect on the glycerol conversion and GC yield probably due to the acid-base properties of the catalysts.

Preparation, Characterizations and Conductivity of Composite Polymer Electrolytes Based on PEO-LiClO4 and Nano ZnO Filler

  • ElBellihi, Abdelhameed Ahmed;Bayoumy, Wafaa Abdallah;Masoud, Emad Mohamed;Mousa, Mahmoud Ahmed
    • Bulletin of the Korean Chemical Society
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    • v.33 no.9
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    • pp.2949-2954
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    • 2012
  • Nano ZnO with an average size of 8 nm was prepared by thermal decomposition of zinc oxalate at $450^{\circ}C$. A series of based composite polymer electrolyte PEO-$LiClO_4$ and nano ZnO as a filler have been synthesized using solution cast technique, with varying the filler ratio systematically. XRD, DSC and FTIR studies have been conducted to investigate the structure and interaction of different groups in the composite polymer electrolyte. Effect of nano ZnO ceramic filler concentration on the structure of composites and their electrical properties (DC-conductivity, AC-conductivity, dielectric constant, dielectric loss and impedance) at different frequencies and temperatures was studied. Melting temperature ($T_m$) of PEO decreased with the addition of both $LiClO_4$ salt and nano ZnO filler due to increasing the amorphous state of polymer. All composite samples showed an ionic conductivity. The maximum room temperature ionic conductivity is found for $(ZnO)_{0.5}(PEO)_{12}(LiClO_4)$ composite sample. All the results are correlated and discussed.

Isolation and Identificatioh~ of a Phthalate Ester Degrading Bacterium and the Optimal Culture Conditions for Production of One Degrading Enzyme (프탈레이트 에스터 분해세균의 분리 및 분해효소의 최적 생성조건)

  • Kim, Byung-O;Kim, Ran-Sug;Jin, Ing-Nyol;Park, Wan
    • Microbiology and Biotechnology Letters
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    • v.18 no.6
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    • pp.553-559
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    • 1990
  • A strain degrading phthalate ester was isolated from a sludge of Taegu area and identified as a strain of Klebsiella. The optimum culture conditions for the protocatechuate dioxygenase production were also investigated. This strain produced the enzyme in question under the shaking cultivation at $30^{\circ}C$for the 48 hrs in the medium containing 0.1% protocatechuate as the sole carbon source, 0.1% ammonium sulfate and 0.1% yeast extract as the nitrogen source and mineral salt mixture of magnesium sulfate, sodium chloride, calcium chloride, ferric chloride, manganese sulfate, zinc sulfate and cupric sulfate. This enzyme was intracellularl j localized and probably linked to cell membrane, and induced by protocatechuate.

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Effects of the Organic Fatty Acid Salts on the Watertightness Properties of the Cementitious Materials (시멘트 재료의 수밀특성에 미치는 유기 지방산 염의 영향)

  • Na, Seung-Hyun;Kang, Hyun-Ju;Ahn, Kwang-Hoon;Song, Myong-Shin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.529-532
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    • 2008
  • The durability of concrete and the water-tightness properties of cementitous material are closely relation. So, water-tightness materials as natural minerals, organic fatty acid, organic fatty salts inorganic materials use for improvement of concrete durability. But these materials are somehow different in water-tightness mechanism. In this study, we studied on hydration properties and water-tightness properties of cementitous materials with zinc-stearate, a kind of organic fatty acid salts.

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A Study of Corrosion Resistance and Torque in Bolt Coated with Magni 565 (Magni 565 코팅 볼트의 내식성 및 토오크 특성에 대한 연구)

  • Kim, Sang-Soo;Kim, Moo-Gil;Jung, Byong-Ho
    • Journal of the Korean Society for Heat Treatment
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    • v.20 no.4
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    • pp.195-202
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    • 2007
  • Corrosion resistance and torque of M10 bolt coated with Magni 565 were investigated. Corrosion protection mechanism were also studied with the microstructure of coating film. The bolts with the optimum conditions showed around $10{\mu}m$ layer thickness, a great corrosion resistance in salt spray test and a proper torque in torque/tension test. But torque coefficient k increased with the number of bolting and clamping force of M10 bolt showed significantly lower than that of specified value 28.3kN. It was thought that the repeated bolting made the coating film peel off and powdery. The sample coated with optimum coating conditions showed more higher polarization resistance and corrosion potential than the specimens of top and base coat only. The base coating film was composed of lamellar zinc flakes, which provides a large sacrificial cathodic protection. Meanwhile, the top coating film was composed of organic aluminium pigments layer, which provides barrier protection to the corrosion circumstances.

Cross-talk between Phosphate Starvation and Other Environmental Stress Signaling Pathways in Plants

  • Baek, Dongwon;Chun, Hyun Jin;Yun, Dae-Jin;Kim, Min Chul
    • Molecules and Cells
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    • v.40 no.10
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    • pp.697-705
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    • 2017
  • The maintenance of inorganic phosphate (Pi) homeostasis is essential for plant growth and yield. Plants have evolved strategies to cope with Pi starvation at the transcriptional, post-transcriptional, and post-translational levels, which maximizes its availability. Many transcription factors, miRNAs, and transporters participate in the Pi starvation signaling pathway where their activities are modulated by sugar and phytohormone signaling. Environmental stresses significantly affect the uptake and utilization of nutrients by plants, but their effects on the Pi starvation response remain unclear. Recently, we reported that Pi starvation signaling is affected by abiotic stresses such as salt, abscisic acid, and drought. In this review, we identified transcription factors, such as MYB, WRKY, and zinc finger transcription factors with functions in Pi starvation and other environmental stress signaling. In silico analysis of the promoter regions of Pi starvation-responsive genes, including phosphate transporters, microRNAs, and phosphate starvation-induced genes, suggest that their expression may be regulated by other environmental stresses, such as hormones, drought, cold, heat, and pathogens as well as by Pi starvation. Thus, we suggest the possibility of cross-talk between Pi starvation signaling and other environmental stress signaling pathways.

Effect of Resorcinol as Free Formaldehyde Scavenger for Fabric Finished with Urea-formaldehyde Precondensate. (Urea-Formaldehyde 수지가공포에 있어 Resorcinol의 유리 Formaldehyde 포착효과)

  • Kang, In-Sook;Kim, Sung-Reon
    • Textile Coloration and Finishing
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    • v.9 no.2
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    • pp.41-49
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    • 1997
  • To control free formaldehyde release from fabric finished with N-methylol compounds, resin finished cotton fabric was treated with resorcinol solution, dried and cured. Factors affecting to control formaldehyde release have been investigated. It was shown that the aftertreatment with resorcinol greatly suppressed the free formaldehyde release. Up to concentration of about 5% of resorcinol, the concentration of resorcinol effected on the control of free and evolved formaldehyde. And at high concentration of resorcinol, however, the concentration became rather insensitive to contol formaldehyde release. Addition of some salt catalysts such as ammonium chloride, zinc nitrate, sodium acetate and ammonium acetate, was effective in decreasing formaldehyde release. Considering the effect on the control of formaldehyde and crease recovery, ammonium acetate was concidered to be the best catalyst. It was observed that the optimum curing temperature for the resorcinol treatment was about 15$0^{\circ}C$, and that the curing time did not affected formaldehyde release over three minutes. Although the treatment of resorcinol had a little adverse effect on crease recovery of resin finished fabric, this effect could be negligible.

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