• Bulletin of the Korean Chemical Society
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• 제15권6호
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• pp.473-477
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• 1994

Second-order rate constants have been measured spectrophotometrically for the nucleophilic substitution reactions of aryl substituted benzenesulfonates $(1,\;X-C_6H_4SO_2-OC_6H_4-Y)$ with aryloxides $(Z-C_6H_4O^{-})$ and ethoxide $(EtO^-)$ in absolute ethanol at $25^{circ}C$. The nucleophilicity of aryloxides increases with increasing electron donating ability of the substituent (Z) on aryloxides, and results in a good Hammett correlation with $\sigma^{-}$ constant. The reactivity of 1 toward aryloxides and ethoxide shows also significant dependence on the electronic nature of the substituent X and Y. Large positive ${\sigma}_{acyl}$ values have been obtained for the reaction of 1 with phenoxide and ethoxide, indicating that the leaving group departure is little advanced at the transition-state of the rate-determining step. This has been further supported from the fact that ${\sigma}^-$ constant gives extremely poor Hammett correlation, while ${\sigma}^0$ does reasonably good correlation for the reaction of 1 with ethoxide. Thus, the present sulfonyl-transfer reaction is proposed to proceed via a ratedetermining attack of nucleophile to the sulfur atom of 1 followed by a fast leaving group departure.

• Structural Engineering and Mechanics
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• 제15권2호
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• pp.181-198
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• 2003

Six large scale models of conventionally reinforced concrete coupling beams with span/depth ratios ranging from 1.17 to 2.00 were tested under monotonically applied shear loads to study their nonlinear behavior using a newly developed test method that maintained equal rotations at the two ends of the coupling beam specimen and allowed for local deformations at the beam-wall joints. By conducting the tests under displacement control, the post-peak behavior and complete load-deflection curves of the coupling beams were obtained for investigation. It was found that after the appearance of flexural and shear cracks, a deep coupling beam would gradually transform itself from an ordinary beam to a truss composed of diagonal concrete struts and longitudinal and transverse steel reinforcement bars. Moreover, in a deep coupling beam, the local deformations at the beam-wall joints could contribute significantly (up to the order of 50%) to the total deflection of the coupling beam, especially at the post-peak stage. Finally, although a coupling beam failing in shear would have a relatively low ductility ratio of only 5 or even lower, a coupling beam failing in flexure could have a relatively high ductility ratio of 10 or higher.

• 산업경영시스템학회지
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• 제29권4호
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• pp.1-7
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• 2006

This study determined the optimal positions of the movable steering wheel and pedal systems of industrial vehicle by various body dimensions. The position of objects and starting driving posture were measured by Martin-type anthropometer and goniometer. The X, Y and Z axis of movable steering wheel and pedal systems were measured horizon distance from right side to left side, horizon distance from front side to rear side and vertical distance from floor to ceiling. During the experiment in order to exclude learning effectiveness with forklift driving, 27 subjects who had male not experiences in driving a forklift used in the experiment. The relationship between the position of steering wheel and driver's posture with body dimensions was analyzed by using correlation relation and paired comparison t-test based on the measured data. The pedal location in X and Z axises was not related with various body dimensions. Also, the steering wheel was different among the angles of the right elbow and shoulder depending on the various body dimensions.

• 한국자기학회지
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• 제4권1호
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• pp.1-6
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• 1994

본 연구에서는 초 연자성(ultra-soft magnetic) 비정질 박막에서 관찰되는 감쇄가 큰(overdamped) 고주파 자기특성의 원인을 이해함으로써 자기 스핀의 동적 자화거동을 확인하고자한다. 고주파에서의 자화율(susceptibility) 특성곡선에 대한 실험결과와 Gilbert의 운동방정식으로 부터의 계산 결과를 비교하여 초 연자성 박막의 겨우 $\alpha=20$ 정도의 큰 감쇄상수와 무시할 정도로 작은 $D_{x}{\approx}D_{y}{\approx}D_{z}{\approx}0$의 반자장 계수를 구하였다. 이 결과로 부터 불균일 박막의 자화율 특성곡선과 자기 스핀의 동적 자화거동을 설 명하기 위해 vortex 형상의 자화분포를 제안하였다. Vortex형 자화분포는 초 연자성 박막 내의 미세한 자성입자들에서의 안정된 스핀 분포로 형성되며, vortex의 불균일한 스핀운동은 스핀파로 부터의 에너지와 박막내 결함구조와의 상호작용에 의해 큰 감쇄를 갖는 것으로 설명되었다.

• 아태비즈니스연구
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• 제11권4호
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• pp.21-36
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• 2020

Purpose - This study analyzes the effect of sellers' dishonesty on various market outcomes such as seller profit, buyer profit, and market welfare, through precisely measuring the level of sellers' information disclosure and its economic impacts. As an explicit observation of sellers' dishonesty is not easy in most other settings, this study is expected to suggest unique and meaningful implications on the effect of sellers' incomplete information disclosure to researchers, managers, and policy makers. Design/methodology/approach - In order to precisely measure the level of sellers' dishonesty under information asymmetry, this study analyzes the data from an incentive-based economic experiment using z-Tree software. This experimental method enables us to focus on the strategic interactions among participants, observe the integrity of seller's information disclosure, and reproduce real market situations. Findings - The analysis of sellers' dishonesty has provided the following important and counterintuitive findings about the reality of buyer-seller interactions under information asymmetry. First, sellers' lies do not affect seller profit even when they are very intensive. Second, sellers' dishonesty negatively affects buyer profit and the entire market welfare. Third, a seller's quality claim has a positive effect on the seller profit only when a seller is being honest. Research implications or Originality - This study analyzes sellers' dishonesty using incentive-based economic experiment using z-Tree software which provides a straightforward examination on dishonest behavior of sellers, that is not readily available with other types of observational or experimental data.

• 한국환경과학회지
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• 제27권11호
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• pp.975-982
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• 2018

In this study, zeolite (Z-C1) was synthesized using a fusion/hydrothermal method from coal fly ash. The morphological structures of Z-C1 were confirmed to be highly crystalline with a cubic crystal structure. Exchange capacities of $Ca^{2+}$ and $Mg^{2+}$ ions in a single and a mixed solution reached equilibrium within 120 min. The exchange kinetics of these ions were well predicted by the pseudo-second-order rate equation. The exchange isotherms of the $Ca^{2+}$ and $Mg^{2+}$ ions matched the Langmuir isotherm better than the Freundlich isotherm. The maximum cation exchange capacities ($q_m$) obtained by the Langmuir isotherm model were 2.11 mmol/g (84.52 mg/L) and 1.13 mmol/g (27.39 mg/L) for the $Ca^{2+}$ and $Mg^{2+}$ ions, respectively.

• 한국기계가공학회지
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• 제19권10호
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• pp.24-30
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• 2020

The high speed of an engine balance box may cause significant additional gear noise. Gear accuracy is the most useful key to reduce gear noise, but the small tooth width and thin-walled anti-backlash gear introduce challenges to the manufacturing process. In order to reduce the gear noise caused by gear pitch error, this paper investigates the correlation between influencing factors and gear pitch error by analyzing the processing technology, tooling fixture, and equipment accuracy. By improving the process and optimizing the gear design, the gear machining accuracy was improved and the processing cost was saved.

• Bulletin of the Korean Chemical Society
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• 제17권4호
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• pp.353-357
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• 1996

Second-order rate constants have been measured spectrophotometrically for the reaction of 2,4-dinitrophenyl X-substituted benzenesulfonates with Z-substituted phenoxides in absolute ethanol at 25.0±0.1 ℃. The nucleophilic substitution reaction gives both S-O bond and C-O bond cleavage products. The extent of S-O bond cleavage increases significantly with increasing electron withdrawing ability of the sulfonyl substitutent X, while that of the C-O bond cleavage is independent on the electronic effect of the substituent. On the contratry, the effect of the substituent Z in the nucleophilic phenoxide is more significant for the C-O bond cleavage than for the S-O bond cleavage. Aminolyses of 2,4-dinitrophenyl benzenesulfonate (1) with various 1°, 2° and 3°amines have revealed that steric effect is little important. The extent of S-O bond cleavage increases with increasing the basicity of the amines, but decreases with increasing the basicity of the nucleophilic aryloxides, indicating that the HSAB principle is not always operative. Besides, reactant and solvent polarizability effect has also been found to be an important factor in some cases but not always to influence the reaction site.

• 한국산업융합학회 논문집
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• 제24권6_1호
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• pp.693-698
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• 2021

As technology advances, there is increasing need for research in different fields where this technology is applied. On of the most researched topic in computer vision is Human activity recognition (HAR), which has widely been implemented in various fields which include healthcare, video surveillance and education. We therefore present in this paper a human activity recognition system based on scale and rotation while employing the Kinect depth sensors to obtain the human skeleton joints. In contrast to previous approaches that use joint angles, in this paper we propose that each limb has an angle with the X, Y, Z axes which we employ as feature vectors. The use of the joint angles makes our system scale invariant. We further calculate the body relative direction in the egocentric coordinates in order to provide the rotation invariance. For the system parameters, we employ 8 limbs with their corresponding angles each having the X, Y, Z axes from the coordinate system as feature vectors. The extracted features are finally trained and tested with the Long short term memory (LSTM) Network which gives us an average accuracy of 98.3%.

• 스마트미디어저널
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• 제11권7호
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• pp.70-75
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• 2022

2019년 정부는 경제성이 예비타당성조사 통과의 결정적 요소로 작용하는 문제 개선을 위해 종합평가의 경제성 항목 가중치 최대치를 50%에서 45%로 축소하도록 제도를 개선하였다. 이 연구는 2019년 제도개선에 따른 효과를 분석하기 위한 것으로 제도 개선 전과 후의 차이를 검증하였다. 회귀분석과 상관관계 분석결과 두 기간 모두 높은 상관성을 보였으며, Z검증을 통한 차이는 통계적으로 유의미하지 않은 것으로 분석되었다. 이 결과는 경제성의 영향력을 축소하기 위한 제도 개선이 효과가 없었다는 것을 의미한다. 따라서 종합평가 각 항목의 가중치를 기존 사업 등에 다양하게 대입해 재평가 해보는 등의 연구를 통해 보다 실효성 있는 종합평가 연구 설계 논의가 필요할 것으로 판단된다.