• Title/Summary/Keyword: Yttrium

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Effect of yttrium additives on the shear bond strength of porcelain fused to Ni-Cr alloy for porcelain fused metal crown (도재용착용 Ni-Cr계 합금의 이트륨 첨가물이 도재전단결합강도에 미치는 영향)

  • Woo, Je-Seung;Noh, Se-Ra;Noh, Hyeong-Rok;Lim, Chung-Ha;Lee, Jung-Hwan
    • Journal of Technologic Dentistry
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    • v.41 no.2
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    • pp.71-80
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    • 2019
  • Purpose: In this study, to evaluate the effect of oxide changes on the shear bond strength according to the composition of Ni-Cr alloys for porcelain fused matal crown, T-4 alloys, Zeroy alloys and Zeroy-X alloys were selected. Methods: 20 specimens were fabricated using selected Ni-Cr alloys and porcelain powders. A Ni-Cr alloy having a diameter of 5 mm and a height of 25 mm was produced and the metal surface was polished. Porcelain powder was fired on the polished metal surface to a diameter of 5 mm and a height of 3 mm. The experiment group consisted of three groups, T-4(TNA), Zeroy(ZNA) and Zeroy-X(ZXA). The fabricated specimens were mounted on a jig of a universal testing machine(UTM) and fracture strength was measured by applying a shear force at a UTM crosshead speed of 0.5 mm/min. The fracture strength was calculated as the bond strength between the porcelain and the alloy. The surface of the fractured alloy was analyzed by X-ray diffraction(XRD) and scanning electron microscopy(SEM), and the components of the oxide were measured by energy dispersive X-ray spectroscopy(EDX) line profile method. Results: In SEM, XRD and EDX analysis, yttrium tended to increase the mechanical and chemical bonding forces. The shear bond strength of ZXA group containing yttrium showed the highest value at 27.53 MPa. Conclusion: Based on the results of this study, it is considered that the yttrium-added Ni-Cr alloy is clinically acceptable in porcelain shear bond strength.

Microstructure and Magnetic Characteristics of Yttrium Iron Garnet Thin Films Prepared by RF Magnetron Sputter (고주파 마그네트론 스퍼터법에 의해 제조된 Yttrium Iron Garnet 박막의 미세구조 및 자기적 특성)

  • 박명범;김병진;조남희
    • Journal of the Korean Ceramic Society
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    • v.36 no.3
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    • pp.293-300
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    • 1999
  • 고주파 마그네트론 스퍼터법을 이용한 YIG(yttrium iron garnet)박막 제조시 기판유형, 기판온도, 스퍼터전력, 스퍼터가스 등의 증착변수와 증착후 열처리 조건이 YIG 박막의 결정성, 화학조성, 미세구조 그리고 자기적 특성에 미치는 영향에 대하여 고찰하였다. 75$0^{\circ}C$ 이상의 온도에서 수행한 증착후 열처리에 의하여 비정질 박막이 결정화되었으며, 특히 GGG(gadolinium gallium garnet)기판 위에 제조된 박막은 강한 (111)우선배향성을 나타냈다. 박막조성은 스퍼터가스 내의 산소분율에 민감하게 영향을 받았으며, 산소분율이 20%인 스퍼터가스를 사용하여 제조된 박막은 Y2.88Fe3.84O12의 조성을 나타내었다. 증착후 열처리 온도가 90$0^{\circ}C$로부터 110$0^{\circ}C$로 증가함에 따라, GGG 기판위의 박막의 표면거칠기는 2.5nm에서 40nm로 증가하였으며, 보자력과 강자성 공명 선폭은 감소하였다.

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Solution-Derived Amorphous Yttrium Gallium Oxide Thin Films for Liquid Crystal Alignment Layers

  • Oh, Byeong-Yun
    • Transactions on Electrical and Electronic Materials
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    • v.17 no.2
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    • pp.109-112
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    • 2016
  • We demonstrated an alternative electrically controlled birefringence liquid crystal (ECB-LC) system with ion beam (IB)-irradiated yttrium gallium oxide (YGaO) alignment films using a sol-gel process. The surface roughness of the films was dependent on the annealing temperature; aggregated particles on surface were observed at lower annealing temperatures, whereas a smooth surface could be obtained with higher annealing temperatures. Higher transmittance in the visible region was observed at higher annealing temperatures. The film had an amorphous crystallographic state irrespective of the annealing temperature. Furthermore, ECB-LC cell with our IB-irradiated YGaO film yielded faster response time when compared to ECB-LC cell with rubbed polyimide. Considering the fast response time and high transmittance, the IB-irradiated YGaO-base LC system is a powerful alternative application for the liquid crystal display industry.

Adsorption Kinetics of Carrier-Free Yttrium-90 on Membrane Filters (막여과지에 대한 이트륨-90의 흡착 반응속도에 관한 연구)

  • Won Mok Jae
    • Journal of the Korean Chemical Society
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    • v.16 no.1
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    • pp.1-5
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    • 1972
  • The adsorption kinetics on a membrane filter have been studied by an introduction of acid or alkali in yttrium-90 solution. The change of the adsorption in the filtration process was determined by the filtrate activities with using a microsyringe filter holder connected with a syringe. The over all reaction rate obeyed a reversible first order reaction, and the rate constants thus obtained, showed the values of $k_1$ = 0.12 $sec^{-1}$ and $k_1'$ = 0.039 $sec^{-1}$. As a result of the present studies, it would be reasonable that the rate determining step of the adsorption reaction was the hydrolysis reaction of the adsorbed yttrium ions.

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Study on Solution Processed Indium-Yttrium-Oxide Thin-Film Transistors Using Poly (Methyl Methacrylate) Passivation Layer (PMMA 보호막을 이용한 용액 공정 기반의 인듐-이티륨-산화물 트랜지스터에 관한 연구)

  • Kim, Han-Sang;Kim, Sung-Jin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.7
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    • pp.413-416
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    • 2017
  • We investigated solution-processed indium-yttrium-oxide (IYO) TFTs using apoly (methyl methacrylate) (PMMA) passivation layer. The IYO semiconductor solution was prepared with 0.1 M indium nitrate hydrate and 0.1 M yttrium acetate dehydrate as precursor solutions. The solution-processed IYO TFTs showed good performance: field-effect mobility of $13.13cm^2/Vs$, a threshold voltage of 8.2 V, a subthreshold slope of 0.93 V/dec, and a current on-to-off ratio of $7.2{\times}10^6$. Moreover, the PMMA passivation layers used to protectthe IYO active layer of the TFTs, did so without deteriorating their performance under ambient conditions; their operational stability and electrical properties also improved by decreasing leakage current.

EFFECT OF ALUMINIDE-YTTRIUM COMPOSITE COATING ON THE OXIDATION RESISTANCE OF TiAl ALLOY

  • Jung, Hwan-Gyo;Kim, Jong-Phil;Kim, Kyoo-Young
    • Journal of the Korean institute of surface engineering
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    • v.29 no.6
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    • pp.607-614
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    • 1996
  • Yttrium(Y) coating was incorporated by ion-plating method either directly on the TiAl substrate or after pack aluminizing on TiAl to improve the oxidation resistance of TiAl alloy. After Y-coating, heat treatment at low oxygen partial pressure was carried out. Performance of various coating was evaluated by isothermal and cyclic oxidation tests. A simple Y-coating without pack aluminizing can give a detrimental effect on the. oxidation resistance of TiAl alloy, because it enhances formation of $TiO_2$. On the other hand, a composite coating of aluminide-yttrium has shown excellent oxidation resistance. A continuous protective $Al_2O_3$ scale is formed on the aluminized TiAl, and Y-coating improves $Al_2O_3$ scale adherence and substantially prevents depletion of Al in the aluminide-coating layer.

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Analysis of Broad-Range DNA Fragments with Yttrium Oxide or Ytterbium Oxide Nanoparticle/Polymer Sieving Matrix Using High-Performance Capillary Electrophoresis

  • Kwon, Hae-Myun;Kim, Yong-Seong
    • Bulletin of the Korean Chemical Society
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    • v.30 no.2
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    • pp.297-301
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    • 2009
  • We have developed the yttrium oxide (YNP) or ytterbium oxide (YbNP) nanoparticle/polymer matrices for the size-dependent separation of DNA ranging from 100 bp to 9,000 bp. High separation efficiency (> $10^6$ plates/m) and the baseline resolution for various DNA standards (100 bp, 500 bp, and 1 kbp DNA ladder) were obtained in 10 min with these matrices. The effects of concentrations of both polyethylene oxide (PEO) and nanoparticles were investigated and the highest performance was obtained at 0.02% PEO with 0.02% YNP or YbNP. Similar sieving power for both YNP and YbNP matrices was observed probably due to the similar sizes of nanoparticles, resulting in the formation of comparable sieving networks for DNA separation. For the reduction of electrosmotic flow, either dynamic or permanent coating of the capillary inner wall was compared and it turned out that PEO was superior to polyvinylpyrrolidone (PVP) or polyacrylamide (PAA) for better separation efficiency.

Crystal Growth of Chromium (4+) Ion Doped Yttrium Aluminum Garnet

  • Yu, Y.M.;Jeong, S.J.;Koh, J.C.
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1998.09a
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    • pp.53-53
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    • 1998
  • Four valence of Chromium ion doped Yttrium Aluminum Garnet crystals were grown by Floating Zone and Czochralski methods. Changes of valence for Chromium (3+) ion to Chromium (4+) were achieved by substitution of Yttrium ion in dodecahedral site to Calcium and by substitution of Aluminum in octahedral site to Magnesium. Growth conditions for high quality of crystals were investigated. Grown crystals were cut and polished and then observed various types of defects. Characterizations by means of measurement of density and lattice parameter as a function of solidification fraction were performed. Results of Q-switching test using grown crystals were also reported.

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Transport Mechanisms of Holmium Sesquioxide-Yttrium Sesquioxide System

  • Kim, Keu-Hong;Choi, Jae-Shi;Park, Sung-Ho;Won, Hui-Jun
    • Bulletin of the Korean Chemical Society
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    • v.6 no.1
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    • pp.11-15
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    • 1985
  • Electrical conductivites of polycrystalline yttrium sesquioxides containing 1.6 and 3.2 mol % of holmium sesquioxdes have been measured from 650 to $1050^{\circ}C$ under oxygen partial pressures of $1{\times}10^{-5}$ to $2{\times}10^{-1}$ atm. Plots of log conductivity vs. 1/T at constant oxygen partial pressures are found to be linear away from the two inflection points. The low- and high-temperature dependences of conductivity show different defect structures of yttrium sesquioxide. The plots of log conductivity vs. log $PO_2$ are found to be linear at $PO_{2'}$s of $10^{-5}$ to $10^{-1} atm. The electrical conductivity dependences on $PO_2$ are found to be $1}5.3$ at $950-1050^{\circ}C$, $\frac{6}{1}$ at $800-950^{\circ}C$ and ($\frac{6.2}{1}$) - ($\frac{6.5}{1}$) at $650-800^{\circ}C$, respectively. The defect structures and conduction mechanisms have been suggested.

Fast Switching of Twisted Nematic Liquid Crystals Display Based on a High-K Yttrium Oxide (고유전율 Yttrium Oxide을 이용한 네마틱 액정 디스플레이의 고속 응답 전기-광학 특성)

  • Jung, Yoon Ho;Jeong, Hae-Chang
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.4
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    • pp.302-306
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    • 2019
  • We investigated a solution-derived $Y_2O_3$ film treated by ion beam (IB) irradiation as a liquid crystal (LC) alignment layer. With IB irradiation, homogeneous LC alignment was achieved irrespective of the annealing temperature. To verify the effect of IB irradiation, we conducted surface analyses such as X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). As $Y_2O_3$ is a high-k material, the electro-optical properties of the twisted nematic (TN) cells were superior to those of conventional TN cells based on a rubbed polymer, with an LC rising time of 4.1ms and falling time of 2.9ms. The IB-irradiated $Y_2O_3$ is a good alternative as an alignment layer for fast-switching TN LC displays.