• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.6
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• pp.204-211
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• 2020

The high-velocity oxy-fuel (HVOF) thermal spraying coating technique has been considered a promising replacement for traditional electrolytic hard chrome plating (EHC), which caused environmental pollution and lung cancer due to toxic Cr⁶⁺. In this paper, two types of cermet coatings were prepared by HVOF spraying: WC-CoCr and WC-CrC-Ni coatings. The produced coatings were analyzed extensively in terms of the micro-hardness, porosity, crystalline phase and microstructure using a hardness tester, optical microscopy, X-ray diffraction, and scanning electron microscopy (including energy dispersed spectroscopy (EDS)), respectively. The wear and friction behaviors of the coatings were evaluated comparatively by reciprocating sliding wear tests at 25 ℃, 250 ℃, and 450 ℃. The results revealed correlations among the microstructures, metallic binder matrixes, porosities, and wear performance of the coatings. For example, WC-CoCr coatings showed better sliding wear resistance than WC-CrC-Ni coatings, regardless of the test temperature due to the more homogeneous microstructure, Co-rich, Cr-rich metallic binder matrix, and lower porosity.

• Journal of the Mineralogical Society of Korea
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• v.28 no.1
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• pp.51-60
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• 2015

We applied gemological analytical approaches on Aquamarine from the Gilgit-Baltistan of Northern Areas, Pakistan. The standard gemological testing indicates that they are consistent with general characteristics of natural aquamarines. We have identified the inclusions of Tantalite-Mn by Raman analysis. It indicates that they occurs in association with the veins of Be-rich coarse pegmatite. And the results of chemical analyses, infrared absorption spectroscopy and Raman spectroscopy indicate that $H_2O$ molecules in channel mostly exist in Type-I and a little Type-II with low alkali ion. The comparison of relative peak intensity of FT-IR analysis can be used for prediction of $Na_2O$ content within not only emerald but also aquamarine.

• Journal of the Korea Concrete Institute
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• v.29 no.4
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• pp.399-406
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• 2017

CaO-based by-product, which consist of CaO, $SO_3$, $Al_2O_3$ and so on, has being used to raw materials of CaO compound. When It was applied to recycling water of remicon, concrete performance can be enhanced because hydration reaction of powder material is accelerated. In this study, activated-sludge, which was putted desulfurization gypsum of CaO-based in recycling water, was manufactured to verify effect of them, and then they was investigated by characteristics of cement matrix and mortar. As a results, they indicated reduction of setting time and high soundness in cement matrix, and acceleration of hydration reaction can be verified by XRD analysis. Also, it can be maintained good workability if water content by usage of desulfurization gypsum, which used for production of activated-sludge, was adjusted. In addition, it can be verified strength development by activated-sludge although cement content by usage of desulfurization gypsum was reduced.

• Journal of the Korean Ceramic Society
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• v.39 no.11
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• pp.1055-1062
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• 2002

The phase stability and the Low Temperature Degradation(LTD) mechanism of Tetragonal Zirconia Polycrystals(TZP), sintered specimens of $Y_2O_3$-Stabilized Zirconia(2Y-TZP), doped with trivalent cations, were evaluated by investigating meachnical properties, Raman spectra, lattice parameter variation and the oxygen vacancy behavior under applied electric field. XRD observation was put forward on 2Y-TZP doped with trivalent cation whose ionic radii were larger than $Zr^{4+}(Sc^{3+},\;Yb^{3+},\;Y^{3+},\;Sm^{3+},\;Nd^{3+},\;La^{3+})$ up to 2 mol% and sintered at 1500 h for 1h. For $La^{3+}$ doping, the stability of tetragonal phase was degraded due to the formation of the pyrochlore phase $(La_2Zr_2O_7)$ as the dopant content increased above exceeded 0.5 mol%. As the dosage increased, tetragonal phase maintained for the case of $Sc^{3+}$, whose radius was similar to $Zr^{4+}$, on the other hand, the cubic phase was formed for the cases of $Yb^{3+},\;Y^{3+},\;Sm^{3+},\;Nd^{3+}$. As the radii of dopant cation increased, c/a ratio increased and it was experimentally observed that the amount of monoclinic phase decreased when the specimens were annealed at $220{\circ}C$ for 500 h.

• Journal of the Korean Ceramic Society
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• v.24 no.3
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• pp.243-250
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• 1987

The effects aging on some properties and thermal-shock behavior of zirconia partially stabilized with 9 mol% MgO (9MZ) were studied. 9MZ specimens were aged over $1200^{\circ}$-$1400^{\circ}C$ for 12hours subsequently, after sintering at $1650^{\circ}C$ for 4 hours. Fracture strength(both before and after thermal-shock test), linear thermal expansion, monoclinic fraction and phase transition by XRD, density, galvanic potential and microstructure were measured. Quantitative chemical analysis around the grain-boundary of the specimen aged at $1350^{\circ}C$ was also conducted by EDX. The aging of 9MZ specimen causes a thermal decomposition of cubic-$ZrO^{2}$ into the formation metastable tetragonal-$ZrO^{2}$ and MgO. The former increases the residual strength after thermal-shock test and the latter improves the thermal-shock resistance due to thermal conduction through the continuous magnesia phase and the formation of monoclinic phase content in matrix were increased with decreasing the aging temperature from $1400^{\circ}C$ to $1200^{\circ}C$. Galvanic potential of the aged specimen exhibited a proper emf characteristic.

• Journal of the Korean GEO-environmental Society
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• v.11 no.4
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• pp.13-18
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• 2010

The present study was undertaken to investigate the characteristic of suspended matter in soils of Imha-Dam area by turbidity. Soil sampling was conducted at 5 points of Yeongyang (Turbid area) and 2 points of Cheongsong (Clean area). Experimental analysis was conducted using those samples. The pH of water in the soils at turbid area was higher than that of clean area. X-ray diffraction analysis showed that every sample consists in mainly quartz, illite and feldspar before precipitation. After precipitation for 3 days, the content of quartz and feldspar was decreased and the content of illite was increased at turbid area. The soil of Sinheung (St. 6) at clean area was analyzed only illite. SEM-EDS analysis showed the much content of $SiO_2$ as to every sample before precipitation, but $K_2O$, MgO, $Al_2O_3$, CaO and $Fe2O_3$ with illite was increased after precipitation for 3 days as to every sample. Experimental results exhibited that the major mineral of turbid water was illite at turbid area and clean area.

• Journal of the Korean Geotechnical Society
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• v.15 no.1
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• pp.113-125
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• 1999

In this study the occurrence and mineralogical characteristics of clay minerals from the Munhyun-dong landslide area in Pusan city were examined by XRD, SEM, and chemical analyses. Several types of clay minerals such as halloysite, vermiculite, mica/vermiculite interstratified mineral, vermiculite/smectite interstratified mineral, kaolinite and illite are found abundantly in the area. The occurrence of clay minerals suggest that they have been formed by weathering of andesite which is the bedrock of the area. It is believed that halloysite was formed in the early stage of weathering, and vermiculite, mica/vermiculite interstratified mineral and mica/vermiculite interstratified mineral were formed in the middle stage, and finally, kaolinite was formed. The clay minerals occurring in the central part of the landsliding area and within the slip surface are dominated by expandable minerals such as halloysite, vermiculite and vermiculite/smectite interstratified mineral. These clay minerals expand by absorbing water and effectively decrease the shear resistance of the rock mass, and therefore, they could be an important factor for the landslide. The analyses of geology and mineralogical characteristics of the area suggest that the landslide was caused by combination of various factors including steep slope, heavy rainfall, abundant joints, alteration of the rocks, and occurrence of expandable clay minerals. The result of this study suggests that the investigation for the prevention of possible landslide must include the examination of clay mineralogy as well as the site geology.

• Journal of the Korean Electrochemical Society
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• v.15 no.2
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• pp.95-100
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• 2012

$LiFePO_4$ is an attractive cathode material due to its low cost, good cyclability and safety. But it has low ionic conductivity and working voltage impose a limitation on its application for commercial products. In order to solve these problems, the iron($Fe^{2+}$)site in $LiFePO_4$ can be substituted with other transition metal ions such as $Mn^{2+}$ in pursuance of increase the working voltage. Also, reducing the size of electrode materials to nanometer scale can improve the power density because of a larger electrode-electrolyte contact area and shorter diffusion lengths for Li ions in crystals. Therefore, we chose electrospinning as a general method to prepare $Li[Fe_{0.9}Mn_{0.1}]PO_4$ to increase the surface area. Also, there have been very a few reports on the synthesis of cathode materials by electrospinning method for Lithium ion batteries. The morphology and nanostructure of the obtained $Li[Fe_{0.9}Mn_{0.1}]PO_4$ nanofibers were characterized using scanning electron microscopy(SEM). X-ray diffraction(XRD) measurements were also carried out in order to determine the structure of $Li[Fe_{0.9}Mn_{0.1}]PO_4$ nanofibers. Electrochemical properties of $Li[Fe_{0.9}Mn_{0.1}]PO_4$ were investigated with charge/discharge measurements, electrochemical impedance spectroscopy measurements(EIS).

• Applied Chemistry for Engineering
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• v.26 no.2
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• pp.145-153
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• 2015

$Cr_2O_3/AP$ (ammonium perchlorate) energetic composites were prepared by a method of solvent/anti-solvent. XRD analysis revealed that the crystalline structure of AP in $Cr_2O_3/AP$ composites is the same as that of pure AP. SEM photomicrograph shows that an average size of cuboid $Cr_2O_3/AP$ composites is approximately $2.5{\mu}m$. TGA analysis shows that the addition of submicron $Cr_2O_3$ particles into AP lowers the HTD (high-temperature decomposition) compared to that of neat AP and the activation energy of the $Cr_2O_3/AP$ composites was calculated by the isoconversional Starlink method. Considering changes in the activation energy, the decomposition reaction mechanism of AP was suggested as follows; the decomposition with the formation of nucleation sites renders formation of porous structure in the composites up to conversion of about 0.25 and after further conversion of over 0.3, it seems that decomposition reaction vigorously takes place rather than sublimation of AP.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.507-511
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• 2005

울돌목은 조류발전의 세계적인 최적지로 꼽히고 있으며 서해와 남해의 점이 지대로서 조류에 의해 해양 생물 군집의 대량 이동이 빈번한 곳이라 할 수 있다. 조류 발전 시설인 터빈의 가동은 물리적인 충격에 의해 해양 생물의 생태-생리 반응에 영향을 미칠 가능성이 있다. 네트를 이용한 1차 조사에서 터빈 가동에 의한 동물플랑크톤의 순 사망률은 $44.3\%$로 나타났다. 1차 조사 이 후 다이아프램 펌프를 이용한 조사 결과 중 출현 개체수가 높았던 조사에서 전체 동물플랑크톤의 순 사망률은 각각 $7.3\%,\;5.8\%$를 나타내었고, 요각류는 각각 $4.4\%,\;5.2\%$를 나타냈다. 물리적인 충격을 인위적으로 가한 실험에서 스트레스를 받은 요각류 Acartia hongi의 알 생산은 스트레스를 받지 않은 것보다 $1.8\~2.3$배 낮은 경향을 보였다. 본 조사에서 동물플랑크톤이 낮은 사망률을 보골 이유는 작은 크기의 생물이 우점하였기 때문이며 조사 결과에서 몸체가 비교적 단단하고 크기가 작은 요각류는 상대적으로 약한 부유유생보다 높은 생존율을 보였다. 울돌목 조사 해역에서 출현한 동물플랑크톤은 크기가 작아 터빈의 물리적인 충격에 의한 사망률은 낮을 수 있으나 순간적으로 강한 스트레스를 받는다면 재생산을 포함한 생리활동이 저하될 수 있음을 보였다. 네트 및 펌프를 이용한 조사 결과에서 네트에 의한 채집은 터빈의 영향뿐만 아니라 빠른 유속으로 인하여 네트가 받는 압력에 의해 생물체가 손상되는 양상이 높아 사망률이 높았던 것으로 보인다. 그러나 다이아프램 펌프는 생물 채집 시 오류를 최소화하는 장점은 있으나 채집의 장시간에 비해 매우 적은 생물량이 채집되는 단점을 보였다TEX>$96.5\%$에 미달하는 문제는 식물성 원료유로 제조한 고순도 바이오디젤과 혼합 사용하거나 감압 증류 공정을 통해 고농도의 폐식용유 바이오디젤을 제조하여 해결 가능하다. 대전시 신성동 소재의 음식점에서 수거한 폐식용유를 원료로 하여 생산한 바이오디젤의 차량 배출가스 실증 테스트 결과 경유 차량의 주 오염물질인 PM과 Soot 및 기타 오염물질의 배출량은 감소하였으나 NOx의 배출량은 약간 증가하는 것으로 나타났다구와 이해를 바탕으로 보존대책이 마련되어야 한다.되었다. 이런 모든 시편들을 각 탈염방법에 따라 탈염처리한 후 XRD와 SEM-EDS으로 분석한 결과 인철광과 침철광은 어떠한 변화도 보이지 않았고, 다만 적금광으로 동정된 시편만이 잔존하지 않았다. 철기 제작별 $Cl^-$ 이온 추출량과 탈염효과에 대한 비교 실험은 이온 크로마토그래피 분석 결과와 마찬가지로 단조 철제유물이 주조 철제보다 $Cl^-$ 이온을 많이 가지고 있었으며, 탈염 처리 후에는 $Cl^-$ 이온은 전혀 발견되지 않았다. 이상의 결과 $K_2CO_3$와 Sodium 용액은 탈염처리에서 가장 적합한 탈염처리 용액으로 알수가 있었으며 특히 어떠한 탈염 용액으로 유물을 처리한다 해도 철제유물에 생성된 부식물은 제거되지 않는다는 것을 알게 되었다. 따라서 보존처리자는 유물 표면의 부식 상태만을 보고 처리하기 보다는 철기제작물로 고려하여 처리하는 것이 필요하다. 또한 금속에 부식을 야기시키는 $Cl^-$ 이온과 부식물을 완전하게 제거하여 탈염처리를 하는 것이 유물 부식을 최대한 지연시킬 수 있는 것이라 생각된다.TEX>$88\%$)였다.(P=0.063). 결론: 본