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Electrochemical Properties of $Li_xV_3O_8$ Composite Cathode for All-solid state Rechargeable Battery (고체전지용 $Li_xV_3O_8$ Composite 정극의 전기화학적 특성)

  • 김종욱;성창호;구할본;박복기
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.9
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    • pp.733-738
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    • 1998
  • 본 논문에서는 고체 리듐 전지를 개발하기 위하여 poly(ethylene oxide) [PEO] 에 $LiClO_4$, poly (vinylidene fluoride) [PVDF] 및 가소제로 propylene carbonate [PC] 와 ethylene carbonate[EC] 등을 혼합여 고분자 저해질을 제조하였다. 또한 고체 리듐 전지용 정극으로써 우수한 특성이 기대되는 $Li_xV_3O_8$을 졸-겔법에 의해 합성하여 $Li_xV_3O_8$SPE/Li cell 의 전기화학적 특성을 측정하였다. 고분자 matrix는 PEO와 PVDE를 혼합 사용한 결과 $PEO_4 PVDF_4LiCIO_4PC_5EC_5$ 고분자 전해질이 상온에서 $5.2 {\times} 10{-3}$ S/cm 의 높은 이온 전도도를 나타냈으며 리듐 이온 transference number는 0.3이었다. 졸-겔법에 의해 제조된 $Li_xV_3O_8$을 사용한 $Li_xV_3O_8$SPE/Li cell의 방전시 cell 저항이 방전 초기에는 비소한 증가를 하다가 방전 말기 전압인 2.0V에서 크게 증가하였다. $Li_xV_3O_8$ composite 정극의 첫 번째 방전 용량은 295㎃h/g이었으며 8번째 충방전 싸이클부터 방전 용량이 안정화 되었고 15번째 방전 용량도 212㎃h/g으로 고체 전지용 정극으로써 우수한 특성을 보였다.

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A study on Mossbauer Spectra of the $Ni_{1-x}Cd_xFeAlO_4$ system ($Ni_{1-x}Cd_xFeAlO_4$계의 Mossbauer 스펙트럼 연구)

  • 고정대;홍성락;백승도
    • Journal of the Korean Magnetics Society
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    • v.8 no.4
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    • pp.192-197
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    • 1998
  • The Mossbauer spectra of the $Ni_{1-x}Cd_xFeAlO_4$ system were investigated with the Cd content x at room temperature. The spectra of the samples exhibit various patterns as follows 1) superparmagnetic relaxation for 0$\leq$x$\leq$0.2, 2) ferrimagnetic sextet for 0.3$\leq$x$\leq$0.5, 3) ferromagnetic relaxation for x=0.6, 0.7, 4) paramagnetic doublet for 0.8$\leq$x$\leq$1, with the Cd content x. In the samples with x values from 0 to 0.2, the substituted $Cd^{2+}$ ions transfer the $Al^{3+}$ ions from A-site to B-site mainly. The superparamagnetic relaxation effect and the ferromagnetic relaxation effect are derived from the $Al^{3+}$, $Cd^{2+}$ respectively. The magnetic structure of the $Ni_{1-x}Cd_xFeAlO_4$ system was explained by the Yafet-Kittel model.

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The Dielectric Properties of $Ba_{1-x}A-x(Mg_{1/3}Nb_{2/3})O_3$ (A = Sr, Ca) Ceramics ($Ba_{1-x}A-x(Mg_{1/3}Nb_{2/3})O_3$ (A = Sr, Ca) 세라믹스의 유전특성)

  • 김부근;김재윤;김강언;정수태;조상희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.248-251
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    • 1999
  • The microwave dielectric properties of The Dielectric Properties of $Ba_{1-x}$A$_{x}$(Mg$_{1}$3/Nb$_{2}$3/)O$_3$ (A = Sr, Ca, x = 0, 0.2 ,0.4 ,0.6, 0.8, 1.0) were investigated. In composition of $Ba_{1-x}$A$_{x}$(Mg$_{1}$3/Nb$_{2}$3/)O, densities are decreased with increasing x values. Grain sizes are decreased with Sr content and Increased with Ca content. The hexagonally ordered superstructure was observed in $Ba_{1-x}$Sr$_{x}$(Mg$_{1}$3/Nb$_{2}$3/)O$_3$(BSMN) systems, the intensity of superlattice increased with x value. In $Ba_{1-x}$Cr$_{x}$(Mg$_{1}$3/Nb$_{2}$3/)O$_3$(BSMN) systems, the additional diffraction patterns were shown. The highest value of $\varepsilon$$_{r}$ was shown in x=0.2 of BCMN systems and the value was 41.9. The highest Q$\times$f was shown in x=0.2 of BSMN systems and the value was 68,000. $\tau$$_{f}$ were shown 0 ppm/$^{\circ}C$ near x=0.8.TEX> near x=0.8.0.8.

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Electrochemical Deposition of $CdSe_xTe_{1-x}$ Thin Films and Analysis of Their Crystal Structure (전착법에 의한 $CdSe_xTe_{1-x}$ 박막의 제작과 결정구조 분석)

  • Kim, Young-You;Lee, Ki-Seon
    • Solar Energy
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    • v.10 no.3
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    • pp.53-59
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    • 1990
  • [ $CdSe_xTe_{1-x}$ ] ($0{\le}x{\le}1$) thin films were deposited cathodically on Ti substrates in aqueous sulfric acid solution containing 1M $CdSO_4$ and 1mM$(TeO_2+SeO_2)$. The limiting current was observed in deposition potential ranging from -0.20 to -0.65 vs.Ag/AgCl ; although its value has changed a little depending on the mole ratio x, the limiting current was almost constant in deposition potential of -0.45V in spite of the change of mole ratio x. The crystal structure of the $CdSe_xTe_{1-x}$ thin films was cubic zinc-blonde in the range of mole ratio $x=0{\sim}0.8$, and hexagonal wurtzite in the mole ratio x=1 When the mole ratio changed from x=0 to x=0.8, diffraction peaks was shifted to the larger diffraction angle.

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Magnetic and Electric Properties of Perovskite Manganite $La{1-x}Ba_xMnO_3(0\leqx\leq1)$ (페로브스카이트 망간산화물 $La{1-x}Ba_xMnO_3(0\leq \chi \leq1)$의 자기적, 전기적 특성)

  • 남윤성;이재은;신현수;주홍렬
    • Journal of the Korean Magnetics Society
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    • v.10 no.3
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    • pp.133-138
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    • 2000
  • We have investigated some crystallographic, magnetic, and transport properties of the first colossal magnetoresistive compounds $La_{1-x}Ba_{x}MnO_3(0\leq\chi\leq$1)$(5\;K\leqT\leq360K,-5T\leqH\leq5T$ and resistivity $(100K\leqT\leq350K$measurements. $La_{1-x}Ba_{x}MnO_3$ were found to be ferromagnetic for all x.The $La_{1-x}Ba_{x}MnO_3$were found to be insulating for x< 0.2, metallic for 0.20.5. The magnitude of saturation magnetization (Ms) increased until x=1/8 and had theoretical maximum Ms for 0.13$\sfrac{3}{8}$ and had a constant value of 335~340 K for x>$\sfrac{3}{8}$. For $x\geq0.5$ the $La_{1-x}Ba_{x}MnO_3$ samples showed a percolation-type conduction behavior and enhanced low field magnetoresistance caused by simultaneous occurrence of the chemical/magnetic phase separation.

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Relationship between Meteorological Factors and Lint Yield of Monoculture Cotton in Mokpo Area (목포지방 기상요인과 단작목화의 생육 및 섬유수량과의 관계)

  • 박희진;김상곤;정동희;권병선;임준택
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.40 no.2
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    • pp.142-149
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    • 1995
  • This study was conducted to investigate the relationships between yearly variation of climatic components and yearly variations of productivity in monoculture cotton. In addition, correlation coefficients among yield and yield components were estimated. The data of yield and yield components from the four varieties(Kinggus, Yongdang local. 113-4, 380) were collected from 1978 to 1992 in Mokpo area. The meteorological data gathered at the Mokpo Weather Station for the same period were used to find out the relationships between climatic components and productivity. Yearly variation of the amount of precipitation and number of stormy days in July are large with coefficients of the variations(C.V)84.89 and 97.05%, respectively, while yearly variation, of the average temperature, maximum temperature, minimum temperature from May to Sep. are relatively small. Seed cotton yield before frost in Sep. and Oct. very greatly with C.V. of 68.77, 78.52%, respectively. Number of boll bearing branches and lint percentage show more or less small in C.V. with 11.77 and 19.13%, respectively and flowering date and boll opening date show still less variation. Correlation coefficients between precipitation in May and number of boll bearing branches, duration of sunshine in July and number of bolls per plant, maximum temperature in July and total seed cotton before the frost in Sep., Oct., and Nov. evaporation in Aug. are positively sig-nificant at the 1% level. There are highly significantly positive correlated relationships among yield(total seed cotton) and yield components. Total seed cotton yield(Y) can be predicted by multiple regression equation with independent variables of climatic factors in July such as monthly averages of average temperature($X_1$), maximum temperature($X_2$) and minimum temperature($X_3$), monthly amount of precipitation ($X_4$), evaporation($X_5$), monthly average of relative humidity($X_6$), monthly hours with sunshine($X_7$) and number of rainy days($X_8$). The equation is estimatedas Y =-1080.8515 + 144.7133$X_1$+15.8722$X_2$ + 164.9367$X_3$ + 0.0802$X_4$ + 0.5932$X_5$ + 11.3373$X_6$ + 3.4683$X_7$- 9.0846$X_8$. Also, total seed cotton yield(Y) can be predicted by the same method with climatic components in Aug., Y =2835.2497 + 57.9134$X_1$ - 46.9055$X_2$ - 41.5886X$_3$ + 1.2559$X_5$ - 21.9687$X_6$ - 3.3763$X_7$- 4.1080$X_8$- 17.5586$X_9$. And the error between observed and theoretical yield were less with approached linear regression.

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Enhanced-TCM CODEC Development for Next Generation Terrestrial DTV Transmission System (차세대 지상파 DTV 전송시스템을 위한 Enhanced-TCM CODEC 개발)

  • Kim Sung-Hoon;Ji Kum-Ran;Lee Jae-Youn;Kim Seung-Won;Lee Soo-In;Kim Chang-Joong;Lee Ho-Kyoung
    • Journal of Broadcast Engineering
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    • v.10 no.1 s.26
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    • pp.14-21
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    • 2005
  • This paper described an Enhanced-xVSB system for improving mobile/pedestrian reception performance to the ATSC(Advanced Television System Committee) DTV 8-VSB transmission standard. E-xVSB system can transmit a mixture of normal (8-VSB) stream and enhanced (robust) stream. The robust stream has a higher threshold of visibility (TOV) compared to the standard stream, and legacy receivers ignore the robust packets. Thus, Enhanced-xVSB system is fully backward compatible with a current ATSC standard. For mobile and portable reception support, E-xVSB system adopts a reduced constellation methodas well as enhanced trellis-coded modulation scheme. E-xVSB system supports a variety of enhanced modulation schemes : Pseudo-2VSB, Enhanced-4VSB, modified Enhanced-8VSB and Hybrid-VSB. Proposed E-xVSB system performs well under serious dynamic multipath reception environment.

Charge/discharge Properties of $Li_xV_3O_8$ Composite Cathode for Lithium Polymer Batteries (리튬 폴리머 전지용 $Li_xV_3O_8$ Composite Cathode의 충방전 특성)

  • Park, B.G.;Kim, J.U.;Park, G.C.;Gu, H.B.
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1591-1593
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    • 1997
  • The purpose of this study is to research and develop $Li_xV_3O_8$ composite cathode for lithium polymer battery. We investigated electrochemical, interfacial properties and charge/discharge cycling of $Li_xV_3O_8$/SPE/Li cell. The radius of semicircle associated with the interfacial resistance of $Li_xV_3O_8$/SPE/Li cell increased very slowly during discharge process from 100% SOC to 90% SOC. And then the cell resistance was increased at discharge process from 10% SOC to 0% SOC. The discharge capacity based on $Li_xV_3O_8$ was 212mAh/g at 15th cycle. The $Li_xV_3O_8$/SPE/Li cell has a good properties.

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Optimized Binary Field Reduction Algorithm on 8-bit ATmega128 Processor (8-bit ATmega128 프로세서 환경에 최적화된 이진체 감산 알고리즘)

  • Park, Dong-Won;Kwon, Heetaek;Hong, Seokhie
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.25 no.2
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    • pp.241-251
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    • 2015
  • In public-key cryptographic system based on finite field arithmetic, it is very important to challenge for implementing high speed operation. In this paper, we focused on 8-bit ATmega128 processor and concentrated on enhancing efficiency of reduction operation which uses irreducible polynomial $f(x)=x^{271}+x^{207}+x^{175}+x^{111}+1$ and $f(x)=x^{193}+x^{145}+x^{129}+x^{113}+1$. We propose optimized reduction algorithms which are designed to reduce repeated memory accesses by calculating final reduced values of Fast reduction. There are 53%, 55% improvement when proposed algorithm is implemented using assembly language, compare to previous Fast reduction algorithm.