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Crystal Structure and Magnetic Properties of $(LaS)_xCrS_2(x{\approx}1.20)$ ($(LaS)_xCrS_2(x{\approx}1.20)$의 결정구조와 자기적 특성)

  • Jo, Nam-Ung;Yu, Gwang-Su;Jeong, Hyeong-Jin
    • Korean Journal of Materials Research
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    • v.4 no.6
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    • pp.704-709
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    • 1994
  • The $(LaS)_xCrS_2(x \approx 1.20$) of the incommensurate misfit layer was systhesized from reactant mixture of$La_S_3$,Cr and S at 1273K. Powder X-ray diffration of $(LaS)_xCrS_2(x \approx 1.20$) was indexed as a complex structure consisted with a monoclinic LaS-sublattice, a triclinic $CrS_{2}$-sublattice and their superlattice. The temperature dependence of sublattice dimension was investigated by the X-ray diffraction analysis at low temperature. The magnetic susceptibility of $(LaS)_xCrS_2(x \approx 1.20$) was measured between 77K and room temperature using a Faraday balance method. $(LaS)_xCrS_2(x \approx 1.20$) was paramagnetic on a $\sigma$-H plot at room temperature. The observed effective magnetic moment( p dr) was in fair agreement with the value calculated by spin-only contribution for $Cr^{3+}$ and spin and orbital contribution for $La^{3+}$.

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Decomposition of Triclosan onto E-beam Process using a Design of Experiment(DOE) (전자빔을 이용한 triclosan 제거에 있어서 실험계획법의 이용)

  • Jang, Tae-Bum;Lee, Si-Jin
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.6
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    • pp.51-57
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    • 2012
  • This study investigated on the photolytic degradation of Triclosan by E-beam process. The optimization of process was investigated during a series of batch experiments by design of experiments(DOEs). The DOE was one of the statistical application that was used for designed the response surface to determine the effects of each parameters. The responses were applied as removal rate of Triclosan(%, $Y_1$) and TOC removal rate(%, $Y_2$). Two independent variables were concentration of Triclosan and irradiation intensity that were designed as "$x_1$" and irradiation intensity was designed as "$x_2$". The regression equation in coded parameter between the Triclosan removal efficiencies(%) and TOC removal efficiencies(%) was $Y_1=63-12.4335x_1+15.1835x_2+5.8125x{_1}^2-5.6875x{_2}^2-0.75x_1x_2(R^2=95.1%,\;R^2(Adj)=91.7%)$ and $Y_2=46-8.8462x_1+11.7175x_2-0.75x{_1}^2-6.25x{_2}^2(R^2=98.7%,\;R^2(Adj)=97.7%)$, respectively. The model predictions agreed well with the experimentally observed results $R^2$ and $R^2(Adj)$ over 90% within both of $Y_1$ and $Y_2$. This result shows that the regression model express well about the effects of parameters on E-beam process and the statistical method was successfully applied.

Eu3+ Luminescence in Two-Dimensional Sr2-2xEuxKxSnO4 with K2NiF4 Structure (2차원적 K2NiF4형 구조의 Sr2-2xEuxKxSnO4에서 Eu3+ 이온의 Luminescence)

  • Yo, Chul-Hyun;Minh Chau, P.T.;Ryu, Kwang-Hyun;Kim, Anh-T.
    • Journal of the Korean Chemical Society
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    • v.41 no.4
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    • pp.175-179
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    • 1997
  • Luminescence of $Eu^{3+}$ has been studied in $Sr_{2-2x}Eu_xK_xSnO_4$ with two-dimensional $K_2NiF_4$ structure. The $^5D_o$$^7F_o$$Eu^{3+}$ ion represents the J=0 → J=0 transition which is forbidden by a Judd-Ofelt selection rule for electric dipole transition in 4f shell of $Eu^{3+}$ ions. However, the emission line of $^5D_o$$^7F_o$$Eu^{3+}$ emission spectra of Sr2-2xEuxKxSnO4$Sr_{2-2x}Eu_xK_xSnO_4$structure around $Eu^{3+}$ ions.

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Synthesis and Superconductivity in $(Ru_{0.8}Nb_{0.2})Sr_2(Gd_{1.5-x}Nd_xCe_{0.5})Cu_2O_z$ System ($(Ru_{0.8}Nb_{0.2})Sr_2(Gd_{1.5-x}Nd_xCe_{0.5})Cu_2O_z$ 계의 합성 및 초전도 특성)

  • Lee, H.K.;Bae, S.M.
    • Progress in Superconductivity
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    • v.10 no.2
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    • pp.128-132
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    • 2009
  • Polycrystalline samples of $(Ru_{0.8}Nb_{0.2})Sr_2(Gd_{1.5-x}Nd_xCe_{0.5})Cu_2O_z$($ 0{\leq}x{\leq}1.25$) have been synthesized by a solid-state reaction route. The X-ray diffraction data revealed that the Nd solubility limit can be placed between x=0.5 and x=0.75. The superconducting transition temperature decreased with increasing Nd content, confirming that Nd entered the lattice. Room-temperature thermoelectric power measurements showed that all the samples are in the underdoped state and the partial substitution of Nd for Gd resulted in a decrease in the carrier density on the superconducting layers.

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FUNCTIONAL EQUATIONS ASSOCIATED WITH INNER PRODUCT SPACES

  • Park, Choonkil;Huh, Jae Sung;Min, Won June;Nam, Dong Hoon;Roh, Seung Hyeon
    • Journal of the Chungcheong Mathematical Society
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    • v.21 no.4
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    • pp.455-466
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    • 2008
  • In, [7], Th.M. Rassias proved that the norm defined over a real vector space V is induced by an inner product if and only if for a fixed integer $n{\geq}2$ $$n{\left\|{\frac{1}{n}}{\sum\limits_{i=1}^{n}}x_i{\left\|^2+{\sum\limits_{i=1}^{n}}\right\|}{x_i-{\frac{1}{n}}{\sum\limits_{j=1}^{n}x_j}}\right\|^2}={\sum\limits_{i=1}^{n}}{\parallel}x_i{\parallel}^2$$ holds for all $x_1,{\cdots},x_{n}{\in}V$. Let V,W be real vector spaces. It is shown that if a mapping $f:V{\rightarrow}W$ satisfies $$(0.1){\hspace{10}}nf{\left({\frac{1}{n}}{\sum\limits_{i=1}^{n}}x_i \right)}+{\sum\limits_{i=1}^{n}}f{\left({x_i-{\frac{1}{n}}{\sum\limits_{j=1}^{n}}x_i}\right)}\\{\hspace{140}}={\sum\limits_{i=1}^{n}}f(x_i)$$ for all $x_1$, ${\dots}$, $x_{n}{\in}V$ $$(0.2){\hspace{10}}2f\(\frac{x+y}{2}\)+f\(\frac{x-y}{2} \)+f\(\frac{y}{2}-x\)\\{\hspace{185}}=f(x)+f(y)$$ for all $x,y{\in}V$. Furthermore, we prove the generalized Hyers-Ulam stability of the functional equation (0.2) in real Banach spaces.

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CaxSr2-xSiO4:Eu2+ Green-emitting Nano Phosphor for Ultraviolet Light Emitting Diodes

  • Kim, Jong Min;Choi, Hyung Wook
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.5
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    • pp.249-252
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    • 2014
  • The aim of this work is to investigate the effect of $Ca_xSr_{2-x}$ and activator on the structural and luminescent properties of green-emitting $Ca_xSr_{2-x}SiO_4:Eu^{2+}$ nano phosphor. Using urea as fuel and ammonium nitrate as oxidizer, $Ca_xSr_{2-x}SiO_4:Eu^{2+}$ has been successfully synthesized, using a combustion method. The particles were found to be small, spherical and of round surface. SEM imagery showed that the phosphors particles are of nanosize. The $Ca_xSr_{2-x}SiO_4:Eu^{2+}$ emission spectrum for 360 nm excitation showed a single band, with a peak at 490 nm, which is a green emission. The highest luminous intensity was at $1,000^{\circ}C$, which was obtained when the $Eu^{2+}$ content (y) was 0.05. The results support the application of $Ca_xSr_{2-x}SiO_4:Eu^{2+}$ phosphor as a fluorescent material for ultraviolet light-emitting diodes (UV-LEDs). Characteristics of the synthesized $Ca_xSr_{2-x}SiO_4:Eu^{2+}$ phosphor were investigated by means of X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), and photoluminescence (PL) detection.

RECURRENCE RELATIONS FOR QUOTIENT MOMENTS OF THE EXPONENTIAL DISTRIBUTION BY RECORD VALUES

  • LEE, MIN-YOUNG;CHANG, SE-KYUNG
    • Honam Mathematical Journal
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    • v.26 no.4
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    • pp.463-469
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    • 2004
  • In this paper we establish some recurrence relations satisfied by quotient moments of upper record values from the exponential distribution. Let $\{X_n,\;n{\geq}1\}$ be a sequence of independent and identically distributed random variables with a common continuous distribution function F(x) and probability density function(pdf) f(x). Let $Y_n=max\{X_1,\;X_2,\;{\cdots},\;X_n\}$ for $n{\geq}1$. We say $X_j$ is an upper record value of $\{X_n,\;n{\geq}1\}$, if $Y_j>Y_{j-1}$, j > 1. The indices at which the upper record values occur are given by the record times {u(n)}, $n{\geq}1$, where u(n)=min\{j{\mid}j>u(n-1),\;X_j>X_{u(n-1)},\;n{\geq}2\} and u(1) = 1. Suppose $X{\in}Exp(1)$. Then $\Large{E\;\left.{\frac{X^r_{u(m)}}{X^{s+1}_{u(n)}}}\right)=\frac{1}{s}E\;\left.{\frac{X^r_{u(m)}}{X^s_{u(n-1)}}}\right)-\frac{1}{s}E\;\left.{\frac{X^r_{u(m)}}{X^s_{u(n)}}}\right)}$ and $\Large{E\;\left.{\frac{X^{r+1}_{u(m)}}{X^s_{u(n)}}}\right)=\frac{1}{(r+2)}E\;\left.{\frac{X^{r+2}_{u(m)}}{X^s_{u(n-1)}}}\right)-\frac{1}{(r+2)}E\;\left.{\frac{X^{r+2}_{u(m-1)}}{X^s_{u(n-1)}}}\right)}$.

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The Photovoltaic Effect of Iodine-Doped Metal Free Phthalocyanine/ZnO System (Ⅱ). The Photovoltaic Effect of $ZnO/H_2Pc(I)_x$ Dispersed in Poly(9-vinylcarbazole) (요오드가 도핑된 무금속 프탈로시아닌/산화아연계의 광기전력 효과 (Ⅱ). Poly(9-vinylcarbazole)에 분산된 $ZnO/H_2Pc(I)_x$계의 광기전력 효과)

  • Heur, Soun-Ok;Kim, Young-Soon
    • Journal of the Korean Chemical Society
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    • v.39 no.3
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    • pp.176-185
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    • 1995
  • To improve photosensisitizing efficiency of ZnO/$H_2Pc(I)_x$ system, ZnO/$H_2Pc(I)_x$ system was dispersed in a typical photoconductive polymer of poly(9-vinylcarbazole)(PVCZ). The iodine dopant level(x) of ZnO/${\chi}-H_2Pc(I)_x$ is proportional to concentration of iodine, whereas x of ZnO/${\beta}-H_2Pc(I)_x$ decreased from the highest x=0.97 at more than $6.3{\times}10^{-3}$ M iodine solution. The Raman spectra of ZnO/${\chi}-H_2Pc(I)_x$ at 514 nm exhibited characteristic $I_3^-$ patterns in the range of 50∼550 $cm^{-1}$ at $x{\geq}0.57.$ The surface photovoltage of ZnO/${\chi}-H_2Pc(I)_{0.48}$/PVCZ was approximately 1.6 times greater than ZnO/${\chi}-H_2 Pc(I)_{0.48}$ and was 1.8 times of ZnO/${\chi}-H_2Pc(I)_{0.57}$/PVCZ at 670 nm. With ZnO/$H_2Pc(I)_x$/PVCZ, the highest iodine dopant levels showed a higher photovoltage. Therefore the injection of holes from H2Pc into PVCZ resulted in that photosensisitizing effect of ZnO/$H_2Pc(I)_x$/PVCZ system was improved compared to ZnO/$H_2Pc(I)_x$ case.

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Prediction of 2X Vibration of a Generator Rotor with Asymmetric Shaft Stiffness (비대칭 축 강성을 가지는 발전기 회전자의 2X 진동 예측)

  • Park, C.H.;Kim, Y.C.;Cho, K.G.;Yang, B.S.
    • Journal of Power System Engineering
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    • v.11 no.1
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    • pp.16-19
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    • 2007
  • The large generator rotor used in fossil power plant has the possibility of high 2X vibration due to asymmetric shaft stiffness. The generator rotor is machined into pole faces to reduce stiffness difference and then is tested through 2X vibration measurement when the balancing works are performed in the balancing shop. However, there are many cases of large difference values between 2X vibration in the balancing shop and 2X vibration in site. This paper presents a new method to estimate 2X vibration in site with more accuracy and applied for the retrofit of a fossil 400 MW class deteriorated generator. It shows that the new generator rotor is manufactured with a good 2X vibration characteristics and is operated in a low 2X vibration level although the generator rotor has high 2X vibration in the balancing shop.

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ADDITIVE ρ-FUNCTIONAL INEQUALITIES

  • LEE, SUNG JIN;LEE, JUNG RYE;SEO, JEONG PIL
    • The Pure and Applied Mathematics
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    • v.23 no.2
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    • pp.155-162
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    • 2016
  • In this paper, we solve the additive ρ-functional inequalities (0.1)${\parallel}f(x+y)+f(x-y)-2f(x){\parallel}$ $\leq$ ${\parallel}{\rho}(2f(\frac{x+y}{2})+f(x-y)-2f(x)){\parallel}$, where ρ is a fixed complex number with |ρ| < 1, and (0.2) ${\parallel}2f(\frac{x+y}{2})+f(x-y)-2f(x)){\parallel}$ $\leq$ ${\parallel}{\rho}f(x+y)+f(x-y)-2f(x){\parallel}$, where ρ is a fixed complex number with |ρ| < 1. Furthermore, we prove the Hyers-Ulam stability of the additive ρ-functional inequalities (0.1) and (0.2) in complex Banach spaces.