• Journal of the Korean Vacuum Society
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• 제17권3호
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• pp.247-252
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• 2008

By using the transmission anode x-ray tube developed to apply to the hand-held XRF equipment, we carried out XRF experiment and evaluated the influences of the x-ray tube on XRF spectra. XRF data, which is measured using the W-target and Rh-target tube, were good agreements with the known results. FWHM of Fe $K_{\alpha}$-line measured by W-target tube with the 35 kV-tube voltage and the $40{\mu}A$-tube current was 180 eV. This result reveals that our XRF equipment using the transmission anode x-ray tube is enough for a qualitative analysis of materials. By comparison XRF data with the integrated intensity of x-ray tube, it was confirmed that Rh-target tube is better than W-target tube for application to the hand-held XRF equipment.

• Journal of the Korean Vacuum Society
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• 제17권3호
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• pp.234-239
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• 2008

Tungsten and rhodium target tube for a 40 kV x-ray transmission anode was developed to apply to the hand-held XRF(X-Ray Fluorescence) apparatus and its characteristics were evaluated. From the measurement of the energy distribution and dose of x-ray, it was confirmed that our results were good agreements with the known ones. The optimum thickness of metal film deposited on Be window to extract the maximum dose were $2.6{\mu}m$ and $2.7{\mu}m$ in case of W-target tube and Rh-target tube, respectively. When it was continuously worked during 30 min. at 40 kV in tube voltage and at $60{\mu}A$ in tube current, the temperature at target did not exceed $50^{\circ}C$. Our results reveals that the 40 kV x-ray transmission anode tube can be applied to the hand-held XRF apparatus.

• Journal of the Korean Vacuum Society
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• 제20권6호
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• pp.409-415
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• 2011

The method to improve the detection sensitivity of Hand-held XRF (X-Ray Fluorescence) device currently being developed is discussed. To minimize the loss of the intensity due to atmospheric gas molecules, the vacuum module, which can be filled with atmospheric or He gas, between the sample and the detector was installed. And the change of the detection sensitivity was measured in a vacuum and in the He gas-filled state. As a result, the following three important results were obtained; Firstly, XRF intensity was increased 2~4 times in the low energy range (3~4 keV). It is a very important result because the enhancement of the detection sensitivity means shortening of the detection time in Hand-held XRF device. Secondly, the possibility of detection of the elements less than 3 keV in emission energy was confirmed. Thirdly, the absorption by atmospheric gas molecules can be minimized without vacuum- sealed vessel in Hand-held XRF device, if the vacuum module filled with He gas is used. We concluded that all of three results are very meaningful in the development of a Hand-held XRF device.

• Analytical Science and Technology
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• 제26권5호
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• pp.340-351
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• 2013

The chemical element and structural characterization of different types of cements and its brick stones are been investigated under forensic aspects using X-ray florescence (XRF) and X-ray diffraction (XRD) spectrometer. The XRF provides rapid compositional data for controlling almost all stages of raw materials, clinker and cement. The decisive advantage of XRD methods is based on the unique character of the diffraction patterns of crystalline substances, the ability to distinguish between elements and their oxides, and the possibility to identify chemical compounds, polymeric forms, and mixed crystals by non-destructive examination. Therefore, combination of these examinations is useful and able to apply for the forensic analysis in comparison of cements and brick stones. There are more study remained to determine the viability of method for forensic analysis of brick stones and the limits of the discrimination that can be achieved.

• Proceedings of the Korean Geotechical Society Conference
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• 한국지반공학회 1999년도 가을 학술발표회 논문집
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• pp.75-80
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• 1999

In this study, clay sampled from Yangsan$.$Mulkum site were used to analyze mineral properties. Mineral and chemical properties of clay were investigated through X-ray fluorescence spectrometer(XRF), X-Ray Diffraction(XRD), and Scanning Electron Microscope(SEM) analysis. The result of this test represents that Yangsan$.$Mulkum clay are composed of quartz, albite, anorthite, orthocalse and illite.

• Journal of the Korea institute for structural maintenance and inspection
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• 제27권6호
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• pp.130-137
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• 2023

By using XRF (X-ray fluorescence), this study investigates the variation of chemical properties in cement pastes at elevated temperatures. High-temperature conditions were prepared by using an electric furnace, planning a total of 11 target temperatures ranging from room temperature to 1000 ℃. A standard library of geo-quant basic was applied for the analysis of 12 elements in cement paste, including Ca, Si, Al, Fe, S, Mg, Ti, Sr, P, Mn, Zn and K. The results revealed that, as the temperature increased, the proportion of each element in the cement paste also increased. With the exception of a few elements present in extremely low amounts in the cement pastes, the variation in the composition ratio of most elements exhibited a strong correlation with temperature, with an R-squared value exceeding 0.98. In this study, cement pastes exposed to normal and high-temperature environments were compared. The authors established that the reasons for the different results in this comparison can be explained from the same perspective as when comparing raw cement with cement paste. Furthermore, this study discussed the potentially most dominant parameter when investigating the properties of cement paste using XRF.

• Korean Journal of Soil Science and Fertilizer
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• 제49권6호
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• pp.635-643
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• 2016

Wine consumers desire to drink a high quality wine. For producing high quality wine, high quality soil is required. Conventionally, soil quality is assessed qualitatively. Using traditional laboratory methods, quantitative data can be obtained for management purpose, but it is time consuming and expensive. Therefore, new technology aims to address these limitations, namely portable X-Ray fluorescence spectrometers (pXRF). This instrument can be used directly in the field, requires no soil sample preparations, and can simultaneously measure a wide range of elements qualitatively that are useful for pedological studies. The chemical composition (Ca, Fe, Ti and Zr) of soils at Tallavera Grove vineyard in New South Wales, Australia, was studied using a pXRF. The analysis of the soil's elemental concentration (i.e. Ca and Fe) using pXRF supports management decisions. Measuring the soil's Ca concentration can be used to identify Ca-rich parent materials (limestone). The limestone indicates good soil conditions for vine production. Fe content was used to identify areas of texture-contrast soils or soil with accumulation of clays in the B horizon. In addition, a soil weathering index was calculated using elemental concentrations (i.e. Ti and Zr) to explore the history of soil formation for making decision of management. This index showed that the soil in the vineyard was affected by two processes: the deposition of materials from elsewhere (Aeolian transport or soil erosion) and mixing of materials from upslope.

• Korean Journal of Food Science and Technology
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• 제48권5호
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• pp.418-423
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• 2016

This study was conducted to identify the geographical origin of soybeans in Cheonggukjang by analyzing its organic components and inorganic elements with Fourier transform near-infrared spectroscopy (FT-NIRS) and with energy dispersive X-ray fluorescence (ED-XRF) coupled with multivariate statistical analysis. For method development, 280 samples from various regions were collected and analyzed. The discriminant accuracy for the developed methods was 97.5% for FT-NIRS and 98.0% for ED-XRF with multivariate statistical analysis. A validation test confirmed the discriminant accuracy to be 96.3% for FT-NIRS and 95.0% for ED-XRF. Overall, the results showed that methods using FT-NIRS and ED-XRF could be used to identify the geographical origin of Cheonggukjang.

• Journal of the Korea Academia-Industrial cooperation Society
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• 제13권5호
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• pp.2291-2297
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• 2012

X-ray fluorescence sprectrum signal include the continuum. XRF analysis the components of material by the amplitude of peaks. XRF remove the noise and background. To remove the noise, we apply the smoothing filter. And background removal methods applied such as SNIP, Morphology, Threshold methods. In this paper, we applied Threshold using DWT. Interval threshold method divide the some blocks in particular levels. We propose the method that is divided the particular level.

• Fire Science and Engineering
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• 제29권6호
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• pp.76-83
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• 2015

EPS sandwich panel contains flame retardants that slow down ignition during fires,reduce the amount of heat generated, and block the spread of combustion. However, if a sandwich panel does not satisfy standards for fire-retardant performance, it may increase damage to property and human life. It is difficult to test the fire-retardant performance of a finishing material with the naked eye, so it is necessary to develop convenient and fast evaluation methods that are convenient and fast. In this study, a fire safety evaluation method for EPS sandwich panel was analyzed using X-ray to detect specific components related to the fire-retardant performance X-ray fluorescence analysis (XRF) indicated that suitable panel products contained more aluminum in comparison to unsuitable products. Gibbsite was identified as the main crystalline material of flame retardant EPS through X-ray diffraction analysis (XRD) and was included in both suitable products and unsuitable products, but there was a difference in crystalline structure. This study was verifies the possibility of evaluating fire-retardant performance using ultimate analysis and crystal analysis through these X-ray methods.