• Corrosion Science and Technology
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• 제22권1호
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• pp.36-43
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• 2023

Single-crystal Ni-rich NCM is a material that has drawn attention in the field of lithium-ion batteries due to its high energy density and long cycle life. In this study, we investigated the properties of single-crystal NCM 811 and its potential for use in lithium-ion batteries. High-quality single crystals of NCM 811 were successfully synthesized by crystal growth via a flux method. The single-crystal nature of the samples was confirmed through detailed characterization techniques, such as scanning electron microscopy and x-ray diffraction with Rietveld refinement. The crystal structure and electrochemical performances of the single-crystal NCM 811 were analyzed and compared to its poly-crystal counterpart. The results indicated that single-crystal NCM 811 had electrochemical performance and thermal stability superior to poly-crystalline NCM 811, making it a suitable candidate for high-performance batteries. The findings of this study contribute to a better understanding of the characteristics and potential of single-crystal NCM 811 for lithium-ion batteries.

• 한국결정성장학회지
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• 제7권3호
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• pp.400-405
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• 1997

KCl을 flux로 사용한 용융염 합성법을 이용하여 $Pb(Sc_{1/2}Nb_{1/2})O_3$ 분말을 제조하였다. $700^{\circ}C$부터 $850^{\circ}C$까지의 온도 범위에서 상형성 및 분말 상태의 변화를 조사하였다. 85$0^{\circ}C$에서 2시간동안 하소하였을 때 순수한 $Pb(Sc_{1/2}Nb_{1/2})O_3$상이 형성되었으며, 평군 입자 크기는 0.5 $\mu \textrm{m}$ 이하이었다. 시차열분석, X-선 회절 분석, 미세구조 변화를 통해 결과를 고찰하였다.

• 한국결정성장학회지
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• 제15권3호
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• pp.99-103
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• 2005

NaCl-KCl을 flux로 사용한 용융염 합성법을 이용하여 $Pb(Sc_{1/2}Ta_{1/2})O_3$, 분말을 제조하였다. $700^{\circ}C$에서 $800^{\circ}C$의 온도범위에서 상형성 및 분말 상태의 변화를 조사하였다. 용융염 합성법으로 $750^{\circ}C$ 2시간 하소하였을 때, 순수한 페로브스카이트 구조를 가진 $Pb(Sc_{1/2}Ta_{1/2})O_3$ 상이 형성되었으며, 평균 입자 크기는 $0.5\{mu}m$ 이하이고 입방체와 유사한 형상을 갖는 분말이 제조되었다. DIA, X-선 회절 분석, 미세구조 변화를 통해 합성된 분말의 특성을 고찰하였다.

• 연구논문집
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• 통권31호
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• pp.5-14
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• 2001

These days, interest in the leaching of hazardous heavy metals to consist of incinerator fly ash is increasing, because the heavy metals that leach from the incinerator fly ash pollute the soil and ground water. Therefore this study was undertaken to crystallize the fly ash and prevent the leaching of hazardous heavy metals from fly ash. The concentrations and the leaching concentration of hazardous heavy metals(Cd, Cr, Hg, Pb, Zn) in the law incinerator fly ash have been measured. The fly ash was melted with two kinds of flux($Na_2CO_3, CaCO_3$) and its add quantity(0, 1, 2, 3 wt%). The crystal structure of melting materials was analyzed by SEM(Scaning Electron Microscope) and X-RD(X-Ray Diffractometer). The leaching test of melting materials was undertaken. And the relation between crystallization of melting materials and flux and leaching concentration. These experiments indicate that the concentration and leaching concentration of heavy metals in incinerator fly ash was much higher than the regulatory standard for leachates in Korea and U.S.A and average concentration of heavy metals in soil. And the crystal structure was better.

• 한국재료학회지
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• 제15권6호
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• pp.382-387
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• 2005

Polyvinylidene fluoride (PVDF) surface was irradiated and became superhydrophilic by low energy (180 eV) and high flux $(\~10^{15}/cm{\cdot}s)$ ion beam. As an ion source, a closed electron Hall drift thruster of $\phi=70mm$ outer channel size without grid was adopted. Ar, $O_2$ and $N_2O$ were used for source gases. When $N_2O^+$ and $O_2^+$ reactive gas ion beam were irradiated with the ion fluence of $5\times10^{15}/cm^2$, the wetting angle for deionized water was drastically dropped from $61^{\circ}\;to\;4^{\circ}\;and\;2^{\circ}$, respectively. Surface energy was also increased up to from 44 mN/m to 81 mN/m. Change of chemical component in PVDF surface was analyzed by x-ray photoelectron spectroscopy. Such a great increase of the surface energy was intimately related with the increase of hydrophilic group component in reactive ion irradiated PVDF surfaces. By using an atomic force microscopy, the root-mean-square of surface roughness of ion irradiated PVDF was not much altered compared to that of pristine PVDF.

• 한국결정성장학회지
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• 제15권3호
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• pp.120-123
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• 2005

[ $Li_2CO_3-V_2O_5$ ], flux를 사용한 liquid phase epitaxy(LPE) 법을 사용하여 $LiNbO_3$ (001) 기판위에 5 mol% ZnO가 첨가된 $LiNbO_3$, 박막과 2 mol% MgO가 첨가된 $LiNbO_3$, 박막을 성장시켰다. $Zn:LiNbO_3$, 막과 $Mg:LiNbO_3$, 막과의 결정성과 격자 부정합은 x-ray rocking curve(XRC)로 분석되었다. 그리고 다층 박막의 단면에서의 ZnO와 MgO의 분포가 electron probe micro analyzer(EPMA)를 사용하여 관측되었다.

• Membrane and Water Treatment
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• 제8권5호
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• pp.437-448
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• 2017

A high quality Na-X zeolite membrane was synthesized on a seeded ${\alpha}-alumina$ disc by the secondary growth method. Structural characterization was done by X-ray spectroscopy, FT-IR spectroscopy, SEM and AFM imaging. The performance evaluation of the membrane was firstly tested in separation of glucose/water solutions by pervaporation process. There was obtained a separation factor $182.7{\pm}8.8$, while the flux through the membrane was $3.6{\pm}0.3kg\;m^{-2}\;h^{-1}$. The zeolite membrane was then used for desalination of aqueous solutions consisting of $Na^+$, $Ca^{2+}$, $Cs^+$ and $Sr^{2+}$ because of the importance of these ions in water and wastewater treatments. The effects of some parameters such as temperature and solution concentration on the desalination process were studied for investigating of diffusion/adsorption mechanism in membrane separation. Finally, high water fluxes ranged from 2 up to $9kg\;m^{-2}\;h^{-1}$ were obtained and the rejection factors were resulted more than 95% for $Na^+$ and $Ca^{2+}$ and near to 99% for $Cs^+$ and $Sr^{2+}$. Based on the results, fluxes were significantly improved due to convenient passage of water molecules from large pores of NaX, while the fouling was declining dramatically. Based on the results, NaX zeolite can efficiently use for the removal of different cations from wastewaters.

• Macromolecular Research
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• 제10권1호
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• pp.2-12
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• 2002

The small-angle X-ray scattering (SAXS) beamline BL4C1 at the 2.5 GeV storage ring of the Pohang Accelerator Laboratory (PAL) has been in its first you of operation since August 2000. During this first stage it could meet the basic requirements of the rapidly growing domestic SAXS user community, which has been carrying out measurements mainly on various polymer systems. The X-ray source is a bending magnet which produces white radiation with a critical energy of 5.5 keV. A synthetic double multilayer monochromator selects quasi-monochromatic radiation with a bandwidth of ca. 1.5%. This relatively low degree of monochromatization is sufficient for most SAXS measurements and allows a considerably higher flux at the sample as compared to monochromators using single crystals. Higher harmonics from the monochromator are rejected by reflection from a flat mirror, and a slit system is installed for collimation. A charge-coupled device (CCD) system, two one-dimensional photodiode arrays (PDA) and imaging plates (IP) are available its detectors. The overall performance of the beamline optics and of the detector systems has been checked using various standard samples. While the CCD and PDA detectors are well-suited for diffraction measurements, they give unsatisfactory data from weakly scattering samples, due to their high intrinsic noise. By using the IP system smooth scattering curves could be obtained in a wide dynamic range. In the second stage, stating from August 2001, the beamline will be upgraded with additional slits, focusing optics and gas-filled proportional detectors.

• Journal of Astronomy and Space Sciences
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• 제18권1호
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• pp.1-6
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• 2001

In this paper we investigate the properties of advection-dominated accretion flows (ADAFs) in case that outflows carry away infalling matter with its angular momentum and energy. Positive Bernoulli number in ADAFs allow a fraction of the gas to be expelled in a form of outflows. The ADAFs are also unstable to convection. We present self-similar solutions for advection-dominated accretion flows in the presence of outflows from the accretion flows(ADIOS). The axisymmetric flow is treated in variables integrated over polar sections and the effects of outflows on the accretion flow are parameterized for possible configurations compatible with the one dimensional self-similar ADAF solution. We explicitly derive self-similar solutions of ADAFs in the presence of outflows and show that the strong outflows in the accretion flows result in a flatter density profile, which is similar to that of the convection-dominated accretion flows(CDAFs) in which convection transports the angular momentum inward and the energy outward. There two different versions of the ADAF model should show similar behaviors in X-ray spectrum to some extent. Even though the two models may show similar behaviors, they should be distinguishable due to different physical properties. We suggest that for a central object of which mass is known these two different accretion flow should have different X-ray flux value due to deficient matter in the wind model.

• 한국작물학회지
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• 제2권
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• pp.46-49
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• 1964

1. 본 시험에 사용된 선량범위내에서는 기건종자에 의한 Thermal neutron이나 X-ray의 처리가 발아율에 크게 영향을 미치지 못하였는데 Fast neutorn 처리종자의 발아율은 선량의 증가에 따라 거의 직선적 저하를 보였다. 2. 선량의 증가에 따라 기형엽발생율은 증가하였으며 특히 Fast neutron에서는 동일 flux일망정 Thermal neutron 조사구에 비해 발생율은 높다. 3. 저선량에서의 기형엽출현은 유식물기에서만 봇 수 있으며 성장함에 따라 회복한다. 이는 정상세포와 이상세포간의 분열속도의 차에 기인되는 상 싶다. 4. 같은 선량에서는 Fast neutron이 Thermal neutron에 비해 그 영향력이 크다는 것이 확실하며 이는 Energy의 차에서 오는 결과이다. 5. 일반적으로 선량의 증가에 따라 성숙이 연장되는 경향이 있었으며, 반면에 아주 희귀하기는 하나 개화와 성숙이 촉진되는 고체도 발견되었다. 6. 선량의 증가에따라 다소 왜소화되기는 하나 저선량에서는 오히려 유의성은 없으나 초장이 증가하였다. 7. 생육초기와 생육종기에 있어서의 선량에 따르는 초장에 대한 영향은 그 초기에 있어서 더 현저하며 성장함에 따라 회복되는 경향을 보인다. 8. 발아와 생육에 별 지장이 없이 재배할 수 있는 선량범위는 Thermal neutron에서 $1O^13$ N/$cm^2$, Fast neutron에서 5$\times$$1O^12$N/$cm^2$ 이하이면 무난할 것이며, X-ray는 본 시험에 이용한 32 Kr 이상에서도 이용에 지장이 없을 것이다.