• Title/Summary/Keyword: Wood decomposition

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Combustion Characteristics and Thermal Properties for Wood Flour-High Density Polyethylene Composites (목분-고밀도폴리에틸렌 복합체의 연소성 및 열적특성)

  • Shin, Baeg-Woo;Chung, Kook-Sam
    • Fire Science and Engineering
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    • v.26 no.1
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    • pp.89-95
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    • 2012
  • In this study, we were manufactured wood flour-HDPE composites by modular co-rotating twin screw extruder with L/D ratio of 42. We was measured cone calorimeter test and thermogravimetric analysis (TGA) to find the combustion characteristics and thermal properties for wood flour-HDPE composites. We then evaluated the effect of three additive-type flame retardants on fire resistance performance. The cone calorimeter test showed that the heat release rate (HRR) of untreated composites was the highest Peak HRR ($446.6kW/m^2$) as well as Mean HRR ($185.5kW/m^2$). From the TGA, it was shown that composites added flame retardants began early thermal decomposition and improved thermal stability.

Evaluation on Physical and Mechanical Properties of Wood Plastic Composites Treated under Ultraviolet Irradiation (자외선을 처리한 목재 플라스틱 복합재의 물리 및 역학적 성질 평가)

  • Lee, Jong-Shin;Kim, Soung-Joon
    • Journal of the Korea Furniture Society
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    • v.26 no.4
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    • pp.428-434
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    • 2015
  • In this study, we received each wood plastic composites (WPC) from three manufacturers. These WPCs were evaluated regarding their physical and mechanical properties of both before and after accelerated weathering by ultraviolet (UV) irradiation. The total time of exposure of the WPCs to UV irradiation was 1800 h. The water absorption, volumetric swelling and shrinkage of WPCs did not affected by UV irradiation. Among the mechanical properties, there was no significant differences in bending strength and screw withdrawal resistance of UV treated WPCs compared with those of reference WPCs. However, surface hardness of WPCs showed decrease under UV irradiation. Stereoscopic microscopy observation revealed deterioration of the surface layer polymer in all weathered WPCs by UV. Exposure of the WPCs to UV irradiation caused decomposition and disappearance of the polymer layer. From this result, we can estimate that damage of polymer by UV led to a decrease in the surface hardness of the WPCs. The wood flours retained original shape after accelerated weathering by UV irradiation.

Carbon and Nitrogen Dynamics of Wood Stakes as Affected by Soil Amendment Treatments in a Post-Fire Restoration Area (산불 훼손 복원지 내 토양개량제 처리가 Wood stakes의 탄소 및 질소 동태에 미치는 영향)

  • Park, Seong-Wan;Baek, Gyeongwon;Byeon, Hee-Seop;Kim, Yong Suk;Kim, Choonsig
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.20 no.4
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    • pp.357-365
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    • 2018
  • This study was carried out to evaluate the weight loss rates, carbon and nitrogen dynamics of wood stakes following soil amendment treatments (CLB: compound fertilizer + lime + biochar; LB: lime + biochar) in a post-fire restoration area, Ulsan Metropolitan city, southern Korea. Soil amendments in the fire-disturbed area were applied to two-times (Mar. and Jun. 2015, 2016) during the study period. Wood stakes on Mar. 2015 were buried at a top 15cm of mineral soil in two soil amendment and control treatments of Liriodendron tulipifera, Prunus yedoensis, Quercus acutissima, Pinus thunbergii plantations and an unplanted area in the post-fire restoration area. Wood stakes were collected at Oct. 2015, Mar. 2016 and Oct. 2016 to measure weight loss rates, organic carbon and nitrogen concentrations. Weight loss rates of wood stakes were not significantly affected by soil amendment treatments. However, remaining carbon of wood stakes were lowest in the control treatment (43.7%), followed by the CLB (71.3%) and the LB (71.6%) treatments. Remaining nitrogen of wood stakes was less in the control treatment (29.7%) compared with the LB treatment (52.6%). The results indicate that carbon and nitrogen mineralization of wood stakes in post-fire restoration area were delayed by soil amendment treatments.

Microbial Conversion of Woody Waste into Sugars and Feedstuff (I) - Optimal Delignification condition with alkaline peroxide for enzymatic hydrolysis of poplar wood (미생물(微生物)에 의한 목질자원(木質資源)의 당화(糖化) 및 사료화(飼料化)에 관(關)한 연구(硏究) (I) - alkaline peroxide에 의한 현사시나무의 효소가수분해를 위한 탈리그닌화의 적정조건)

  • Kim, Yoon-Soo;Bang, Joo-Wan;Chung, Ki-Chul;Myung, Kyu-Ho;Kim, Youn-Sik
    • Journal of the Korean Wood Science and Technology
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    • v.14 no.3
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    • pp.23-29
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    • 1986
  • Alakline peroxide pretreatment for the delignification of poplar wood was performed. sinceit is a simple and efficent method for enhancing the enzymatic digestibility of wood residues. Approximately one-half of their lignin and most of the hemicellulose present in poplar wood were removed when the wood sawdust was reacted at 25$^{\circ}C$ for 100 hrs in an alkaline solution (pH 11.5) of 1% peroxide. The rate of decomposition as well as the saccharification efficiency were enhanced up to 350% and 260% respectively in comparision with those of the controll. This enhancement is comparable with that pretreated with 1% sodium hydroxide and 20% peracetic acid successively. The advantages of alkaline peroxide as delignifying agents against other chemicals were also discussed.

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Analysis on Thermogravimetric Characteristics about Copyrolysis of Waste Wood Chip and Linear Low Density Polyethylene (선형 저밀도 폴리에틸렌과 폐목재 우드칩 혼합열분해의 열중량 특성 분석)

  • Lee, Young-Man;Bae, Wookeun;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.22 no.1
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    • pp.87-90
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    • 2011
  • Copyrolysis of biomass/plastic mixture was carried out from room temperature to $600^{\circ}C$ with varing the heating rates of 10, 20, and $30^{\circ}C/min$ using a thermogravimetric analyzer. Waste wood chip (WWC) and linear low density polyethylene (LLDPE) were selected as a biomass and plastic, respectively. Individual pyrolysis temperature ranges were $430{\sim}550^{\circ}C$ and $230{\sim}600^{\circ}C$ for LLDPE and WWC, respectively. For the copyrolysis of WWC and LLDPE, the decomposition temperature range of WWC was not varied, while the decomposition temperature range of LLDEP was increased to a higher temperature. The results imply that the interaction might occur between LLDEP and WWC during copyolyis of LLDPE and WWC.

Fused Filament Fabrication of Poly (Lactic Acid) Reinforced with Silane-Treated Cellulose Fiber for 3D Printing

  • Young-Rok SEO;Birm-June KIM
    • Journal of the Korean Wood Science and Technology
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    • v.52 no.3
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    • pp.205-220
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    • 2024
  • Various polylactic acid (PLA) blends were reinforced with untreated or silane-treated micro-sized cellulose fiber (MCF), successfully prepared as 3D printing filaments and then printed using a fused filament fabrication (FFF) 3D printer. In this study, we focused on developing 3D-printed MCF/PLA composites through silane treatment of MCF and investigating the effect of silane treatment on the various properties of FFF 3D-printed composites. Fourier transform infrared spectra confirmed the increase in hydrophobic properties of silane-treated MCF by showing the new absorption peaks at 1,100 cm-1, 1,030 cm-1, and 815 cm-1 representing C-NH2, Si-O-Si, and Si-CH2 bonds, respectively. In scanning electron microscope images of silane-treated MCF filled PLA composites, the improved interfacial adhesion between MCF and PLA matrix was observed. The mechanical properties of the 3D-printed MCF/PLA composites with silane-treated MCF were improved compared to those of the 3D-printed MCF/PLA composites with untreated MCF. In particular, the highest tensile and flexural modulus values were observed for S-MCF10 (5,784.77 MPa) and S-MCF5 (2,441.67 MPa), respectively. The thermal stability of silane-treated MCF was enhanced by delaying the initial thermal decomposition temperature compared to untreated MCF. The thermal decomposition temperature difference at T95 was around 26℃. This study suggests that the effect of silane treatment on the 3D-printed MCF/PLA composites is effective and promising.

Comparison of Efficiency for Wood Fuels (Chips and Pellets) by Life Cycle Assessment (LCA 접근방법에 의한 목질연료(칩, 펠릿)의 효율성 비교)

  • Choi, Young-Seop;Kim, Joon-Soon;Cha, Du-Song
    • Journal of Korean Society of Forest Science
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    • v.98 no.4
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    • pp.426-434
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    • 2009
  • This study was carried out to derive the most optimal production process for the wood fuels(chip and pellet), by collecting cost data on each procedure through the life cycle assessment approach, and to compare between the profitability and efficiency, from the view points of producers and consumers, irrespectively. The costs accounted in this analysis were based on the opportunity cost. The results show that wood chips are cheaper than wood pellets in production costs. In respect to the process with the lowest production cost, while wood chips should be to crush collected residues into pieces on the spot for merchandizing, wood pellets need to be transported to manufactory for pelletizing. The study findings also include that the profits, which is estimated by subtracting expenses from gained sale revenue, were a bit higher for wood chips than wood pellets. Additionally, the price ratio of wood pellets to wood chips for getting the same caloric value appears to be 1.27. Despite of economic benefits of processing wood chips, there are several problems in practice. For producers, there is a possible increase in not only transportation cost for conveying crushers to the dispersed places, but storage cost due to the lack of the marketplaces in the immediate surroundings. For consumers, on the other hand, there are some challenging issues, such as bulky storage facility requirement, additional labor for fuel supplement, frequent ashes disposal, and decomposition in summer and freezing in winter caused by wood chips' own moisture.

Analysis of Structure and Physical and Chemical Properties of the Carbonized Powder of Pine Wood (Pinus densiflora Sieb. et Zucc.) (II) - FT-IR, Raman - (가열처리 및 탄화처리 소나무재(Pinus densiflora) 목분의 구조 및 물리·화학적 특성(II) - FT-IR, Raman -)

  • Lee, In-Ja;Lee, Won-Hee
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.4
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    • pp.52-57
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    • 2008
  • In this study, the effects of carbonization temperature on the physico-chemical properties of porous wood charcoal are studied by FT-IR and Raman spectroscopies. IR studies showed that cellulose and hemicellulose are mostly decomposed in the precarbonization stage at $500^{\circ}C$, while the decomposition reaction of relatively more stable lignin lasts up to $700^{\circ}C$. Above $900^{\circ}C$, the peak at $1575cm^{-1}$ disappears and a new peak at $1630cm^{-1}$, which seems to be related to the new carbon deposit phase, is evolved. The results of Raman studies, which show the red-shift of D-band and the increase in the relative intensity of D- to G-band, indicate that the size of the crystalline becomes smaller with increasing the carbonization temperature.

Microbial Treatment of Saw Dust for Animal Food -(I) Changes of Lignin and Protein Contents- (톱밥을 이용한 미생물사료에 관한 연구 -(I) 리그닌 및 단백질 함량의 변화-)

  • Lee, Bae-Ham
    • The Korean Journal of Mycology
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    • v.3 no.2
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    • pp.25-29
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    • 1975
  • Twelve strains of wood decaying Basidiomycetes were tested for ability to decomposelignin in saw dust of Pine, Quelcus, Rawan and Zelkowa, wood and to transform inorganic nitrogen in the medium into organic crude protein. In this test, one strain of Pleurotus ostreatus showed to be 49% of its ability of lignin decomposition. The increasing rate of the crude protein went up to 26%. It is considered, therefore, saw dust can he a useful animal food by microbial treatment.

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A Study on The Thermal Properties and Activation Energy of Rapidly Torrefied Oak Wood Powder using Non-isothermal Thermogravimetric Analysis (비등온 열중량분석법을 이용한 급속 반탄화 참나무 목분의 열적 특성과 활성화 에너지 연구)

  • Lee, Danbee;Kim, Birm-June
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.1
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    • pp.96-105
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    • 2016
  • This study investigated thermal properties and activation energy ($E_a$) of torrefied oak wood powders treated with various torrefaction times (0, 5, 7.5, 10 min) by using non-isothermal thermogravimetric analysis at heating rates of 10, 20, $40^{\circ}C/min$ to check the feasibility of rapidly torrefied oak wood powders as a fuel. As the torrefaction time increases, onset of thermal decomposition temperature, lignin content, and the amount of final residue of torrefied oak wood powders were accordingly increased with reduced hemicellulose content. $E_a$ was determined by using Friedman and Kissinger models and respective R-square values were over 0.9 meaning very good availability of calculated $E_a$ values. The $E_a$ values of the samples were decreased with the increase of torrefaction time and the lowest $E_a$ value ob served in the torrefied oak wood powders treated for 7.5 min showed high feasibility of rapidly torrefied oak wood powder as a biomass-solid refuse fuel.