• Title/Summary/Keyword: Wet-spinning

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Effect of spinning parameters of polyethersulfone based hollow fiber membranes on morphological and mechanical properties

  • Tewfik, Shadia R.;Sorour, Mohamed H.;Shaalan, Hayam F.;Hani, Heba A.
    • Membrane and Water Treatment
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    • v.9 no.1
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    • pp.43-51
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    • 2018
  • Hollow fiber (HF) membranes are gaining wide interest over flat membranes due to their compaction and high area to surface volume ratio. This work addresses the fabrication of HF from polysulfone (PS) and polyethersulfone (PES) using N-methylpyrrolidone (NMP) as solvent in addition to other additives to achieve desired characteristics. The semi-pilot spinning system includes jacketed vessel, four spinneret block, coagulation and washing baths in addition to dryer and winder. Different parameters affecting dry-wet spinning phase inversion process were investigated. Dope compositions of PES, NMP and polyvinyl pyrrolidone (PVP) of varying molecular weights as additive were addressed. Some critical parameters of importance were also investigated. Those include dope flow rate, air gap, coagulation & washing baths and drying temperatures. The measured dope viscosity was in the range from 1.7 to 36.5 Pa.s. Air gap distance was adjusted from 20 to 45 cm and coagulation bath temperature from 20 to $46^{\circ}C$. The HF membranes were characterized by scanning electron microscope (SEM), atomic force microscope (AFM) and mechanical properties. Results indicated prevalence of finger like structure and average surface roughness from about 29 to 78.3 nm. Profile of stress strain characteristics revealed suitability of the fibers for downstream interventions for fabrication of thin film composite membrane. Different empirical correlations were formulated which enable deeper understanding of the interaction of the above mentioned variables. Data of pure water permeability (PWP) confirmed that the fabricated samples fall within the microfiltration (MF)-ultrafiltration (UF) range of membrane separation.

The Effect of After-treatment on the Permeability of Polysulfone Hollow Fiber Membranes (후처리조건에 따른 한외여과용 폴리설포중공사막의 투과특성에 관한 연구)

  • 박유인;김정훈;이규호
    • Membrane Journal
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    • v.2 no.1
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    • pp.67-73
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    • 1992
  • The effects of after-treatment condition on the permeability of polysulfone hollow fiber membranes were investigated. It was well known that the permeability of and the rejection of hollow fiber membranes prepared by dry-wet spinning technique was highly affected by spinning conditions such as composition of spinning solution, inner and outer coagulant and spinning height. But these are also governed by after-treatment condition such as drying, hot water treatment and glycerine treatment. Since it was difficult to remove DMAc and NMP in membranes by washing with in cold water and even traces of such solvent affected the reproducibility of the membrane characteristics, the hot water-treatment should be required.

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Preperation of fiber and Characterization of Hydroxyapatite/PVA hybrid fiber in Wet spinning (습식방사를 이용한 Hydroxyapatite/PVA 복합섬유의 제조 및 특성)

  • 강성일;정용식;박병기;김환철;이근완
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.325-326
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    • 2003
  • 유기물질과 무기물질의 복합체 제조는 일찍이 1980년대 초부터 연구되어 오고 있고, 새로운 성능 및 기능 확대를 목표로 계속 이루어지고 있다[1-2]. 폴리비닐알코올(Poly(vinyl alcohol), PVA)은 분리막, 투석, 약물전달, 암세포 괴사용 색전제 등 의료 및 산업용 섬유로 널리 사용되고 있는 비닐계 고분자이다[3,4]. 또한 무기화합물인 Hydroxyapatite(HAp)는 칼슘 포스페이트계 세라믹으로, 중금속 흡착성, 항균성, 생체 친화성 등이 우수하여 의료용 소재로 사용되어 오고 있다. (중략)

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Wet Spinning of Silk Polymer(II) -Effect of drawing on the structural characteristics of the filaments- (실크 고분자의 습식방사(II) -연신비에 따른 재생 실크 필라멘트의 구조특성 변화-)

  • 엄인철;기창석;권해용;임대우;박영환
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.111-114
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    • 2002
  • 실크는 우수한 광택, 촉감, 물성을 바탕으로 하여 인류에 있어 최고의 의류용 섬유로서 널리 이용되어 왔으며 최근에는 생체적합성 등을 활용한 의료용 및 생물공학용 소재로서 응용하고자 하는 연구가 활발하게 진행중이다[1-2]. 그러나 실크는 합성섬유와는 달리 누에가 토사하는 그 순간에 그 구조 및 형태가 결정되어 고정되는 단점을 안고 있어 다양한 특성이 요구되는 의류용 및 산업용 분야로의 응용에 한계가 있다. (중략)

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A Study on the Preparation and Properties of Cellulose-EVOH Fibers (Cellulose-EVOH 섬유의 제조와 물성에 관한 연구)

  • 문병화;임상규;손태원;김삼수
    • Textile Coloration and Finishing
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    • v.10 no.5
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    • pp.19-23
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    • 1998
  • In this study, Cellulose-Poly(Ethylene-Co-Vinyl Alcohol) (EVOH) fibers from MMNO(N-me-thylmorpholine-N-oxide) /water/cellulose/EVOH were prepared according to changes of EVOH content(wt%), which is main factors to dry-jet wet spinning. The mechanical properties and morphology of produced fibers were investigated. The resultant fibers had tensile strength of 3.7∼4.5g/d, elongation of 3.3∼7.5% and exhibited lower density than the density of pure cellulose fiber.

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중공사막 PLASMA 고분자 코팅에 관한 연구 - 고분자층 두께분포를 중심으로 -

  • 손우익;구자경;김병식
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.141-142
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    • 1997
  • 1. 서론 : 중공사막은 제조과정인 wet spinning의 과정에서 defect가 형성될 수 있어 분리선택도에 큰 영향을 미친다. 이러한 defect의 처리방법으로는 dipping method등의 방법이 현재 널리 쓰이고 있다. dipping method는 제조된 중공사막을 PDMS등의 고분자 용액 속으로 통과시켜 결과적으로 중공사막 표면에 얇은 고분자막이 형성되도록 하는 방법이다. 그러나 이러한 방법으로 중공사막을 처리할 경우 고분자 용액이 pore내로 침입하거나 중력으로 인하여 용액의 아래쪽으로 몰려 하반부의 두께가 두꺼워진다는 단점이 있다.(생략)

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Wet Spinning of Silk Polymer(I) -Morphological characteristics of regenerated silk fibroin filament- (실크 고분자의 습식방사(I) -재생 실크 필라멘트의 형태학적 구조 특성-)

  • 엄인철;권해용;박영환;임대우
    • Proceedings of the Korean Fiber Society Conference
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    • 2001.10a
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    • pp.123-126
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    • 2001
  • 실크는 우수한 광택, 촉감, 물성을 바탕으로 하여 인류에 있어 최고의 의류용 섬유로서 널리 이용되어 왔으며 최근에는 생체적합성 등을 활용한 의료용 및 생물공학용 소재로서 응용하고자 하는 연구가 활발히 진행 중에 있다[1-2]. 그러나 실크의 경우 누에로부터 얻어지는 천연섬유로서 합성섬유와는 달리 누에로부터 토사되면서 그 구조 및 형태가 결정되어 고정되는 단점을 안고 있어 의류용 및 산업용 분야로의 활용에 있어 한계가 있다. (중략)

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Influences of solvent-exchange drying on the properties of cellulose hollow fiber membranes

  • Jie, Xingming;Cao, Yiming;Wu, Ming;Yuan, Quan
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.69-69
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    • 2004
  • Cellulose hollow fiber membranes (CHFM) were prepared from the cellulose/N-methylmorpholine-N-oxide/$H_2O$ system by immersion-precipitation and wet spinning. Different drying methods were carried out to investigate their influences on the properties of CHFM.(omitted)

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Fabrication and Characteristics of Chitosan Non-woven Fabric developed using only water as plasticizer

  • Lee, Shin-Hee;Hsieh, You-Lo
    • Fashion & Textile Research Journal
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    • v.16 no.2
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    • pp.319-325
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    • 2014
  • This article describes a method for producing chitosan non-woven fabrics by just hot pressing without the use of a binder. A study has been made of the wet spinning of chitosan fiber. The fibers were rinsed thoroughly in running water and chopped wet into staples of with a length of approximately 5-10 mm. The chopped chitosan staples were dispersed uniformly in water and fabricated using a non-woven making machine. This study examined the formation and the characteristics of chitosan non-woven fabrics manufactured by hot pressing without the use of a binder. The effects of the non-woven fabrication conditions on the thermal, morphological, structural, and physical properties of chitosan non-woven fabric with and without water as a plasticizer were studied. The temperature of the exothermic peak, decomposition of chitosan fibers increased with increasing heating rate. Water in the chitosan fiber effectively plasticized the chitosan fiber. The thermal bonded structure of the wet chitosan fiber with water as a plasticizer was clearly found in many parts of the non-woven fabric at a fabrication temperature of $200^{\circ}C$. The intensity and profile of the (100) plane($2{\theta}=10.2^{\circ}$) and (040) plane($2{\theta}=20.9^{\circ}$) in the chitosan non-woven fabric decreases and became smooth in the non-woven fabric formation by melting.

Manufacturing and Material Analysis of Collagen/Chitosan Conjugated Fibers for Medical Application (의료용 소재 활용을 위한 콜라겐/키토산 복합섬유의 제조 및 특성 분석)

  • Gwak, Hyeon Jung;Ahn, Hyunchul;Lee, Won Jun;Yeo, Sang Young
    • Textile Coloration and Finishing
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    • v.33 no.3
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    • pp.131-140
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    • 2021
  • Collagen and chitosan are used in medical and cosmetic materials as natural polymers. In order to utilize the advantages of the materials, collagen/chitosan conjugated wet-spun fibers were prepared. The analysis of surface, optical, thermal and mechanical properties was carried out on the various composition of collagen and chitosan. As a result of images analysis, it was verified that the collagen/chitosan conjugated fibers were stably spun. In addition, the optical and thermal properties of fibers were observed to be changed by hydrogen bond. As a result, an optimized composition could be found at an appropriate content. Moreover, the optimized fibers have mechanical properties similar to chitosan fibers, while improving the structural and thermal stability by its hydrogen bond. In addition, the wet-spun collagen/chitosan conjugated fibers can be applied to medical and various fields through mechanical properties according to content control.