• Title/Summary/Keyword: Wet-reduction process

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The Extraction of Co-PET from Non-Woven Fabrics of Nylon/Co-PET Sea-island Type Composite Microfiber

  • Park, Myung-Soo;Yoon, Jong-Ho;Cho, Dae-Hyun
    • Fashion & Textile Research Journal
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    • v.3 no.5
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    • pp.466-472
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    • 2001
  • To find a suitable condition in this process examined, we investigated the main control factors, such as, the NaOH concentrations, such as, the NaOH concentrations, the heat treating times, and the heating temperatures. The resulting mechanical properties of the fabrics also studied. The samples used were Nylon/Co-PET sea-island type composite microfiber (Co-PET content: 35%) non-woven fabric. The conclusions obtained were as follows. 1. For the complete extraction of Co-PET from the sample non-woven fabric in the dry hot air process, $160^{\circ}C$ of air temperature, 15 min. of treatment time, and around 30% of NaOH concentration were required. On the other hand, in the wet hot air process, $140^{\circ}C$ of air temperature, 3.5 min. of treatment time, and around 30% of NaOH concentration were required. 2. The mechanical properties of the continuous processed samples showed that the WT, B, and WC increased with increasing the weight reduction ratio. However, the G, decreased with increasing the weight loss ratio. Note that, particularly in B, it increased drastically when the weight deduction ratios exceeded 30%. 3. As increasing the wet hot air temperature from 130 to $140^{\circ}C$, B appeared to increase, however, WT, G, and WC appeared to decrease. 4. The best condition found in this continuous process to extract Co-PET is the wet hot air temperature of 140, NaOH concentration of 28% or above, and the treatment time 2-4 min.

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Reduction Effect of Air Cleaner on Particulate Matters and Biological Agents in a Swine Facility (공기정화기 적용에 따른 돈사 작업장내 입자상 물질 및 생물학상 물질 저감 효과에 관한 연구)

  • Kim, Ki Youn
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.27 no.1
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    • pp.70-76
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    • 2017
  • Objectives: This on-site study was performed to evaluate the reduction efficiency of an air cleaner on particulate matters and biological agents in a swine facility. Materials and Methods: Particulate matter was measured using a real-time monitoring recorder and biological agents were sampled with a one-stage impactor and then analyzed based on the microbial culture method. An experimental process for the reduction effect on airborne pollutants through air cleaner operation consisted of three conditions: no treatment, wet scrapper by water spray and wet scrapper by disinfectant spray. Results: Geometric mean levels of particulate matter(TSP, $PM_{10}$, $PM_{2.5}$ and $PM_1$) were presented at $1,608{\mu}g/m^3$, $1,373.8{\mu}g/m^3$, $401.8{\mu}g/m^3$ and $144.5{\mu}g/m^3$ for no treatment; $1,503{\mu}g/m^3$, $1,017{\mu}g/m^3$, $159.4{\mu}g/m^3$ and $69.8{\mu}g/m^3$ for wet scrapper by water spray; and $1,222.17{\mu}g/m^3$, $477.17{\mu}g/m^3$, $33.2{\mu}g/m^3$ and $11.1{\mu}g/m^3$ for wet scrapper by disinfectant spray, respectively. In the case of biological agents, the geometric averaged concentrations of total airborne bacteria and fungi were as follows: $45,371cfu/m^3$ and $13,474cfu/m^3$ for no treatment, $43,286cfu/m^3$ and $8,610cfu/m^3$ for wet scrapper by water spray, and $2,440cfu/m^3$ and 1,867 cfu/ for wet scrapper by disinfectant spray, respectively. Regardless of particulate matter and biological agent, the highest concentrations were found for no treatment, while the lowest concentrations were found with wet scrapper by disinfectant spray. Conclusions: Based on the results obtained from this on-site evaluation, there was a significant reduction effect on particulate matter and biological agents through the application of an air cleaner in this study.

Upgrading of Iron from Waste Copper Slag by A Physico-chemical Separation Process (Physico-chemical 분리 공정에 의한 폐동슬래그로부터 철의 품위향상)

  • Lee, Kwang-Seok;Jo, Seul-Ki;Shin, Doyun;Jeong, Soo-Bock;Lee, Jae-Chun;Kim, Byung-Su
    • Resources Recycling
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    • v.23 no.3
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    • pp.30-36
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    • 2014
  • A large amount of waste copper slag containing about 35 ~ 45% iron has been generated and discarded every year from pyrometallurgical processes for producing copper from copper concentrate. Thus, recovery of iron from the waste copper slag is of great interest for comprehensive use of mineral resource and reduction of environment problems. In this study, a physico-chemical separation process for upgrading iron from the waste copper slag discharged as an industrial waste has been developed. The process first crushes the waste copper slag below 1 mm (first crushing step), followed by carbon reduction at $1225^{\circ}C$ for 90 min (carbon reduction step). And then, resulting material is again crushed to $-104{\mu}m$ (second crushing step), followed by wet magnetic separation (wet magnetic separation step). Using the developed process, a magnetic product containing more than 66 wt.% iron was obtained from the magnetic separation under a magnetic field strength of 0.2 T for the waste copper slag treated by the reduction reaction. At the same conditions, the percentage recovery of iron was over 72%. The iron rich magnetic product obtained should be used as a iron resource for making pig iron.

Effect of Reaction Conditions on the Preparation of Nano-sized Ni Powders inside a Nonionic Polymer

  • Kim, Tea-Wan;Kim, Dong-Hyun;Park, Hong-Chae;Yoon, Seog-Young
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.462-463
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    • 2006
  • Monodispersed and nano-sized Ni powders were synthesized from aqueous nickel sulfate hexahydrate $(NiSO_4{\cdot}6H_2O)$ inside nonionic polymer network by using wet chemical reduction process. The sucrose was used as a nonionic polymer network source. The effect of reaction conditions such as the amount of sucrose and a various reaction temperature, nickel sulfate hexahydrate molarity. The influence of a nonionic polymer network on the particle size of the prepared Ni powders was characterized by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), and particle size analysis (PSA). The results showed that the obtained Ni powders were strong by dependent of the reaction conditions. In particular, the Ni powders prepared inside a nonionic polymer network had smooth spherical shape and narrow particle size distribution.

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Study On the Characteristics of Milled $UO_2$ Powder Prepared by Oxidation and Reduction Process (산화ㆍ환원처리된 $UO_2$ 분말의 분쇄특성 연구)

  • Lee Jae-Won;Lee Jung-Won
    • Resources Recycling
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    • v.11 no.4
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    • pp.3-10
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    • 2002
  • The characteristics of dry and wet milled powder prepared by 1 cycle OREOX (oxidation and reduction of oxide fuels) treatment were investigated using the simulated spent fuel pellet. Sintered pellets simulating spent nuclear fuel burned in reactor were fabricated from $UO_2$ powder using as a starting material in fabrication of nuclear fuel. The 1 cycle OREOX-treated powder was prepared by only one path of oxidation md reduction of the simulated pellet. Powder having average particle size of less than 1 $\mu\textrm{m}$ could be easily obtained by dry milling, but not be achieved by wet milling. And, specific surface area of dry milled pow-der was higher than that of wet milled powder. Dry milled powder formed loose agglomerate, while wet milled powder showed the shape of irregular and angular particles. Dry milled powder provided higher green density, resulting in higher sintered density of higher than 95% TD and average grain size of larger than 8 $\mu\textrm{m}$ satisfying the standard specification of sintered pellets.

Thin Film Battery Using Micro-Well Patterned Titanium Substrates Prepared by Wet Etching Method

  • Nam, Sang-Cheol;Park, Ho-Young;Lim, Young-Chang;Lee, Ki-Chang;Choi, Kyu-Gil;Park, Gi-Back
    • Journal of the Korean Electrochemical Society
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    • v.11 no.2
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    • pp.100-104
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    • 2008
  • Titanium sheet metal substrates used in thin film batteries were wet etched and their surface area was increased in order to increase the discharge capacity and power density of the batteries. To obtain a homogeneous etching pattern, we used a conventional photolithographic process. Homogeneous hemisphere-shaped wells with a diameter of approximately $40\;{\mu}m$ were formed on the surface of the Ti substrate using a photo-etching process with a $20\;{\mu}m{\times}20\;{\mu}m$ square patterned photo mask. All-solid-state thin film cells composed of a Li/Lithium phosphorous oxynitride (Lipon)/$LiCoO_2$ system were fabricated onto the wet etched substrate using a physical vapor deposition method and their performances were compared with those of the cells on a bare substrate. It was found that the discharge capacity of the cells fabricated on wet etched Ti substrate increased by ca. 25% compared to that of the cell fabricated on bare one. High discharge rate was also able to be obtained through the reduction in the internal resistance. However, the cells fabricated on the wet etched substrate exhibited a higher degradation rate with charge-discharge cycling due to the nonuniform step coverage of the thin films, while the cells on the bare substrate demonstrated a good cycling performance.

A Study on the Development of Rolled Dry Floor Heating System for Improving Workability (현장 시공성 개선을 위한 롤타입 건식바닥난방시스템 개발)

  • Lee, Gyu-Dong;Kim, Jun-Ho;Jeong, Chang-Ho;Kim, Dong-Woo;Ogawa, Keiichiro
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.11a
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    • pp.177-180
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    • 2012
  • Korea residential housing generally use wet floor heating system 'Ondol' which consist of insulation cushioning, lightweight foamed concrete, hot water pipe and mortar on top of reinforced concrete slab. Wet floor heating system's installation process is too complicate and difficult to supervise field for continuing assurance quality. Also, this method has a huge impact on the progress of construction because it take a long time to cure finishing mortar and lightweight foamed concrete. Therefore, it is considered a disturbance factor of reduction of construction duration for enhancing competitiveness. In this study, we conducted an experiment about the radiant heat performance and temperature difference on upper panel of rolled dry floor heating systems which is jointly developed by Kolon global and Sumisho Metalex for remodeling housing, studio apartment and the urban-life housing.

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Fabrication of Size- and Shape- Controlled Gold Particles using Wet Chemical Process (환원 석출법을 이용한 모양과 크기가 제어된 금 입자의 제조)

  • Hong, So-Ya;Lee, Chang-Hwan;Kim, Joo-Yong
    • Textile Coloration and Finishing
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    • v.22 no.2
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    • pp.123-131
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    • 2010
  • Shape and size controlled synthesis of gold particles has been studied by using wet-chemical method. When ${AuCl_4}^-$ in aqueous $HAuCl_4$ precursor was reduced using $Na_2SO_3$ as a reducing agent, mixtures of spherical, triangular and hexagonal particles were prepared in a few minutes. It was found that the shape selective oxidative etching by ${AuCl_4}^-\;+\;Cl^-$ anions and crystal growth took place simultaneously. As the ${AuCl_4}^-$ and $Cl^-$ concentration increased, yields of large triangular and hexagonal plate type particles increased, while the spherical particles decreased in most cases. Possible etching and growth mechanisms are discussed.

Fabrication and Characterization of Ag Particles by Polyol Process and Wet Chemical Process (폴리올 공정과 액상 환원 공정에 따른 은 입자 제조 및 특성 평가)

  • Yoo, Juyeon;Jang, Hyosung;Lee, Kun-Jae
    • Journal of Powder Materials
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    • v.23 no.4
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    • pp.297-302
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    • 2016
  • Ag nanoparticles are extensively studied and utilized due to their excellent catalysis, antibiosis and optical properties. They can be easily synthesized by chemical reduction methods and it is possible to prepare particles of uniform size and high purity. These methods are divided into vapor methods and liquid phase reduction methods. In the present study, Ag particles are prepared and analyzed through two chemical reduction methods using solvents containing a silver nitrate precursor. When Ag ions are reduced using a reductant in the aqueous solution, it is possible to control the Ag particle size by controlling the formic acid ratio. In addition, in the Polyol process, Ag nanoparticles prepared at various temperatures and reaction time conditions have multiple twinned and anisotropic structures, and the particle size variation can be confirmed using field emissions scanning electron microscopy and by analyzing the UV-vis spectrum.

Nanoparticles Synthesis and Modification using Solution Plasma Process

  • Mun, Mu Kyeom;Lee, Won Oh;Park, Jin Woo;Kim, Doo San;Yeom, Geun Young;Kim, Dong Woo
    • Applied Science and Convergence Technology
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    • v.26 no.6
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    • pp.164-173
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    • 2017
  • Across the most industry, the demand for nanoparticles is increasing. Therefore, many studies have been carried out to synthesize nanoparticles using various methods. The aim of this paper is to introduce an industry-applicable as well as financially and environmentally effective solution plasma process. The solution plasma process involves fewer chemicals than the traditional kit, and can be used to replace many of the chemical agents employed in previous synthesis of nanoparticles into plasma. In this study, this process is compared to the wet-reaction process that has thus far been widely used in the most industry. Furthermore, the solution plasma process has been classified into four different types (in-solution, out of solution, direct type, and remote type), according to its plasma occurrence position and plasma types. Thus, the source of radicals, nanoparticle synthesis, and modification methods are explained for each design. Lastly, unlike nanoparticles with hydrophilic functional groups that are made inside the solution, a nanoparticle synthesis and modification method to create a hydrophobic functional group is also proposed.