• Membrane Journal
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• v.18 no.2
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• pp.116-123
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• 2008

Proton conductive hybrid nanocomposite polymer electrolyte membranes comprising polystyrene-5-poly (hydroxyethyl methacrylate) (PS-b-PHEMA), sulfosuccinic acid (SA) and phosphotungstic acid (PWA) were prepared by varying PWA concentrations. The PHEMA block was thermally crosslinked by SA via the esterification reaction between -OH of PHEMA and -COOH of SA. Upon the incorporation of PWA into the diblock copolymer, the symmetric stretching bands of the $SO_3^-$ group at $1187cm^{-1}$ shifted to a lower wavenumber at $1158cm^{-1}$, demonstrating that the PWA particles strongly interact with the sulfonic acid groups of SA. When the concentration of PWA was increased to 30wt%, the proton conductivity of the composite membrane at room temperature increased from 0.045 to 0.062 S/cm, presumably due to the intrinsic conductivity of the PWA particles and the enhanced acidity of the sulfonic acid in the membranes. The membrane containing 30wt% of PWA exhibited a proton conductivity of 0.126 S/cm at $100^{\circ}C$. Thermal stability of the composite membranes was also enhanced by introducing PWA nanoparticles.

• Resources Recycling
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• v.20 no.3
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• pp.68-76
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• 2011

For the separation of aluminum and iron from platinum mixtures, extraction resins were synthesized and separation efficiencies were compared with those by commercial one, $P_{204}$. During synthesis, the suspension polymerization method was adopted with D2EHPA as an extractant. Also, benzoyl peroxide as a starter was divided into 3parts and injected for the uniform size and dispersion of resin particles. Comparison tests resulted in 100% separation of Fe and Pt for both synthetic and $P_{204}$ resins. In case of Al and Pt, synthetic and $P_{204}$ resin gave extraction efficiencies of 99.9% and 98.9%, respectively. Difference in extractant contents of synthetic resin(61.8%) and $P_{204}$(60%) was considered to give differences in separation efficiencies of aluminum and iron elements. For both resins, separation efficiencies of Al and Fe increased up to $55^{\circ}C$. According to FT-IR analyses of both resins, specific peaks of D2EHPA and crosslinked polystyrene were identified at the wavenumber of $1000cm^{-1}$ and $2900cm^{-1}$ respectively.

• Economic and Environmental Geology
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• v.29 no.2
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• pp.129-138
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• 1996

The ores of the Bobae mine are mainly composed of sericite and quartz, and with appreciable amount of some other minerals such as andalusite. pyrophyllite, and albite, etc.. Sericite occurs in various a1teration zones having different crystal size and habit. Sericites can be c1assified into two types based on the crystal size; fine-grained and coarse-grained sericite. Fine-grained sericite occurs as an aggregate. Mineralogical characterizations of both types of sericites have been studied with various methods. Lattice parameters of two types of sericites occurred in various alteration zones are almost identical. but b parameter of coarse-grained sericite appears to be slight1y bigger than that of fine-grained aggregates. Average structural formula of fine- and coarse-grained sericite is $K_{1.44}Al_{3.86}(Si_{6.35}Al_{1.65})O_{20}(OH)_4$ and $K_{1.71}Al_{3.82}(Si_{6.20}Al_{1.80})O_{20}(OH)_4$, respectively. Structural formulae of coarse-grained sericites are close to that of muscovite. Infrared spectra show that there is slight distinction between sericites occurred in andalusite-pyrophyllite zone and other subzones. IR spectra of sericites due to Si-O vibration ($540{\sim}530cm^{-1}$) tend to shift to smaller wavenumber side from center to outer alteration zone. All samples have litt1e or no interstratified minerals. and this is demonstrated by Ir and DTA-TG results. It indicates that the Bobae mine is formed at relatively high temperature. That the ratio of quartz to sericite in ores varies greatly indicates that several discontinuous hydrothermal alteration processes have been involved.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.14 no.2
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• pp.127-139
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• 1996

This paper presents a procedure to recover sea surface heights (SSH) and free-air (FA) gravity anomalies from dense satellite altimeter SSH data with enhanced accuracies over the full spectrum of the gravity field. A wavenumber correlation filtering (WCF) of co-linear SSH tracks is developed for the coherent signals of sub-surface geological masses. Orbital cross-over adjustments with bias parameters are applied to the filtered SSH data, which are then separated into two groups of ascending and descending tracks and gridded with tensioned splines. A directional sensitive filter (DSF) is developed to reduce residual errors in the orbital adjustments that appear as track patterned SSH. Finally, FA gravity anomalies can be obtained by the application of a gradient filter on a high resolution estimate of geoid undulations after subtracting dynamic sea surface topography (DSST) from the SSH. These procedures are applied to the Geosat Geodetic Mission (GM) data of the southern oceans in a test area of ca. $900km\;\times{1,200}\;km$ to resolve geoid undulations and FA gravity anomalies to wavelengths of-10 km and larger. Comparisons with gravity data from ship surveys, predictions by least squares collocation (LSC), and 2 versions of NOAA's predictions using vertical deflections illustrate the performance of this procedure for recovering all elements of the gravity spectrum. Statistics on differences between precise ship data and predicted FA gravity anomalies show a mean of 0.1 mgal, an RMS of 3.5 mgal, maximum differences of 10. 2 mgal and -18.6 mgal, and a correlation coefficient of 0.993 over four straight ship tracks of ca. 1,600 km where gravity changes over 150 mgals.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.41 no.6
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• pp.427-434
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• 2008

Processing of collagen from yellowfin tuna (Thunnus albacares) abdominal skins was optimized by response surface methodology and central composite design. The values of independent variables at optimal conditions were NaOH concentration: 0.5 N, NaOH treatment time: 36.2 hr, pepsin concentration: 1:4.9 ratio (0.245%, w/v), and digestion time: 48.1 hr, respectively. The collagen content estimated under optimal conditions was 33.1%, and the actual experimental collagen content was 32.3%. Physicochemical properties of collagen from yellowfin tuna abdominal skin were investigated by amino acids analysis, SDS-PAGE, FT-IR, viscosity and denaturation temperature. Amino acids content of the collagen was 21.0%. SDS-PAGE pattern of the collagen showed two different $\alpha$-chain (${\alpha}_1$- and ${\alpha}_2$- chain), $\beta$-component and $\gamma$-component. The spectrum of FT-IR of the collagen showed wavenumber at 3,434, 1,650, 1,542 and $1,235\;cm^{-1}$ representing the regions of amide A, I, II and III, respectively. Relative viscosity of the collagen decreased continuously on heating up to $32^{\circ}C$, and the rate of decrease was retarded in the temperature range of $35-50^{\circ}C$. Denaturation temperature (Td) of the collagen solution (0.06%, w/v) was $31^{\circ}C$ and was lower than calf skin collagen ($35^{\circ}C$).

• Journal of the Korean earth science society
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• v.39 no.3
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• pp.211-227
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• 2018

This study evaluates the prediction skills of stratospheric polar vortex intensification events (VIEs) in Global Seasonal Forecasting System (GloSea5) model, an operational subseasonal-to-seasonal (S2S) prediction model of Korea Meteorological Administration (KMA). The results show that the prediction limits of VIEs, diagnosed with anomaly correlation coefficient (ACC) and mean squared skill score (MSSS), are 13.6 days and 18.5 days, respectively. These prediction limits are mainly determined by the eddy error, especially the large-scale eddy phase error from the eddies with the zonal wavenumber 1. This might imply that better prediction skills for VIEs can be obtained by improving the model performance in simulating the phase of planetary scale eddy. The stratospheric prediction skills, on the other hand, tend to not affect the tropospheric prediction skills in the analyzed cases. This result may indicate that stratosphere-troposphere dynamic coupling associated with VIEs might not be well predicted by GloSea5 model. However, it is possible that the coupling process, even if well predicted by the model, cannot be recognized by monotonic analyses, because intrinsic modes in the troposphere often have larger variability compared to the stratospheric impact.

• Journal of the Korean Society of Food Science and Nutrition
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• v.43 no.10
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• pp.1535-1542
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• 2014

This study was conducted to investigate the physicochemical properties and biological activities of collagens with different molecular weights from Alaska pollack (Theragra chalcogramma) skin as well as their efficacies as functional materials. The molecular weights of collagens were between 1~10 kDa (below 1 kDa (AP1), 1~3 kDa (AP2), 3~10 kDa (AP3), and above 10 kDa (AP4). The protein content of AP4 (40.19 g/100 g) was the highest. Collagen contents of AP1, AP2, AP3, and AP4 were 36.43, 32.23, 19.23, and 14.89%, respectively. The free amino acid and essential amino acid contents of AP1 were higher than those of AP2, AP3, and AP4. Fourier transform infrared spectroscopy spectra of collagens with different molecular weights showed wavenumbers representing the regions of amide I, amide II, amide III, and amide A, respectively. The electron-donating ability (29.51%) and SOD-like activity (38.45%) of AP1 were higher than those of AP2, AP3, and AP4. Tyrosinase inhibition activity of AP1 improved with higher treatment concentration. The rate of inhibition of MMP-1 production in HS68 cells exposed to UVB was suppressed by treatment with AP1 (29.78%) and AP2 (26.49%) at 1 mg/mL. Furthermore, there was a strong correlation between DPPH, superoxide dismutase, tyrosinase activity, and MMP-1 inhibition rate of collagens with different molecular weights.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.28 no.10
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• pp.788-793
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• 2017

This paper presents the verification of accuracies of theoretical models for calculating the microwave reflections from rough sea surfaces. First of all, the Pierson-Moskowitz ocean spectrum was used to generate the rough sea surfaces. Then the relationship between the significant wave heights, root-mean-square(RMS) heights and wind speed was derived by estimating the significant wave heights and RMS heights of the generated sea surfaces according to various wind speeds, and compared the derived relationship with other measurement data sets. The reflection coefficients of the sea surfaces were calculated by using a numerical method(the moment method). Then, the numerical results were compared with Ament model, PO(Physical Optics) model, GO(Geometrical Optics) model and B-M(Brown-Miller) model for various roughness conditions(wind speed) and incidence angles. It was found that the Ament model is not accurate except for a very low roughness conditions($kh_{rms}$<0.4, k is wavenumber and $h_{rms}$ is RMS height). It was also found that at incidence angles lower than $70^{\circ}$, the PO and the GO models agree well with the numerical results, while the B-M model agrees well with the numerical analysis results at incidence angles higher than $80^{\circ}$ for very rough sea surfaces with $kh_{rms}$>10.

• Korean journal of food and cookery science
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• v.28 no.6
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• pp.711-719
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• 2012

The collagens from squid (Todarodes pacificus) skin and Alaska pollack (Theragra chalcogramma) skin were extracted and their physicochemical properties were investigated. The yield was improved with the increase of NaOH concentration and was increased Neutrase than Alcalase in enzymatic hydrolysates. Protein and collagen contents from Alaska pollack skin were 38.3~62.7% and 13.1~28.9%, respectively. All enzymatic hydrolysates also showed high antioxidant activities as NaOH concentration decrease. Composition of their amino acids was mainly glycine and proline. The spectrum of FT-IR of the collagen showed wavenumber at $1,631cm^{-1}$, $1,549cm^{-1}$, $1,234cm^{-1}$ and $3,322cm^{-1}$ representing the regions of amide I, amide II, amide III and amide A, respectively. The decomposition temperature for the collagen was in the range of $300^{\circ}C$ and showed relatively good enough for their thermal stabilities.

• Geophysics and Geophysical Exploration
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• v.12 no.1
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• pp.143-153
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• 2009

Using a discrete wavenumber method, we examine the effects on Logging-While-Drilling (LWD) logs when a mismatch exists between the amplitudes or generating times of the signals from individual monopoles in a LWD multipole source. An amplitude-mismatched LWD dipole/quadrupole source produces non-dipole/non-quadrupole modes as well as flexural and screw modes. The strongest of non-dipole/non-quadrupole modes is the Stoneley mode, whose amplitude increases with increasing mismatch. However, we can recover the flexural mode signals by A-C processing, and the screw mode by A-B+C-D processing, respectively. The Stoneley mode, which has the same amplitude at the same radial distance from the borehole axis, is cancelled out by A-C and A-B+C-D processing as long as the tool is placed at the centre of the borehole. The responses from a time-mismatched LWD multipole source look like the summation of responses by two or four monopole sources off the borehole axis. However, we can avoid the misinterpretation of the formation velocities by referring to the computed dispersion curves, which are independent of the arrival times of the modes, on the frequency semblance plot.