• Polymer(Korea)
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• v.31 no.5
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• pp.374-378
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• 2007

Water-soluble terpolymer of acrylamide, diacetone acrylamide, and acrylic acid was prepared by redox initiators in aqueous medium. One component photoresist was synthesized by reaction of terpolymer with 4-azidoaniline. By blending the aqueous acrylamide/diacetone acrylamide copolymer solution with bisazide, 4,4'-diazidostilbene -2,2'-disulfuric acid sodium salt, two component photoresist was prepared. The photosensitivity per azido group unit mole of one component photoresist was 4 times higher than that of two component photoresist. The dot-type pattern was successfully achieved with one component photoresist at low exposure energy, which is prospective to be used as black matrix negative photoresist.

• Journal of the korean Society of Automotive Engineers
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• v.14 no.3
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• pp.109-114
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• 1992

The purpose of this study is to experimentally research the effects of polymer additives on turbulent transition of Couette flow between concentric cylinders when outer one is rotating and inner one is at rest; the diameter ratio being 0.2. Aqueous polymer solution generate the degradation phenomena in machine forming work, but this is not effected in about 10 minute at 5ppm. aqueous polymer solution testing. The Reynolds number, referred to the gap distance and rotation velocity of the outer cylinder, of turbulent transition is about 20000 for water flow. In the laminer region, the torque value is as same as theoretical one in the region of low Reynolds number, but becomes high with an increase in the Reynolds number. The polymer additives reduce the Reynolds number for turbulent transtition. In the turbulent region, the torque is remarkably reduced by the polymer additives, soluble polymer take down effect of turbulent transition boundary torque.

• Proceedings of the Korean Fiber Society Conference
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• 2007.11a
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• pp.195-196
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• 2007

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• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2006.11a
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• pp.213-215
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• 2006

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2012.10a
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• pp.111-112
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• 2012

• Journal of Pharmaceutical Investigation
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• v.34 no.4
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• pp.289-297
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• 2004

Acyclovir (ACV) is one of the most effective and selective agents against viruses of the herpes group. Because of low solubility, bioavailability of ACV has shown below 30% with oral dosage form. In our previous study, we reported that the fabrication of solid dispersion of ACV was possible and the solid dispersion of ACV and PVP was the most useful in all samples. In this study, we examined the effect of mixture ratio of polymers (PEG and PVP) to ACV. Solubility of ACV was dramatically increased up to 25 mg/ml in $80^{\circ}C$ distilled water. So water was used as a solvent to eliminate problem of residual solvent. Spray drying method was used for the solid dispersion of ACV as solvent extraction. Different scanning calorimeter was used to check degradation of drug. Polymer carriers were PEG 6,000 and PVP. In summary, ACV-PVP (1:3) showed the best solubility in distilled water.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.17 no.6
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• pp.16-23
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• 2018

A polymer porous sheet, which can be applied to diverse wearable devices, has some advantages such as light-weight, high flexibility, high elongation, and so many others. In order to fabricate a porous sheet, water-soluble particles like sugar were utilized frequently, and there has been great advances. However, with our best knowledge, there are not enough reports on the mechanical behavior of porous sheets having different porosity. So, in this work, we tried to find out the relationship between porosity and mechanical deformation of a porous sheet. The process parameters such as a particle size, sheet thickness and PDMS mixing ratio with curing agent were analyzed on the effect of increasing the porosity of a sheet. Also, mechanical deformation of a sheet was tested using a tensile experiment. Through the experimental results, we make a conclusion that a highly porous sheet with thin thickness has high flexibility, and it deformed nearly double elongation comparing to worst one among nine cases.

• Journal of Pharmaceutical Investigation
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• v.25 no.1
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• pp.31-36
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• 1995

Solid dispersions and inclusion complex were prepared for the enhancement of solubility and dissolution rate of poorly water-soluble ibuprofen(IPF) as a model drug. Polyethylene glycol 4000(PEG4000) and polyvinylpyrrolidone(PVP) were used for the preparation of solid dispersion. $2-Hydroxypropyl-{\beta}-cyclodextrin(2-HP{\beta}CD)$ was also used for the preparation of inclusion complex. The solubility of IPF increased as the concentration of PEG4000, PVP and $2-HP{\beta}CD$ increased. Solubilization capacity of $2-HP{\beta}CD$ was increased about 10 times when compared to PEG 4000 and PVP. The dissolution rate of drug from solid dispersions and inclusion complex in the simulated gastric fluid was enhanced when compared to pure IPF and commercial $BR4^{\circledR}$ tablet as a result of improvement of solubility. In case of solid dispersions, dissolution rate of drug was proportional to polymer concentration in the formulation. The marked enhancement of dissolution rate of drug by inclusion complexation with $2-HP{\beta}CD$ was noted. However, dissolution rate of drug from solid dispersions and inclusion complex in the simulated intestinal fluid was not significant because IPF was readily soluble in that condition. From these findings, water-soluble polymers and cyclodextrin were useful to improve solubility and dissolution rate of poorly water-soluble drugs. However, easiness and reliability of preparation method, scale-up and cost of raw materials must be considered for the practical application of solid dispersion and inclusion complex in pharmaceutical industry.

• Applied Chemistry for Engineering
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• v.25 no.6
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• pp.581-585
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• 2014

We conducted investigation on the hybridization of poly(3,4-ethylenedioxythiophene)/poly(styrene sulfonate) (PEDOT : PSS) with graphene derivative (G-PSS), which has been prepared by wrapping reduced graphene oxide (RGO) with PSS. In situ polymerization of PEDOT/PSS in the presence of G-PSS afforded the PEDOT/PSS and graphene hybrid (GP). The analysis of XPS, IR and Raman spectroscopies for GP showed that PEDOT/PSS was successfully synthesized and hybridized with graphene. Compared to the G-PSS, GP showed an enhanced electrical conductivity of $4.46{\times}10^2S/m$ with a good wter-dispersity.

• Macromolecular Research
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• v.10 no.2
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• pp.103-107
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• 2002

High purity water soluble chitosans (WsCs) were employed as a flocculant to remove heavy metal ions from wastewater of industrial plating wastewater treatment complex. Their weight average molecular weights and polydispersities were 272,000~620,000 g/mol and 1.4~1.9 range, respectively and were readily soluble in water in the pH range of 3~11. Heavy metal ions such as chromium, iron and copper were removed well by WsCs. When WsCs was blended with either sodium N, N-diethyldithiocarbamate trihydrate (SDDC$_{T}$) or sodium salicylate (SSc), the removal efficiency was further increased primarily due to the excess amount of hydrophilic sulfonic and carboxylic groups. Especially, in the case of WsCs-SSc the remaining chromium and copper concentrations were 0.1 mg/L and 9.5 mg/L, which are 1/15 and 1/3 compared with that of pure WsCs, respectively. The former is within the acceptable limit, but the latter is not. Therefore, the effective copper flocculant remains to be studied.d.