• Title/Summary/Keyword: Water exchange

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Molecular Dynamics (MD) Study of Proton Exchange Membranes for Fuel Cells (연료전지용 수소이온 교환막의 분자동역학 연구)

  • Park, Chi Hoon;Nam, Sang Yong;Hong, Young Taik
    • Membrane Journal
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    • v.26 no.5
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    • pp.329-336
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    • 2016
  • Proton exchange membrane (PEM) is one of the key components of membrane-electrode assembly (MEA), which plays important role in fuel cell performance together with catalysts. It is widely accepted that water channel morphology inside PEMs as a proton pathway significantly affects the PEM performance. Molecular dynamics (MD) simulations are a very useful tool to understand molecular and atomic structures of materials, so that many related researches are currently being studied. In this paper, we summarize the current research trend in MD simulations, present which properties can be characterized, and finally introduce the usefulness of MD simulations to the researchers for proton exchange membranes.

Simulation of Flow field and Water exchange Change on the Redevelopment of Busan North Port (부산북항 재개발에 따른 유동장 및 해수교환 변화 모의)

  • Gum, Dong-Ho;Kim, Kang-Min;Lee, Joong-Woo;Jun, Sung-Hwan
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • v.1
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    • pp.425-431
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    • 2006
  • In connection with redevelopment of Busan North Port, there has been lots of studies and efforts for the development of superannuated North general piers into a center of marine tourism and waterfront for the citizens of Busan. Recently it has moved to the stage of execution, after several trials to find concrete solutions. On the other hand, the change of flow field and tidal exchange cuased by redevelopment is one of the important investigation subjects. This study deals with the change of flow field and water exchange after redevelopment using numerical simulation technique, based on the general data which were collected and analyzed. As a result of simulation, the speed of tidal currents are tended to decrease near the North and inner-port and increase at the main waterway. Furthermore, the tidal exchange had a tendency to be small both before and after redevelopment by about 77% in a quasi steady state, which is about 15 days after.

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A study on the power plant system combined with PEM fuel cell and the wasted hydrogen from the sea water electrolyzer of nuclear power plants (원자력 발전소의 해수전해설비 폐수소를 활용한 PEM 연료전지 발전 시스템에 관한 연구)

  • Choi, Jongwon;Lee, Juhyung;Cha, Sukwon;Kim, Minsoo
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.124.2-124.2
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    • 2010
  • Generally, a coolant of the nuclear power plant is manufactured by electrolyzing the sea water near the plant for making the sodium hypochlorite(NaOCl), which is used for sterilizing the bacteria and the shellfishes sticking to the drains or the pumps at the outlet of the cooling system due to $8-10^{\circ}C$ warmer temperature than the inlet sea water. During manufacturing the sodium hypochlorite, the hydrogen with the high purity is also produced at the anode side of the electrolyzer. This paper describes a novel power plant system combined with the polymer electrolyte membrane(PEM) fuel cell, the wasted hydrogen from the sea water electrolyzer and the wasted heat of the nuclear power plant. The present status over the exhausted hydrogen at twenty nuclear power plants in Korea was investigated in this study, from which an available power generation is estimated. Furthermore, the economic feasibility of the PEM fuel cell power plant is also evaluated by a current regulations over the power production and exchange using a renewable energy shown in Korea Power Exchange(KRX).

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Removal of Lead from Sea Water using Electrolysis and Coprecipitation Method (전기분해와 공침법을 이용한 해수중의 납 제거)

  • Jin, Hong-Sung;Lee, Jae-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.2
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    • pp.149-154
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    • 2010
  • The feasibility of lead removal by electrolytic coprecipitation was investigated. Electrolysis bath was divided into anode and cathode chamber with anion exchange resin filled membrane. Sea water was electrolyzed and pH of the electrolyte in cathode chamber was increased. Consequently it induced the formation of $Mg(OH)_2$ and $CaCO_3$. The colloidal type precipitates, hich have high surface area, adsorbed lead ions in sea water and coprecipitated. Sea water electrolyses were conducted at different current density. Concentrations of Mg, Ca and Pb in the solution were measured with titration and ASV method. Morphology and crystallography were analyzed with SEM, EDS and XRD. As pH and current density increased, most of lead ions in the sea water were successfully removed.

Efficiency Tests of Seawater Exchange System for Enhancement of Seawater Quality (해수교환시스템의 수질향상 효율평가)

  • Jang, Chang-Hwan;Kim, Sang-Taek;Kim, Hyo-Seob;Kim, Kyu-Han;Song, Man-Soon
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.13 no.3
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    • pp.206-215
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    • 2010
  • The multi-outlets were installed on the existing seawater exchange breakwater in order to improve seawater exchange rate at Jumunjin harbor. Physical and numerical model system were fulfilled for 4 cases to evaluate seawater exchange system which is able to discharge water remotely. The seawater circulation pattern and seawater exchange rate in the harbor were compared and analyzed. Consequently, total seawater exchange rate for CASE 1 was calculated 48% due to the dead zones which hinder seawater circulation in the harbor. Otherwise, the seawater exchange rates of CASE 2, CASE 3, and CASE 4 with the installation of the system were enhanced 19%, 15% and 17%, respectively compare to CASE 1.

Chemical and ecological studies of grasslands and soils of the Young-dong in Seoul, Korea (영동지구의 야초지와 토양에 대한 화학적, 생태학적 연구)

  • 박봉규;한진순
    • The Korean Journal of Ecology
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    • v.3 no.1_2
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    • pp.1-10
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    • 1980
  • This study was carried out to find out the correlation between plant groups and environomental gradient in the native grassfild near Kang Nam Express Terminal from August 26 to september 15, 1977. The correlations among plant species were calculated by using the method of x2 and the various relationships among soil environmental gradients were grouped by means of correlation coefficient. As a result, both the species and the soil environmental factors could be subdivided into four groups, and the four groups of the native grassfield were turned out to be correlated with the four groups of soil environmental factors. The first plant group (Panicum dichotomiflorum, Chenopodium album, Bidens forndosa, Humulus japonicus, Alopeculus amurensis, Potentilla fragarioides, Centipeda minima, Beckmannia erucaeformis) was formed in the releve 1∼10 reagions, organic matter by Turins's method, Total N, Exchange Ca and total of Exchange K, Na, Kg, Ca were abundent. The second plant group (Digitaria sanguinalis, Paltulaca oleracea, Echinochlea macrocrovi, Cyperus amuricus) was formed in the relve 11∼18 reagions, where Exchange Ca and total of Exchange K, Ng, Mg, Ca were little but Exchange A1 and sand were aburdent. In relve 19∼20 reagions, with much of Exchange Ca, total of Exchange K, Na, Mg, Ca, pH and a little Exchange Al, was found the third plant group (Pycreus sanguinoloentus, Cyperus amuricus, Ludwigia prostrata, Echinochloa echinata, Polygonum thunbergii, Salix glandulosa seedling) The fourth plant group (Cassia nomame, Polygnoum perfoliatum, Setaria viridis, Glocien ussuriensis, Lactuca indica, setaria glauca, Artemisia capill aris, Artmisia asiatica, Calamagrostis arundinacea, Kummerowia striata, Denothera odorata, Artemisia japonica, Carey laceolata) was formed in relve 21∼25 reagions, where organic matter by loss on ignition, Exchange Mg and Maximum water holding capacity were abundent but sand was a little. Thus it can be concluded that there is a close relationship between the vegetation group clasified by meaus of x2 and the environtal factors of soil devided by means of correlations coefficient.

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The Fabrication of Ion Exchange Membrane and Its Application to Energy Systems (고분자 이온교환막의 제조와 이온교환막을 이용한 에너지 공정)

  • Kim, Jae-Hun;Ryu, Seungbo;Moon, Seung-Hyeon
    • Membrane Journal
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    • v.30 no.2
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    • pp.79-96
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    • 2020
  • Secondary energy conversion systems have been briskly developed owing to environmental issue and problems of fossil fuel. They are basically operated based on electro-chemical systems. In addition, ion exchange membranes are one of the significant factors to determine performance in their systems. Therefore, the ion exchange membranes in suitable conditions must be developed to improve the performance for the electro-chemical systems. These ion exchange membranes can be classified into various types such as cation exchange membrane, anion exchange membrane and bipolar membrane. Their membranes have distinct characteristics according to the chemical, physical and morphological structure. In this review, the types of ion exchange membranes and their fabrication processes are described with main characteristics. Moreover, applications of ion exchange membranes in newly developed energy conversion systems such as reverse electrodialysis, redox flow battery and water electrolysis process are described including their roles and requirements.

Water and Salt Budgets for the Yellow Sea

  • Lee, Jae-Hak;An, Byoung-Woong;Bang, Inkweon;Hong, Gi-Hoon
    • Journal of the korean society of oceanography
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    • v.37 no.3
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    • pp.125-133
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    • 2002
  • Water and salt budgets in the Yellow Sea and Bohai are analyzed based on the historical data and CTD data collected recently using box models. The amounts of volume transport and of water exchange across the boundary between the Yellow and East China Seas are estimated to be 2,330-2,840 $\textrm{km}^3$/yr and 109-133 $\textrm{km}^3$/yr, respectively, from the one-layer box model. Corresponding water residence time is 5-6 years. In the Bohai, water residence time is twice as long as that in the Yellow Sea, suggesting that the Yellow Sea and Bohai cannot be considered as a single system in the view of water and salt budgets. The results indicate that water and salt budgets in the Yellow Sea depend almost only on the water exchange between the Yellow and East China Seas. The computation with the coupled two-layer model shows that water residence time is slightly decreased to 4-5 years for the Yellow Sea. In order to reduce uncertainties for the budgeting results the amount of the discharge from the Changjiang that enters into the Yellow Sea, the vertical advection and vertical mixing fluxes across the layer interface have to be quantified. The decreasing trend of the annual Yellow River outflow is likely to result that water residence time is much longer than the current state, especially for the Bohai. The completion of the Three Gorges dam on the Changjiang may be change the water and salt budgets in the Yellow Sea. It is expected that cutting back the discharge from the Changjiang by 10% through the dam would increase water residence time by about 10%.