• Journal of the Korean Chemical Society
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• v.16 no.3
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• pp.135-141
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• 1972

In the past years, a number of theories have been published to elucidate the structure of liquid water. common to most of these theories is that water mainly consist of several different kinds of clusters and also hydrogen bonds in water may be bent to some degree. Recentrly, in a series of paper, Jhon and Eyring successfully explained thermodynamic, dielectric, surface and transport properites of water, assuming that it contains small domains of about 46 molecules. According to the theory, the cluster size does not change with temperature, but the cluster concentration changes. In this paper, the potential function for the hydrogen bond, the dispersion energy and dipole-dipole interaction terms. The calculated results show that the domain of nearly 46 molecules is energetically most probable, and its size is independent of temperature. And also, we evaluated the effect of angel variation of the bent hydrogen bond. In addition, the relaxation energy different for ice and water is also explained by this method.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.33 no.1
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• pp.23-30
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• 2015

A shoreline mapping is essential for describing coastal areas, estimating coastal erosions and managing coastal properties. This study has planned to map the 3D shorelines with the airborne LiDAR(Light Detection and Ranging) data and the KOMPSAT-2 imagery, acquired in Uljin, Korea. Following to the study, the DSM(Digital Surface Model) is generated firstly with the given LiDAR data, while the NDWI(Normalized Difference Water Index) imagery is generated by the given KOMPSAT-2 imagery. The classification method is employed to generate water and land clusters from the NDWI imagery, as the 2D shorelines are selected from the boundaries between the two clusters. Lastly, the 3D shorelines are constructed by adding the elevation information obtained from the DSM into the generated 2D shorelines. As a result, the constructed 3D shorelines have had 0.90m horizontal accuracy and 0.10m vertical accuracy. This statistical results could be concluded in that the generated 3D shorelines shows the relatively high accuracy on classified water and land surfaces, but relatively low accuracies on unclassified water and land surfaces.

• Journal of Korea Water Resources Association
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• v.57 no.2
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• pp.87-97
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• 2024

This study analyzed the water shortage hotspot areas in South Korea using spatial clustering analysis for water shortage estimates in 2030 of the Master Plans for National Water Management. To identify the water shortage cluster areas, we used water shortage data from the past maximum drought (about 50-year return period) and performed spatial clustering analysis using Local Moran's I and Getis-Ord Gi*. The areas subject to spatial clusters of water shortage were selected using the cluster map, and the spatial characteristics of water shortage areas were verified based on the p-value and the Moran scatter plot. The results indicated that one cluster (lower Imjin River (#1023) and neighbor) in the Han River basin and two clusters (Daejeongcheon (#2403) and neighbor, Gahwacheon (#2501) and neighbor) in the Nakdong River basin were found to be the hotspot for water shortage, whereas one cluster (lower Namhan River (#1007) and neighbor) in the Han River Basin and one cluster (Byeongseongcheon (#2006) and neighbor) in the Nakdong River basin were found to be the HL area, which means the specific area have high water shortage and neighbor have low water shortage. When analyzing spatial clustering by standard watershed unit, the entire spatial clustering area satisfied 100% of the statistical criteria leading to statistically significant results. The overall results indicated that spatial clustering analysis performed using standard watersheds can resolve the variable spatial unit problem to some extent, which results in the relatively increased accuracy of spatial analysis.

• Korean Membrane Journal
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• v.1 no.1
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• pp.73-80
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• 1999

The removal of trace chlorinated and aromatic hydrocarbons from water by a pervaporation technique has been carried out through poly (dimethylsiloxane) membrane which had been fabricated by the addition crosslinking reaction. This study dealt with the swelling and permeation behaviors of the PDMS membranes with dichloroethane trichloroethane and toluene aqueous solutions. The swelling ratio in the toluene aqueous solution was much higher than those in the chloroethane solutions at all of the operating temperatures and concentrations. The solubility parameter theory was introduced to interpret the affinity between permeates and a membrane material and in all cases this approach seemed to be proper. It was suggested that the existence of water clusters in the membrane due to the hydrophobic characteristics of the membrane made the size of the permeating water larger resulting in suppressing water permeation and increasing enrichment of the organic components. The permeation behaviors at different membrane thicknesses were indirectly interpreted in terms of the effect of concentration polarization.

• Journal of Marine Bioscience and Biotechnology
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• v.16 no.1
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• pp.63-86
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• 2024

This study analyzed the distribution, diversity, and density variation of algal clusters in a freshwater reservoir from an oceanic island and a traditional inland water system to gain insights on future marine freshwater resource management. In the Paldang water system (Han River), despite the upstream Paldang Dam and the downstream Jamsil underwater reservoir being in the same meteorological zone, their algae density patterns varied inversely. The distinct algal cluster structure (diversity/dominance) of Paldang was altered in the downstream reservoir, suggesting that physical devices aid algae management in traditional water systems. In contrast, 24 out of 35 genera (63.2%) identified in the Jeolgol Reservoir (Baeknyeong Island) were unique, lacking regulatory mechanisms, and existing in a complex ecotone. The desmid Chlorophyceae Cosmarium, adapted to higher photosynthetic stress and low temperatures, dominated in January (38.04%) and August (86.45%) during the periods of extreme photosynthetic stress. Jeolgol's annual algal cluster structure (H' 2.097; D 0.259; S' 35) demonstrated higher stability than Paldang (H' 1.125; D 0.448; S' 13) and the Jamsil underwater reservoir (H' 1.078; D 0.469; S' 12), maintaining an H' above 1.5 even during midwinters. No evidence of TN/TP inflow from surrounding soils was observed, even during torrential rainfalls, with phosphorus being the limiting factor for algal growth. TOC, BOD, chlorophyll-a, and turbidity peaked during Cosmarium bloom. Future climate change is expected to cause fluctuations in algal clusters and related water quality factors. The complex transitional nature of the Jeolgol Reservoir, its algal diversity, and the interspecies interactions contribute to the high stability of its algal community.

• Journal of Environmental Impact Assessment
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• v.18 no.6
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• pp.401-409
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• 2009

Multivariate statistical approaches to classify sampling sites with measuring their similarity by water quality data and understand the characteristics of classified clusters have been discussed for the optimal water quality monitering network. For empirical study, data of two years (2005, 2006) at the 9 sampling sites with the combination of 2 depth levels and 7 important variables related to water quality is collected in Yongdam reservoir. The similarity among sampling sites is measured with Euclidean distances of water quality related variables and they are classified by hierarchical clustering method. The clustered sites are discussed with principal component variables in the view of the geographical characteristics of them and reducing the number of measuring sites. Nine sampling sites are clustered as follows; One cluster of 5, 6, and 7 sampling sites shows the characteristic of low water depth and main stream of water. The sites of 2 and 4 are clustered into the same group by characteristics of hydraulics which come from that of main stream. But their changing pattern of water quality looks like different since the site of 2 is near to dam. The sampling sites of 3, 8, and 9 are individually positioned due to the different tributary.

• Journal of Korean Society of Rural Planning
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• v.26 no.4
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• pp.53-65
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• 2020

This study aimed to provide a basic information for managing the water quality of national and regional 1st rivers in Gyeongnam by analyzing the emerging hot spot patterns in BOD, T-P, and TOC, and by grouping the changing trends into clusters. The emerging hot spot analysis for each water quality item was implemented in ArcGIS Desktop with monthly water quality data from 96 water environmental monitoring stations in Gyeongnam, and then four patterns of water quality change were classified by the K-mean cluster analysis. As for BOD, persistent cold spot pattern covered about 42.9% of target rivers, and T-P concentration tended to be low or be getting lower at over 70% of target rivers. While, for TOC, about 70% of target rivers resulted in oscillating hot spots. In addition, the cluster analysis showed that the downstream of Nakdong river had the top priority in terms of water quality management because of the increasing concentration for all the three water quality.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.9 no.7
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• pp.1588-1593
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• 2005

In coagulant control of water treatment plants, rule extraction, one of datamining categories, was performed for coagulant control of a water treatment plant. Clustering methods were applied to extract control rules from data. These control rules can be used for fully automation of water treatment plants instead of operator's knowledge for plant control. To perform fuzzy clustering, there are some coefficients to be determined and these kinds of studies have been performed over decades such as clustering indices. In this study, statistical indices were taken to calculate the number of clusters. Simultaneously, seed points were found out based on hierarchical clustering. These statistical approaches give information about features of clusters, so it can reduce computing cost and increase accuracy of clustering. The proposed algorithm can play an important role in datamining and knowledge discovery.

• Journal of the Korean Society of Marine Environment & Safety
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• v.16 no.4
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• pp.321-337
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• 2010

Long-term trends and distribution patterns of water quality were investigated in the Mokpo coastal areas of the Yellow Sea, Korea from 1979 to 2009. Water samples were collected at 5 stations and physicochemical parameters were analyzed including water temperature, salinity, suspended solids (SS), chemical oxygen demand (COD), dissolved oxygen (DO) and nutrients. Spatial distribution patterns of temperature, pH and DO were not clear among stations but the seasonal variations were distinct except ammonium. The trend analysis by principal component analysis (PCA) during 30 years revealed the significant variations in water quality in the study area. Spatial water qualities were discriminated into 3 clusters by PCA; station cluster 1, 2~4, and 5. Annual water qualities were clearly discriminated into 4 surface water clusters and 2 bottom water clusters by PCA. By this multi-variate analysis, the annual trends were summarized as the followings; water temperature, pH and COD tended to increase from late 1980's, salinity to decrease, phosphate to increase from 1994 and dissolved inorganic nitrogen to increase, due to the input of fresh water same as shown in Kyoungin coastal area, Asan coastal area, Choensoo bay and Gunsan coastal area.

• Journal of Environmental Science International
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• v.16 no.12
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• pp.1411-1424
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• 2007

Long-term trends and distribution patterns of water quality were investigated in the Asan coastal areas of Yellow Sea, Korea from 1975 to 2005. Water samples were collected at 3 stations and physicochemical parameters were analyzed including water temperature, salinity, suspended solids(SS), chemical oxygen demand(COD), dissolved oxygen(DO) and nutrients. Spatial distribution patterns were not clear among stations but the seasonal variations were distinct except COD, SS and nitrate. The trend analysis by principal component analysis(PCA) during twenty years revealed the significant variations in water quality in the study area, Annual water qualities were clearly discriminated into 4 clusters by PCA; year cluster 1988-1991, 1994-1997, and 1992-1993/1998-2005. By this multi-variate analysis we can summarize the annual trends as the followings; salinity, suspended solids and dissolved oxygen tended to increase from late 1980's, increased pH and COD from 1992, and decreased salinity and increased nitrogen and COD from 1990 due to the runoff frow agricultural lands causing eutrophication.