• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2002.05a
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• pp.34-45
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• 2002

The new measuring method of micro-stickies considering both the effects of charge neutralization and evaporation of process water was developed by KRICT PPRC. By the new KRICT method, the contamination of metal dryer surface and other machine clothes could be estimated quickly and simultaneously. According to this study, it could be confirmed that the novel method is a useful one for the evaluation of several treatments regarding the reduction of stickies troubles.

• Journal of Electrochemical Science and Technology
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• v.7 no.1
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• pp.1-12
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• 2016

The production of oxygen and hydrogen from solar water splitting has been considered to be an ultimate solution for energy and environmental issues, and over the past few years, nano-sized semiconducting metal oxides alone and with graphene have been shown to have great promise for use in photocatalytic water splitting. It is challenging to find ideal materials for photoelectrochemical water splitting, and these have limited commercial applicability due to critical factors, including their physico-chemical properties, the rate of charge-carrier recombination and limited light absorption. This review article discusses these main features, and recent research progress and major factors affect the performance of the water splitting reaction. The mechanism behind these interactions in transition metal oxides and graphene based nano-structured semiconductors upon illumination has been discussed in detail, and such characteristics are relevant to the design of materials with a superior photocatalytic response towards UV and visible light.

• Journal of Digital Convergence
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• v.7 no.3
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• pp.103-111
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• 2009

In this paper, we introduce automatic meter reading system for tap water. The system is composed of automatic meter, router using RF and CDMA network, and data server. This system will easily extend to fire detect, gas, and electric charge meter system. In addition, this system will be used to monitoring a water leak and human which live in solitude. Proposed system is installed at Gimhae-City and Gijang-gun. As a result of the automatic meter reading system for tap water, The leak of water and complain of user is decreased. But The building cost is still an obstacle to expand into entire city.

• Bulletin of the Korean Chemical Society
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• v.20 no.8
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• pp.893-896
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• 1999

Novel citric acid based Ti, Nb and Ta precursors that are highly stable in the presence of water were developed. No alkoxides of Ti, Nb and Ta were utilized in the preparation, instead much less moisture-sensitive metallic Ti, NbCl5 and TaCl5 were chosen as starting chemicals for Ti, Nb and Ta, respectively. The feasibility of these chemicals as precursors is demonstrated in the powder synthesis of BaTi4O9, Y3NbO7 and LiTaO3. The water-resistant Ti precursor was employed as a new source of water-soluble Ti in the amorphous citrate method, and phase pure BaTi4O9 in powdered form was successfully synthesized at 800 ？. The Pechini-type polymerizable complex method using the water-resistant Nb and Ta precursors was applied to the synthesis of Y3NbO7 and LiTaO3, and both the powder materials in their pure form were successfully synthesized at reduced tempera-tures, viz. 500-700 ？. The remarkable retardation of hydrolysis of these water-resistant precursors is explained in terms of the partial charge model theory.

• Journal of Mechanical Science and Technology
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• v.16 no.7
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• pp.966-974
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• 2002

An analytic approach has been employed to study condensate film thickness distribution inside cave-shaped cavity of a flat plate heat pipe. The results indicate that the condensate film thickness largely depends on mass flow rate and local velocity of condensate. The increasing rate of condensate film for circular region reveals about 50% higher value than that of vertical region. The physical properties of working fluid affect significantly the condensate film thickness, such as the condensate film thickness for the case of FC-40 are 5 times larger than that of water. In comparison with condensation on a vertical wall, the average heat transfer coefficient in the cave-shaped cavity presented 10∼15% lower values due to the fact that the average film thickness formed inside the cave-shaped cavity was larger than that of the vertical wall with an equivalent flow length. A correlation formula which is based on the condensate film analysis for the cave-shaped cavity to predict average heat transfer coefficient is presented. Also, the critical minimum fill charge ratio of working fluid based on condensate film analysis has been predicted, and the minimum fill charge ratios for FC-40 and water are about Ψ$\_$crit/=3∼7%, Ψ$\_$crit/=0.5∼1.3% respectively, in the range of heat flux q"=5∼90kW/㎡.

• Bulletin of the Korean Chemical Society
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• v.26 no.12
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• pp.2007-2016
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• 2005

An artificial neural network (ANN) is successfully presented for prediction acidity constant (pKa) of various benzoic acids and phenols with diverse chemical structures using a nonlinear quantitative structure-property relationship. A three-layered feed forward ANN with back-propagation of error was generated using six molecular descriptors appearing in the multi-parameter linear regression (MLR) model. The polarizability term $(\pi_1)$, most positive charge of acidic hydrogen atom $(q^+)$, molecular weight (MW), most negative charge of the acidic oxygen atom $(q^-)$, the hydrogen-bond accepting ability $(\epsilon_B)$ and partial charge weighted topological electronic (PCWTE) descriptors are inputs and its output is pKa. It was found that properly selected and trained neural network with 205 compounds could fairly represent dependence of the acidity constant on molecular descriptors. For evaluation of the predictive power of the generated ANN, an optimized network was applied for prediction pKa values of 37 compounds in the prediction set, which were not used in the optimization procedure. Squared correlation coefficient $(R^2)$ and root mean square error (RMSE) of 0.9147 and 0.9388 for prediction set by the MLR model should be compared with the values of 0.9939 and 0.2575 by the ANN model. These improvements are due to the fact that acidity constant of benzoic acids and phenols in water shows nonlinear correlations with the molecular descriptors.

• Bulletin of the Korean Chemical Society
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• v.22 no.2
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• pp.219-227
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• 2001

The silver colloidal effects on the excited-state structure and intramolecular charge transfer (ICT) of p-N,N-dimethylaminobenzoic acid (DMABA) in aqueous cyclodextrin (CD) solutions have been investigated by UV-VIS absorption, steady-state and time-resolved fluorescence, and transient Raman spectroscopy. As the concentration of silver colloids increases, the ratio of the ICT emission to the normal emission (Ia /Ib) of DMABA in the aqueous $\alpha-CD$ solutions are greatly decreased while the Ia /Ib values in the aqueous B-CD solutions are significantly enhanced. It is also noteworthy that the ICT emission maxima are red-shifted by 15-40 nm upon addition of silver colloids, implying that DMABA encapsulated in $\alpha-CD$ or B-CD cavity is exposed to more polar environment. The transient resonance Raman spectra of DMABA in silver colloidal solutions demonstrate that DMABA in the excited-state is desorbed from silver colloidal surfaces as demonstrated by the disappearance of νs (CO2-)(1380 cm-1 ) with appearance of ν(C-OH)(1280 cm -1) band, respectively. Thus, in the aqueous B-CD solutions the carboxylic acid group of DMABA in the excited-state can be readily hydrogen-bonded with the secondary hydroxyl group of B-CD while in aqueous and $\alpha-CD$ solutions the carboxylic acid group of DMABA has the hydrogen-bonding interaction with water. Consequently, in the aqueous B-CD solutions the enhancement of the Ia /Ia value arises from the intermolecular hydrogen-bonding interaction between DMABA and the secondary hydroxyl group of B-CD as well as the lower polarity of the rim of the B-CD cavity compared to bulk water. This is also supported by the increase of the association constant for DMABA/ B-CD complex in the presence of silver colloids.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.317-317
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• 2011

Water dissociation on oxide surface has been researched in many fields because of its importance as fundamental phenomenas. MgO(001) is a good model system to understand heterogeneous catalysis, gas sensors, ground-water contaminants, and atmosphere chemistry. Over decades, ultrathin film of MgO on Ag(100) have attracted research activities thanks to its enhanced catalytic property. Correlation of the oxide and the metal, potential screening, charge fluctuation from interface reconstruction makes different energetics of hydroxylation of waters on film. We calculate the water-spliting energetics under the vacuum system.

• Applied Science and Convergence Technology
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• v.27 no.4
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• pp.61-64
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• 2018

The basic principle and concept for hydrogen production via water-splitting process are introduced. In particular, recent research activities and their progress in the photoelectrochemical water-splitting process are investigated. The material perspectives of semiconducting photocatalysts are considered from metal oxides, including titanium oxides, to carbon compounds and perovskites. Various structural configurations, from conventional photoanodes with metal cathodes to tandem and nanostructures, are also studied. The pros and cons of each are described in terms of light absorption, charge separation/photoexcited electron-hole pair recombinations and further solar-to-hydrogen efficiency. In this research, we attempt to provide a broad view of up-to-date research and development as well as, possibly, future directions in the photoelectrochemical water-splitting field.

• Journal of Korean Society on Water Environment
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• v.16 no.4
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• pp.459-468
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• 2000

This study is to investigate the floc structure and removal of turbidity and organic matter by PACI coagulation. The turbidity removal by PACI coagulation was obtained at larger pH range than alum coagulation. And the removal of organic matter was obtained at smaller pH range than that of turbidity. The organic matter was removed by the adsorption of $Al(OH)_3$ precipitates. Floc structure was characterized by measuring fractal dimension and volume diameter using AIA and SALLS. Fractal dimension measured by AIA did not show the different characteristics of floc produced in sweep floe and charge neutralization region. Using SALLS, floes in sweep floc region were found to be larger size and fractal dimension than flocs in charge neutralization region. As pollutant removal increased. larger fractal dimension and size of floc were measured. SALLS method was found to be more useful method to characterize flocs in coagulation than AIA method.