• International Journal of Air-Conditioning and Refrigeration
• /
• 제14권2호
• /
• pp.49-56
• /
• 2006

Heat transfer performances of individual row of two-row fin and tube heat exchangers are experimentally investigated. Tested are four heat exchangers which are geometrically identical with the exception of fin shape, slit or louver, and that the fins between the first row and the second row are connected or separated. The tube diameter and fin spacing of the heat exchangers examined are 7mm and 1.4mm, respectively. All thermal fluid measurements are made using a psychrometric calorimeter. In order to evaluate air-side heat transfer coefficients of individual rows, tube-side water flow rates of individual rows are independently controlled such that the water-side temperature drops in each row remain at $5^{\circ}C$. Frontal air velocity varies in the range from 0.7m/s to 2.5m/s. Heat transfer coefficients are presented in terms of Colburn ${\jmath}-factor$. The results show that the heat transfer coefficient of the upstream row is larger than that for the downstream row at low Reynolds numbers.

• 접착 및 계면
• /
• 제12권1호
• /
• pp.1-10
• /
• 2011

자동화된 반응 열량계를 이용하여 중합비율을 관찰하면서 blockiness가 다른 PVOH를 이용하여 VAE 에멀젼을 합성하였다. 입자 분포도를 관찰 결과 단량체와 물과 비율에 따른 일정한 그라프트율은 없었다. 초기 단량체-물의 비율이 낮은 곳에서 겔 효과가 관찰되었다. 또한 입자 분포는 넓고 이중 피크가 관찰되었다. 지속적으로 제한적으로 응징집되면서 입자성장이 이루어지는 것이 관찰되었다. 이것은 제한적인 응집현상과 사슬이 PVOH로 그라프팅되어 발생한 결과로 판단된다.

• 한국기계기술학회지
• /
• 제13권2호
• /
• pp.63-70
• /
• 2011

In the present study, we developed optimal heat supply algorithm which minimizes the heat loss through the distribution pipe line in group energy apartment. Heating load variation of group energy apartment building in accordance with outdoor air temperature was predicted by the correlation obtained from calorimeter measurements of whole households of apartment building. Supply water temperature and mass flow rate were conjugately controlled to minimize the heat loss rate through distribution pipe line. Group heating apartment located in Hwaseong city, Korea, which has 1,473 households divided in 4 regions, was selected as the object apartment for verifying the present heat supply control algorithm. Compared to the original heat supply system, 10.4% heat loss rate reduction can be accomplished by employing the present control algorithm.

• 한국식생활문화학회지
• /
• 제37권4호
• /
• pp.345-353
• /
• 2022

This study compared the physicochemical and gelatinization properties of naked barley, tetrastichum barley, and waxy barley. Compared to tetrastichum barley and waxy barley, naked barley had shorter and rounder grains with a 1.43 length/width ratio. Tetrastichum barley had lower crude protein, crude lipid, and crude ash content and higher amylose content compared to naked barley and waxy barley. The L, a, b color values of waxy barley were significantly higher than those of naked barley and tetrastichum barley. The water absorption index (WAI) and the water soluble index (WSI) were highest in waxy barley. The X-ray diffraction pattern was type A in all samples, and the peak intensity was highest in waxy barley. The maximum viscosity, cooling viscosity, breakdown, and setback of amylogram properties were the highest in tetrastichum barley. The thermal properties through the differential scanning calorimeter showed that the waxy barley had higher values of the onset, peak, conclusion temperature and enthalpy (?H). In conclusion, the variety of barley influenced the physicochemical and gelatinization properties, which could be important factors in the manufacture of processed foods. These results would thus useful inputs for the manufacturing of these foods using barley.

• Journal of Pharmaceutical Investigation
• /
• 제34권4호
• /
• pp.289-297
• /
• 2004

Acyclovir (ACV) is one of the most effective and selective agents against viruses of the herpes group. Because of low solubility, bioavailability of ACV has shown below 30% with oral dosage form. In our previous study, we reported that the fabrication of solid dispersion of ACV was possible and the solid dispersion of ACV and PVP was the most useful in all samples. In this study, we examined the effect of mixture ratio of polymers (PEG and PVP) to ACV. Solubility of ACV was dramatically increased up to 25 mg/ml in $80^{\circ}C$ distilled water. So water was used as a solvent to eliminate problem of residual solvent. Spray drying method was used for the solid dispersion of ACV as solvent extraction. Different scanning calorimeter was used to check degradation of drug. Polymer carriers were PEG 6,000 and PVP. In summary, ACV-PVP (1:3) showed the best solubility in distilled water.

• 공업화학
• /
• 제20권6호
• /
• pp.632-637
• /
• 2009

Pluronic F127을 함유한 poly(${\varepsilon}-caprolacton$) / ethyl cellulose (PCL/EC) 마이크로 캡슐을 분무건조법으로 제조하였다. 20% (w/v)의 pluronic F127 수용액을 수상으로, 5% (w/w)의 PCL/EC이 녹아있는 디클로로메탄(dichloromethane)을 유기상으로 이용하여 water-in-oil (W/O) 에멀젼을 제조하였고, 이를 분무건조하여 마이크로 캡슐을 얻어낼 수 있었다. 주사전자현미경과 입도분석기로 분석한 결과, 수 마이크로부터 수십 마이크로 크기의 마이크로 캡슐이 형성을 확인되었다. 시차주사열량측정기로 마이크로 캡슐의 상전이 온도를 조사한 결과, 마이크로 캡슐 제조 시 사용된 고분자들의 상전이 온도가 관찰되었다. 마이크로 캡슐의 온도 의존적 방출 특성은 $30{\sim}45^{\circ}C$에서 관찰하였으며, 수용성 염료인 fluorescein isothiocyanate-dextran (FITC-dextran)과 blue dextran을 방출모델시약으로 하였다. 온도가 증가할수록 마이크로 캡슐로부터 방출되는 양이 증가하였으며, 방출모델시약의 분자량이 작을수록 더 많이 방출되었다.

• 동아시아식생활학회지
• /
• 제7권4호
• /
• pp.519-526
• /
• 1997

Propylene oxide와 반응시켜 치환도가 0-0.2645되는 하이드록시프로필화 감자 전분을 제조하여 이화학적 성질들을 측정하였다. 전분의 하이드록시프로필기 함량은 propylene oxide의 농도에 비례하였다. 하이드록시프로필화 감자 전분의 물결합력은 치환도가 증가할수록 증가하였고 pH는 치환도가 증가할수록 감소하였다. 청가와 요오드 흡착 강도는 치환도가 증가할수록 감소하였다. 시차주사열량계에 의한 호화양상에서는 하이드록시프로필화에 의해 전분의 호화온도가 낮아지는 것으로 나타났다. 하이드록시프로필화에 의해 전분의 상대 결정 화도는 낮아졌고, 전분 입자가 파괴되었음이 X-선 회절도와 주사전자현미경으로 각각 관찰되었다. 이것은 고농도의 하이드록시프로필화가 전분의 무정형 부분뿐만 아니라 결정성 영역에까지 영향을 주었음을 의미하였다.

• 한국수소및신에너지학회논문집
• /
• 제21권4호
• /
• pp.307-312
• /
• 2010

Poly (ether sulfone)s with Bisphenol-TP and Bisphenol-AF were prepared with Bisphenol-TP <4,4-dihydroxy tetraphenyl methane>, 4-Fluorophenyl sulfone, and Bisphenol-AF <4,4-(hexafluoroisopropylidene) diphenol> using Potassium carbonate in Sulfolane at $210^{\circ}C$. Sulfonated PBTP-AF were obtained by reaction of Chlorosulfuric acid with copolymers. A series of copolymers were studied by $^1H$-NMR spectroscopy, Differential Scanning Calorimeter (DSC), and Thermo Gravimetric Analysis (TGA). Sorption experiments were conducted to observe the interaction of polymers with water and methanol.

• 한국건축시공학회지
• /
• 제2권2호
• /
• pp.145-150
• /
• 2002

The hydration of cement paste occurs when the cement is miked with water. During the hydration, hydration heat causes the thermal stress depending on the site of concrete and the cement content. Especially in the high-strength concrete, we must give care to the concrete due to its large cement content. In this study conduction calorimeter and concrete insulation hydration heat meter were used to investigation the hydration heat characteristics of cement and concrete. To reduce hydration heat of high-strength concrete, several types of replacement of fly-ash and blast-furnace slag powder were used in this experiment. As a result of this study, it was found that hydration heat of high-strength concrete was reduced by replacement of fly-ash and blast-furnace slag powder. In case of high-strength concrete using blast-furnace slag powder, the max-heat arrival time was delayed but an effect of heat reduction was lower than a case of high-strength concrete using fly-ash, because it was considered that the heat-dependence property of blast-furnace slag powder was higher than that of fly-ash.

• 폴리머
• /
• 제38권4호
• /
• pp.484-490
• /
• 2014

Reduced graphene oxide (RGO) was fabricated using gelatin as a reductant, and it could be stably dispersed in gelatin solution without aggregation. A series of RGO/gelatin composite films with various RGO contents were prepared by a solution-casting method. The structure and thermal properties of the RGO/gelatin composite films were characterized by UV-vis spectroscopy, Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), atomic force microscopy (AFM), scanning electron microscopy (SEM), differential scanning calorimeter (DSC) and thermal gravimetric analysis (TGA). The addition of RGO enhances the degree of crosslinking of gelatin films and decreases the swelling ability of the gelatin films in water, indicating that RGO/gelatin composite films have a better wet stability than gelatin films. The glass transition temperature ($T_g$) of gelatin films is also increased with the incorporation of RGO. The presence of RGO slightly increases the degradation temperature of gelatin films due to the very low content of RGO in the composite films. Since gelatin is a natural and nontoxic biomacromolecule, the RGO/gelatin composite films are expected to have potential applications in the biomedical field.