• Proceedings of the Korean Vacuum Society Conference
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.338-338
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• 2011

The behavior of hydroxide ions on water-ice films was studied by using $Cs^+$ reactive ion scattering (RIS), low energy sputtering (LES) and temperature-programmed desorption (TPD). A $Cs^+$ beam of a low kinetic energy (<100 eV) from $Cs^+$ ion gun was scattered at the film surface, and then $Cs^+$ projectiles pick up the neutral molecules on the surface as $Cs^+$-molecule clusters form (RIS process). In LES process, the preexisting ions on the surface are desorbed by the $Cs^+$ beam impact. The water-ice films made of a thick (>50 BL) $H_2$O layer and a thin $D_2O$ overlayer were controlled in temperatures 90~140K. We prepared hydroxide ions by using Na atoms which proceeded hydrolysis reaction either on the ice film surface or at the interface of the $H_2O$ and $D_2O$ layers.[1] The migration of hydroxide ions from the $H_2O/D_2O$ interface to the top of the film was examined as afunction of time. From this experiment, we show that hydroxide ions tend to reside at the water-ice surface. We also investigated the H/D exchange reactions of $H_2O$ and $D_2O$ molecules mediated by hydroxide ions to reveal the mechanism of migration of hydroxide to the ice surface.

• Proceedings of the Korean Vacuum Society Conference
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.363-363
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• 2010

The high capillarity of a plastic fiber network having superhydrophilic Si-DLC coating is studied. Although the superhydrophilic surface maximize wetting ability on the flat surface, there remains a requirement for the more wettable surface for various applications such as air-filters or liquid-filters. In this research, the PET non-woven fabric surface was realized by superhydrophilic coating. PTE non-woven fabric network was chosen due to its micro-pore structure, cheap price, and productivity. Superhydrophobic fiber network was prepared with a coating of oxgyen plasma treated Si-DLC films using plasma-enhanced chemical vapor deposition (PECVD). We first fabricated superhydrophilic fabric structure by using a polyethylene terephthalate (PET) non-woven fabric (NWF) coated with a nanostructured films of the Si-incorporated diamond-like carbon (Si-DLC) followed by the plasma dry etching with oxygen. The Si-DLC with oxygen plasma etching becomes a superhydrophilic and the Si-DLC coating have several advantages of easy coating procedure at room temperature, strong mechanical performance, and long-lasting property in superhydrophilicity. It was found that the superhydrophobic fiber network shows better wicking ability through micro-pores and enables water to have much faster spreading speed than merely superhydrophilic surface. Here, capillarity on superhydrophilic fabric structure is investigated from the spreading pattern of water flowing on the vertical surface in a gravitational field. As water flows on vertical flat solid surface always fall down in gravitational direction (i.e. gravity dominant flow), while water flows on vertical superhydrophilic fabric surface showed the capillary dominant spreading.

• Journal of the Korean institute of surface engineering
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• 제54권5호
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• pp.222-229
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• 2021

Icing causes various serious problems, where water vapor or water droplets adhere at cold conditions. Therefore, understanding of ice adhesion on solid surface and technology to reduce de-icing force are essential for surface finishing of metallic materials used in extreme environments and aircrafts. In this study, we controlled wettability of aluminum alloy using anodic oxidation, hydrophobic coating and lubricant-impregnation. In addition, surface porosity of anodized oxide layer was controlled to realize superhydrophilicity and superhydrophobicity. Then, de-icing force on these surfaces with a wide range of wettability and mobility of water was measured. The results show that the enhanced wettability of hydrophilic surface causes strong adhesion of ice. The hydrophobic coating on the nanoporous anodic oxide layer reduces the adhesion of ice, but the volume expansion of water during the freezing diminishes the effect. The lubricant-impregnated surface shows an extremely low adhesion of ice, since the lubricant inhibits the direct contact between ice and solid surface.

• Journal of the Korean institute of surface engineering
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• 제54권2호
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• pp.90-95
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• 2021

Surface modification technique enabling the control of condensation provides various benefit in various engineering systems, such as heat transfer, desalination, power plants, and so on. In this study, lubricant oil-impregnation into Teflon-coated nanoporous anodic oxide layer of aluminum to enhance a de-wetting and mobility of water droplet on surface. Due to the surface treatment improving water-repellency, the condensation mode is changed to dropwise, thus the frequency of sliding condensed water droplet on surface is increased. For these reasons, the surface of oil-impregnated Teflon-coated nanoporous anodic aluminum oxide shows significantly enhanced condensation heat transfer compared to bare aluminum surface. In addition, the porosity of anodic aluminum oxide affected the mobility of water droplet even with oil-impregnation and Teflon-coating, indicating that the optimization of porous structure of anodic oxide is required for maximizing the condensation heat transfer.

• Proceedings of the Korea Water Resources Association Conference
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• 한국수자원학회 2005년도 학술발표회(2)
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• pp.1434-1436
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• 2005

• Fashion & Textile Research Journal
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• 제22권1호
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• pp.112-118
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• 2020

This paper examined the water repellency, water proofing and water vapor permeability of twelve types of woven fabrics for sports wear clothing. Their physical properties were compared and discussed with the fabric structural parameters and surface finishing effect. A water repellent property of 100% was obtained in the coated or laminated water repellent finished fabrics; in addition, cotton/nylon breathable composite fabrics treated with a laminated finishing and with low fabric density showed a 90% water repellency. Water proofing fabric above 6,000 mm H₂O hydraulic pressure was achieved by coated or laminated finishing; however, high density fabric or medium-level coated fabrics exhibited 100% water repellent and low water proofing characteristics. Superior water vapor permeability characteristics with good water repellency and proofing properties were achieved at the 2.5 layered low density and with 0.7 - 0.9 cover factor nylon fabrics treated with hydrophilic laminated finishing. The regression analysis for examining the effects of fabric structural parameters and surface finishing such as coating and laminating to the water vapor permeability exhibited a high determination coefficient of fabric structural parameters of 63.5%; in addition,, main factors among fabric structural parameters appeared to be cover factor and fabric thickness per weight. Coating and Laminating factors exhibited determination coefficient of water vapor permeability parameters of 36.5%.

• The Journal of Engineering Geology
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• 제27권3호
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• pp.313-322
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• 2017

The purpose of this study is to estimate the surface and subsurface flows through the modelling of the model area and facility agricultural complex, and to calculate the groundwater recharge rate through water budget analysis. From results of surface flow modeling, the surface water is flowed to a depth of about 1 to 5 meters from the upper region (northeast) to the lower region (southeast) of the Miryang River. At the M01 point (upper), the observed surface water flux and the model surface water flux are consistent. At the M02 points (lower), the observed surface water flux and the model surface water flux are a difference of 1%. From results of subsurface flow modeling, the depth of groundwater is similar to elevation in the river and higher to the forest area. Ground water depth considering groundwater pumping is that the model values appears higher than the observed values to be within 1.5 m. From results of surface-subsurface integrated modeling, the groundwater recharge area is estimated about 90% of the model area, and the groundwater recharge rate is estimated $1.92{\times}10^5m^3/day$. From results of annual water budget analysis, the groundwater recharge rate per unit area is estimated to be 503.9 mm/year, and average annual rainfall is estimated at around 39%.

• Journal of the Korean Society of Visualization
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• 제9권4호
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• pp.74-79
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• 2011

In this study the change of free surface vortex is represented at different times according to height of water and with or without curtain wall installation. The air volume fraction is investigated at each condition of water level and the influence about creation of vortex is analyzed. The height of sump intake is taken as 100mm and the water level is divided into 5 steps. The sump model is the TSJ model and the curtain wall is applied by HI standard of America. The results shows that the free surface vortex can be identified on the isotropic surface at air volume fraction 1%~5% and the vortices make an air column from the free surface to the sump intake and are created and destroyed repeatedly. In the higher water level, less air is absorbed into the intake pipe. After curtain wall installation, the suction rate of the air volume fraction is decreased by 6.7%. The result of the vortex motion according to time, works on a cycle.

• Journal of Korean Society of Water and Wastewater
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• 제22권3호
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• pp.323-328
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• 2008

During the full-scale water treatment operation at "G" Water Treatment Plant in Seoul, we investigated changes in pore volume distribution and specific surface area of GAC with time. The pore volume of the used GAC decreased to the level below 0.6 cc/g while that of the brand new GAC was ranged 0.7~0.9 cc/g. The specific surface area of GAC pores changed within the range between $1100{\sim}1200m^2/g$ and $700{\sim}800m^2/g$. Bacteria attached to the surface of GAC shows a gradual increase ($0.4{\time}10^6{\sim}8.5{\time}10^6CFU/g$) under scanninig electron microscope (SEM). TOC removal was enhanced due to growth of the attached bacteria on GAC. It was found that TOC removal was closely related with physical parameters (pore volume, specific surface area) linearly under the investigated conditions. The used GAC need to be exchanged into new one or re-generated to remove organic matters (TOC) effectively from the finished drinking water.

• Journal of Environmental Science International
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• 제4권5호
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• pp.427-435
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• 1995

In order to discuss the differences among the SMP(Surface Moisture Availability Parameter), by previous researchers on the basis of their own theoretical and empirical background, we assessed the SMP according to the soil types and volumetric soil water contents. The results are as follows. There are differences among all the five SMAPs. There's a tendency that the larger grain size, the higher value of parameters. And they divided into two groups for their value: one group has parameters with exponential function and the other with cosine and linear function. The maximum difference between the two groups appears when the volumetric soil water contents are 0.07m3m-3 for sand, 0.l1m3m-3 for loam, 0.12 for clay, and 0.13m3m-3 for silt loam. So, these differences must be considered when we estimate the surface evaporation rate. From field data, the paddy field soil around Junam reservoir is classified as a silt has high wetness, 0.56. So, the parameter obtained from the field measurement is much higher than that of Clapp and Hornberger(1978)'s Table. This study treated the SMP for a certain point of time in winter season. But if we measured the soil water contents continuously, we could obtain better time-dependent parameter. Key words : SMAP(Surface Moisture Availability Parameter), Paddy field, Volumetric soil water content, Evaporation, Capillary potential.