• Proceedings of the Korean Environmental Sciences Society Conference
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• 2018.10a
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• pp.50-50
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• 2018

• Journal of Korean Society of Water and Wastewater
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• v.21 no.6
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• pp.653-661
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• 2007

The Disinfectants/Disinfection By-products (D/DBP) Rule proposed by the US Environmental Protection Agency requires the implementation of enhanced coagulation as a control strategy for natural organic matter (NOM) removal and as a means of limiting the formation of all DBPs, i.e., not just the trihalomethanes and haloacetica acids. To control DBP formation, several best available technologies (BATs) were determined for removal of DBPs and DBP precursors. The enhanced coagulation is one of the BATs for DBP precursors removal. Treatment facilities that achieve a specified percent removal of total organic carbon (TOC) prior to the application of a continuous disinfectant or that achieve a residual TOC concentration < 2mg/L prior to the application of a continuous disinfectant are considered to be in compliance with enhanced coagulation. The enhanced coagulation was applied to raw water in Korea, the Han River. Raw water were examined and effects of different raw water qualities on enhanced coagulation were investigated. Three analyses were used for raw water characteristics, water quality measurement, molecular weight distributions, hydrophobic/hydrophilic fractionation. The Han River had the relatively low alkalinity and low organic carbon concentration. The results of molecular weight distributions showed significant portions of low molecular weight organics, which is very different from most water in USA. The alum doses for the required TOC removal guided from USEPA manual were quite low (i.e. 10~30 mg/L alum) for the water, probably due to the specific water quality of the Han River.

• Journal of Korean Society of Water and Wastewater
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• v.21 no.3
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• pp.315-322
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• 2007

The purpose of this study was to investigate the biodegradability and performance of organic removal and methane production rate when treating piggery wastewater using a granule of two-phase anaerobic process applied UASB. BMP test was conducted as simple means to monitor relative biodegradability of substrate and to determine methane production of an organic material. The two-phase anaerobic process is consisted of a continuous flow stirred-tank reactor (CFSTR) for the acidification phase and an Upflow Anaerobic Sludge Blanket reactor (UASB) for the methanogenesis. The acidogenic reactor played key roles in reducing the periodically applied shock-loading and in the acidification of the influent organics. A stable maximum biogas production rate was 400mL. The methane contents ranged from 73 to 80% during the experimental period. It is known that most of the removed organic matter was converted to methane gas, and the produced biogas might be high quality for its subsequent use.

• Journal of Korean Society of Water and Wastewater
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• v.19 no.6
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• pp.775-780
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• 2005

This study was performed to investigate the effect of foulant characteristics on Membrane fouling index such as Silt Density Index (SDI) and Modified Fouling Index (MFI). A linear relationship was found relating the fouling index (both SDI and MFI) on particle concentration, but fouling index values were nonlinearly (exponentially) with increasing organic concentration. When organic matter was the primary cause of fouling, the MFI was not accurately predicted due to internal fouling such as pore adsorption. The fouling index was determined mainly by particle characteristics when both particle and organic coexisted in the feed water. This observation was attributed to lessening of organic pore adsorption by particle cake layer formed on the membrane surface. Bench-scale actual fouling experiments demonstrated that permeate flux declines much faster with feed water containing particles than organic matters although fouling potential predicted by SDI values were identical, indicating that the accurate prediction of fouling potential requires the development of fouling index reflecting different foulant characteristics.

• Journal of Korean Society of Water and Wastewater
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• v.22 no.1
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• pp.131-140
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• 2008

The application of magnetic ion exchange resin($MIEX^{(R)}$) is effective for natural organic matter(NOM) removal and for control of the formation of disinfection byproducts(DBPs). NOM removal is also enhanced by adding $MIEX^{(R)}$ with coagulant such as polyaluminium chloride(PACl) in conventional drinking water treatment systems. In the application of $MIEX^{(R)}$, it is important to understand changes of NOM characteristics such as hydrophobicity and molecular weight distributions with $MIEX^{(R)}$ or $MIEX^{(R)}$+coagulant treatment.To observe characteristics of NOM by treatment with $MIEX^{(R)}$ or $MIEX^{(R)}$+coagulant, four major drinking water sources were employed. Results showed that the addition of $MIEX^{(R)}$ to coagulation significantly reduced the amount of coagulant required for the optimum removal of dissolved organic matter(DOC) and turbidity in the all four waters. The DOC removal was also increased approximately 20%, compared to coagulant treatment alone. The process with $MIEX^{(R)}$ and coagulant showed that complementary removal of hydrophobic and hydrophilic fraction of DOC. The combined processes preferentially removed the fractions of intermediate (3,000-10,000 Da) and low (< 500 Da) molecular weight. The microfiltration test showed that membrane cake resistance was decreased for waters with flocs from $MIEX^{(R)}$+coagulant. A porous layer was formed to $MIEX^{(R)}$ on the membrane surface and the layer consequently inhibited settling of coagulant flocs, which could act on a foulant.

• Journal of Korean Society of Water and Wastewater
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• v.30 no.3
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• pp.233-240
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• 2016

Control degree and property changes of dissolved organic matter (DOM) were conducted by coagulation of chemical treatment for 2 sewage treatment plants with different technical methods. As the result, SUVA value of the second treated water (supernatant of the second settling pond after biological treatment) was increased and DOC was reduced in comparison with supplied raw water. And, SUVA value and DOC were reduced by coagulation after coagulation treatment of the second treated water. Properties of dissolved organic matter for 2 sewage treatment plants's DOC were divided. As the result, there was lots of hydrophilic component with hydrophilicity in case of plant A. In case of the second treated water, Plant A showed fulvic acid with little molecular weight was reduced among the hydrophobic component with hydrophobicity, but numic acide with lots of molecular weight was increased. However, in case of plant B, both fulvic acid with little molecular weight and humic acid with lots of molecular weight were increased among the hydrophobic components with hydrophilicity. Before the operation of phosphorus facility, properties of dissolved organic matter after biodegradation with effluent water showed hydrophilic components were reduced and hydrophobic components were increased. However, after coagulation treatment of the second treated water, hydrophilic components and hydrophobic components were outstandingly decreased or increased. During the biodegradation after coagulation treatment, hydrophilic components were significantly decreased and hydrophobic components were increased.

• Membrane and Water Treatment
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• v.10 no.6
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• pp.471-484
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• 2019

The complex combination of organic contaminants in the wastewater made water treatment challenging; hence, organic matter in water bodies is usually measured in terms of organic carbon. Since it is important to identify the types of compounds when deciding suitable treatment methods, this study implemented a quantitative and qualitative analysis of the organic matter content in an actual graywater sample from Ulsan, Republic of Korea using mass spectroscopy (MS). The graywater was treated using adsorption to remove the organic contaminants. Using orbitrap MS, the organic matter content between an untreated graywater and the treated effluent were compared which yielded a significant formula count difference for the samples. It was revealed that CHON formula has the highest removal count. Isotherm studies found that the Freundlich equation was the best fit with a coefficient of determination ($R^2$) of 0.9705 indicating a heterogenous GAC surface with a multilayer characteristic. Kinetics experiments fit the pseudo-second order equation with an $R^2$ of 0.9998 implying that chemisorption is the rate-determining step between the organic compounds and GAC at rate constant of $52.53g/mg{\cdot}h$. At low temperatures, the reaction between GAC and organic compounds were found to be spontaneous and exothermic. The conditions for optimization were set to achieve a maximum DOC and TN removal which yielded removal percentages of 94.59% and 80.75% for the DOC and TN, respectively. The optimum parameter values are the following: pH 6.3, 2.46 g of GAC for every 30 mL of graywater sample, 23.39 hrs contact time and $38.6^{\circ}C$.

• Journal of Korean Society of Water and Wastewater
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• v.26 no.5
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• pp.685-692
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• 2012

UV technology is widely used in water and wastewater treatment. Many researches have been conducted on microbial disinfection and micro pollutant reduction with UV treatment. However, the study on NOM with UV has limited because low/medium pressure UV lamp is not sufficient to affect refractory organics such as NOM. Pulsed UV treatment using UV flash lamp can be operated in the pulsed mode with much greater peak intensity. The pulse duration is typically in microseconds, whereas the interval between pulses is in the order of milliseconds. The high intensity of pulsed UV would mineralize NOM itself as well as change the characteristics of NOM. Chlorine demand and DBPs formation is affected on the changed amounts and properties of NOM. The objective of this study is to investigate the effect on NOM, chlorine residual, and chlorinated DBPs formation with pulsed UV treatment.

• Journal of Environmental Health Sciences
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• v.34 no.6
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• pp.452-458
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• 2008

This study was undertaken to establish the biological reaction characteristics of the marine products industry wastewater which contains high concentrations of organic matter and saline. As the S/I is varied from 0.3 to 1.2, the results were follows : the observed ultimate anaerobic biodegradability varied from 72.0 to 88.0%, the first order reaction rate varied from 0.1735 to $0.3420\;day^{-1}$ and the second order reaction rate varied from 0.0132 to $0.0295\;day^{-1}$. When S/I was 0.9, the first order reaction rate had a maximum value, but the variations of the second order reaction rate were less than 1st-order reaction rate. When the operation time exceeded 2 days the gas production rapidly increased. The source of this rapid increase was due to that the activity of the granular sludge used in this study being faster than that of conventional sludge. Under aerobic condition, the characteristics of organic matter were as follows: the marine industry wastewater used in this study contained about 81% of biodegradable matter, and it was divided into readily biodegradable COD(Ss), slowly biodegradable COD(Xs), soluble COD(Si) and inert suspended COD (Xi). The percentages of each COD were 87.3%, 23.9%, 6.4% and 12.4% respectively.

• Korean Journal of Ecology and Environment
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• v.46 no.2
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• pp.175-184
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• 2013

Organic carbon and total nitrogen stable isotope ratios of suspended materials were determined at 3 stations (from Mongtan Bridge to Youngsan river estuary barrage) (n=6, each) from November 2008 to August 2009, in order to understand the origin of particulate organic matter at the Estuary of Youngsan River. Allochthonous organic matter, ammonia-N and silicate were increased after heavy rain (in August). Carbon isotope ratios were significantly different between stations in November and August, and it was possible to determine the origin of organic matter. The heavier nitrogen isotope ratios, as well as higher phosphate concentrations, were found in November than other sampling times. Livestock wastewater and farmland input was likely the main causes of these high values. In addition, YS3 station, the nearest site to estuary barrage, appears to be affected by a substantial amount of livestock wastewater and farmland input, considering that nitrogen isotope ratios were heavier than those at the upper sites. These results suggest that the analysis of stable isotope ratios is a simple but useful tool for the determination of organic matter origin in aquatic environments.