Characteristics of Natural Organic Matter (NOM) on Han River and Criterion of Enhanced Coagulation

한강원수 자연유기물의 특성분석 및 강화응집 기준 평가

  • 정영미 (한국과학기술연구원 환경기술연구단) ;
  • 권지향 (건국대학교 공과대학 환경공학과) ;
  • 이상협 (한국과학기술연구원 환경기술연구단)
  • Received : 2007.04.03
  • Accepted : 2007.11.14
  • Published : 2007.12.15

Abstract

The Disinfectants/Disinfection By-products (D/DBP) Rule proposed by the US Environmental Protection Agency requires the implementation of enhanced coagulation as a control strategy for natural organic matter (NOM) removal and as a means of limiting the formation of all DBPs, i.e., not just the trihalomethanes and haloacetica acids. To control DBP formation, several best available technologies (BATs) were determined for removal of DBPs and DBP precursors. The enhanced coagulation is one of the BATs for DBP precursors removal. Treatment facilities that achieve a specified percent removal of total organic carbon (TOC) prior to the application of a continuous disinfectant or that achieve a residual TOC concentration < 2mg/L prior to the application of a continuous disinfectant are considered to be in compliance with enhanced coagulation. The enhanced coagulation was applied to raw water in Korea, the Han River. Raw water were examined and effects of different raw water qualities on enhanced coagulation were investigated. Three analyses were used for raw water characteristics, water quality measurement, molecular weight distributions, hydrophobic/hydrophilic fractionation. The Han River had the relatively low alkalinity and low organic carbon concentration. The results of molecular weight distributions showed significant portions of low molecular weight organics, which is very different from most water in USA. The alum doses for the required TOC removal guided from USEPA manual were quite low (i.e. 10~30 mg/L alum) for the water, probably due to the specific water quality of the Han River.

Keywords

Acknowledgement

Supported by : 서울지역환경기술개발센터

References

  1. 김정현 (1999) Enhanced Coagulation의 적용성 평가 연구. 한국수처리학회지. 7(4). pp. 31-41
  2. 박현, 김창모, 장현성, 김현숙, 박창민, 한성희 ,유명진, (2006) 한강본류와 유입지천의 천연유기물과 염소소독부산물 생성능 고찰, 2006년 대한환경공학회 학술발표회
  3. Edzwald, J.K. (1993) Coagulation in Drinking Water T reatrnent: Particles, Organic and Coagulation, Water Science Tech., 27(11), pp. 21-35 https://doi.org/10.2166/wst.1993.0261
  4. Edzwald, J.K and Bencshoton, J.E. Van. (1990) Aluminiwn Coagulation of Natural Organic Matter, Proc. of 4th Gothenburg Sym.
  5. Edzwald J. K., John E. Tobiason (1999) Enhanced Coagulation: US requirements and a Broader View, Wat. Sci. Tech., 40(9), pp. 63-70
  6. Kimberlyk, A.B. and Mortza, A., Gary, A. (1996) Enhanced and Optimized Coagulation for removal of Particulate and Microbial Contaminants, In Proceedings of the 1996 AWWAAnnual Conference, New York, pp. 303-310
  7. Marc Edwards (1997) Predicting DOC Removal During Enhanced Coagulation, J. AWWA, 89(5), pp. 78-89
  8. Mark C. White, Jeffrey D. Thompson, Gregory W. Harrington, Philip C. Singer (1997) Evaluating criteria for enhanced coagulation compliance, J. AWWA, 89(5), pp. 6477
  9. Mark Morgan, John Mogavero, Gail Charles (1995) Optimization of Particulate Removal under Enhanced Coagulation Conditions, In Proceedings of the 1995 A WW A Annual Conference, New Orleans
  10. Seung-Hyun Kim (2005) Enhanced Coagulation: Determination of Controlling Criteria and An effect on Turbidity Removal, Environ. Eng. Res., 10(3), pp. 105-111 https://doi.org/10.4491/eer.2005.10.3.105
  11. Singer, P.C. (1995) Enhanced Coagulation and Enhanced Softening gar the Removal of Disinfection By-product Precursors: An Evaluation Report to the Disinfectants/ Disinfection By-products Technical Advisory Workgroup of the Water Utility Council of the AWWA
  12. Thurman, E.M., Tonald L. Malcolm (1981) Preparative Isolation of Aquatic Humic Substances, Environ. Sci. & Tech., 15(4), pp. 463-466 https://doi.org/10.1021/es00086a012
  13. US Environmental Protection Agency (1999) Definitions of Enhanced Coagulation and Enhanced Precipitative Softening, Prepared for Health and Ecological Criteria Div., Washington, D.C.
  14. US Environmental Protection Agency (1998) National primary drinking water regulations: disinfectants and disinfection by-products. Fed Regist 63(241): 69389