• 자원리싸이클링
• /
• 제22권1호
• /
• pp.48-54
• /
• 2013

LCD용 편광필름에 핵심적으로 사용되어진 요오드화칼륨 (KI, Potassium Iodide) 폐용액으로부터 분별결정법을 이용하여 고순도의 요오드화칼륨 결정을 제조하는 실험을 행하였다. 본 연구에서는 붕소, 나트륨 및 PVA 등의 불순물을 포함한 1.3% 요오드화칼륨 폐액을 3회에 걸쳐 농축하였으며, 용해도 차이를 이용하여 최대 불순물인 붕소화합물을 제거하고, 여과지를 이용하여 유기물을 제거하였다. 또한 24시간 숙성을 통하여 $K_2SO_4$ 형태로 불순물을 제거하여 99.5% 이상의 고순도 요오드화칼륨 결정을 제조하였으며, 재결정을 통하여 농축되어진 불순물을 약 70% 제거할 수 있었다.

• 한국농공학회지
• /
• 제38권5호
• /
• pp.106-115
• /
• 1996

This study was carried out to provide fundamental data for reuse of resources and prevention of environmental pollution Actual states of environmental pollution by biological production facilities were investigated. Various pollution loads and quantity of wastes from greenhouse and animal housings estimated. In greenhouse contents of investigation were wastes of plastic cover, noise of heater and fan, air pollutant of heater, and wastes of soilless culture system, etc. In animal housings, those were actual state of livestock waste treatment and reuse, pollutant mass unit discharge, noise pollution, and malodorant, etc. The main pollutants discharged from greenhouses were wastes of plastic cover, rockwool, and waste fluid of nutrient solution. Developments of waste disposal methods for plastic cover and rockwool are required. And recycle technique of nutrient solution for soilless culture should be developed and propagated. With the buildup of legal control, pollutant mass discharged from livestock wastes are, on the decrease. The other side, reuse of livestock excreta increased. Most animal housings are located near the dwelling house. Malodorant and noise from animal housings have bad effects on the rural living conditions. So developments of integrated complex for small scale livestock farms are required.

• 한국분말재료학회지
• /
• 제30권6호
• /
• pp.502-508
• /
• 2023

With the increasing demand for electronic products, the amount of multilayer ceramic capacitor (MLCC) waste has also increased. Recycling technology has recently gained attention because it can simultaneously address raw material supply and waste disposal issues. However, research on recovering valuable metals from MLCCs and converting the recovered metals into high-value-added materials remains insufficient. Herein, we describe an electrospinning (E-spinning) process to recover nickel from MLCCs and modulate the morphology of the recovered nickel oxide particles. The nickel oxalate powder was recovered using organic acid leaching and precipitation. Nickel oxide nanoparticles were prepared via heat treatment and ultrasonic milling. A mixture of nickel oxide particles and polyvinylpyrrolidone (PVP) was used as the E-spinning solution. A PVP/NiO nanowire composite was fabricated via E-spinning, and a nickel oxide nanowire with a network structure was manufactured through calcination. The nanowire diameters and morphologies are discussed based on the nickel oxide content in the E-spinning solution.

• 한국표면공학회지
• /
• 제57권2호
• /
• pp.92-97
• /
• 2024

The LiBr aqueous solution, which is the absorption liquid of absorption refrigerator, must be replaced periodically because the concentration of impurities such as Cu²⁺, Fe²⁺, Ca²⁺, etc., increases due to corrosion of the tubes as the period of use increases, and the refrigeration efficiency decreases significantly. In order to reuse the waste absorption liquid, flocculation-precipitation method is mainly applied to precipitate the impurities, which requires hundreds of times the concentration of impurities and generates additional waste. In this study, a process for removing Cu ion impurities from cyclone electrolyzer by electrolytic reduction is presented in a small-scale facility without additional waste. It was confirmed that Cu ion impurities can be removed down to 1 ppm by electrolytic reduction process, and to further improve the removal rate, the mass transfer rate was increased by using a cyclone electrolyzer. The removal rate of Cu ions increased with the increase of flow rate and current density, and it was confirmed that Cu was removed at a rate of 1.48 ppm/h under the condition of 330 mL/sec and 2.5 mA/cm².

• 한국산학기술학회논문지
• /
• 제16권11호
• /
• pp.7736-7744
• /
• 2015

막대한 산업용 에너지가 폐열로 버려지는 상황에서 폐열, 특히 저온 폐열의 효과적인 이용은 매우 중요하다. 본 연구에서는 $160^{\circ}C$의 고온 열원과 $17^{\circ}C$ 저온 하수열을 사용하여 $50^{\circ}C$의 온수를 $70^{\circ}C$로 승온시키며 성적계수는 1.6을 만족하는 2중 효용 2단 흡수식 히트펌프 사이클을 고안하였다. 제 1 재생기에서 증발한 냉매 증기는 제 1 응축기에서 응축하면서 제 2 재생기에서 다시 냉매를 발생시킨다. 이 냉매는 제 2 응축기를 거쳐 제 2 증발기에 모아진다. 이 냉매의 일부는 제 1 증발기로 이동하여 저온 열원을 받아들이고 제 1 흡수기를 거쳐 제 2 증발기에 공급된다. 제 2 증발기를 나온 냉매는 제 2 흡수기에서 용액에 흡수된다. 이 때 온수의 온도는 제 2 응축기와 제 2 흡수기에서 승온된다. 시행착오를 통하여 승온 $20^{\circ}C$, 성적계수 1.6을 만족시키는 유량과 열교환기의 UA 값을 도출하였다. 성적계수는 고온수의 온도가 증가할수록, 온수의 온도가 감소하고 유량이 증가할수록, 폐온수의 온도와 유량이 증가할수록, 용액 순환량이 감소할수록 증가한다. 반면 온수의 승온온도는 고온수의 온도가 증가할수록, 온수의 온도가 증가하고 유량이 감소할수록, 폐온수의 온도와 유량이 증가할수록, 용액 순환량이 증가할수록 증가한다. 또한, 열교환기의 UA 값이 증가할수록 성적계수 및 온수 승온 온도도 증가한다.

• 산업기술연구
• /
• 제21권B호
• /
• pp.45-49
• /
• 2001

Many cities and provinces are rapidly depleting landfill spaces. As the result, some municities have adopted to incinerate their municipal solid waste(MSW). The motive behind the choice is that incineration significantly reduces the volume of solid waste in need of disposal, destroys the harmful organic compounds that are present in MSW, and provides an attractive source of alternative energy. Conclusively, the generation of MSW ash is expected to increse in the furture. However, disposing the MSW ash in landfills may not always be an environmentally or an economically feasible solution. This paper addresses the various issues associated with MSW ash and its possible use in construction applications.

• 한국표면공학회지
• /
• 제36권2호
• /
• pp.194-199
• /
• 2003

Polarization measurements were peformed to investigate the electrochemical behavior of copper ions and limiting current density in waste rinse water from copper electroplating processes. A newly designed cyclone type electrolyzer was tested to recover the copper powder. Synthetic solutions were prepared using analytical grade $CuSO_4$ to the desired waste water concentration and pH was adjusted with $H_2$$SO_4$. Electrowinning was peformed at room temperature and the solution was cycled with a pump. Results showed that more than 99 percent of Cu was recovered and the size of the recovered Cu powder ranges from 0.1 - $0.5\mu\textrm{m}$. The chemical composition of the Cu powder mainly consists of $Cu_2$O and Cu and can be easily reduced to pure Cu powder.

• 대한전자공학회:학술대회논문집
• /
• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
• /
• pp.387-392
• /
• 2001

Kobe Steel, LTD. and Midrex Technologies Inc. jointly developed the FASTMET$\circledR$ process as a steel mill waste recycle technology in which the DRI product meets BF feed material or BOF/EAF feed material requirements. FASTMET(R) process turns value-less wastes into valuable DRI and sellable zinc oxide, and gives the solution for the steel mill wastes recycling from both economical and environmental viewpoints. During the development of the process, Laboratory, Pilot Plant and Demonstration Plant tests were carried out from 1990 to 1998. The first FASTMET(R) commercial plant began operation in April, 2000 and the second commercial plant started in April, 2001 Both commercial plants have proceeded successfully preying that FASTMET$\circledR$ is a suitable process for recycling steel mill waste and for producing DRI as an iron source.

• 한국환경과학회지
• /
• 제12권1호
• /
• pp.63-68
• /
• 2003

Effective alginate extraction from waste-brown seaweeds was studied. The waste-brown seaweeds almost consist of stems of seaweeds. Alginate could be obtained from the stems as well as leaves of seaweed. Ultrasonic vibration(47kHz) facilitated filtering step in the alginate extraction process. Among various alkalies for alginate extraction, $NaHCO_3$ was most appropriate concerning use of dealginates. The yield of alginate extraction using $NaHCO_3$ 2wt% solution was 19.3% at $60^{\circ}C$. The dealginates from $NaHCO_3$-extraction process have been found most suitable food for red-worms.

• 한국펄프종이공학회:학술대회논문집
• /
• 한국펄프종이공학회 2011년도 추계학술발표회 논문집
• /
• pp.43-47
• /
• 2011

In woody waste separated from municipal solid waste, medium density fiberboard was major contributors with particleboard, paper, plywood and log, with different composition based on collected period. In chemical compositional analysis of woody waste, it was similar to softwood based on carbohydrate composition analysis. Based on the carbohydrate composition, saccharified solution from MWW could be good resource for biorefinery.