• 토지주택연구
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• 제15권1호
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• pp.147-156
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• 2024

본 연구는 시멘트 클링커 제조에 사용되는 탄산염 광물인 석회석(CaCO₃)을 CO₂가 결합되어 있지 않은 탈탄산 원료를 사용하여 제조 공정 중에 발생하는 CO₂를 저감하고자 하는 연구로 다양한 산업부산물 중 폐콘크리트에 부착되어 있는 시멘트페이스트를 이용하고자 하였다. 일반적으로 시멘트용 석회석은 최소한 CaCO₃의 함유량이 80% 이상(CaO, 44% 이상)의 것을 사용해야만 시멘트 클링커의 품질을 확보할 수 있다. 하지만 폐콘크리트 미분말의 CaO 함량은 평균 20% 정도로 시멘트 클링커 원료로 사용하기 위하여 CaO 함량을 35% 이상으로 조성비를 올려줘야 이용이 가능하다. 따라서 폐콘크리트 미분말의 조성 광물 경도차이를 이용하여 경도가 상대적으로 낮은 CaO 형태의 광물을 선택적으로 분쇄하여 분급 및 체가름을 할 경우 CaO 함량을 35% 이상 상승시킬 수 있다. 이에 본 연구에서는 분쇄 공정을 통해 경도가 상대적으로 낮은 CaO를 함유한 광물들을 선택적으로 분쇄하여 효율적으로 CaO와 SiO₂ 외 기타 성분을 분리하는 최적 조건에 대하여 실험적 및 통계적으로 검토·분석하였다. 시멘트 크링커 원료로서 탈탄산된 35% 이상 CaO를 함유한 폐콘크리트 미분말 제조를 위한 최적 분쇄 조건 실험 결과, 분쇄 시간 5분 이내, 피분쇄물 종류 30mm, 피분쇄물양 1.0 이상이 최적 조건인 것을 알 수 있었지만 단일 입도의 분쇄물이 아닌 혼합입도의 분쇄물에 대한 검토가 필요할 것으로 판단된다.

• Nuclear Engineering and Technology
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• 제24권3호
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• pp.219-227
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• 1992

모의 붕산폐액을 석회와 반응시키고 반응기를 겸한 건조기에서 이를 건조시켜 얻어진 건조물의 특성을 살펴보았다. 반응과 건조후 생성된 건조물의 주된 화학종은 2CaO.B$_2$O$_3$로 확인되었다 건조물의 입도분포로부터 첨가제로서는 생석회가 소석회보다 우수함을 알 수 있었고, 건조물의 부착성 및 응집성을 고려하여 반응몰비(Ca/B)는 3/4인 조건으로 결정하였다. 수분함량이 8 wt% 정도까지 되도록 건조시켜도 건조물은 유동성이 있어 수송에 문제가 발생되지 않으며 건조시간의 단축도 가능하다.

• Fisheries and Aquatic Sciences
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• 제25권7호
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• pp.357-379
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• 2022

Increased fisheries products have raised by-products that are discarded due to low economic value. In addition, marine by-products are still rich in protein and nutritional value that have biological activities and give benefits to human health. Meanwhile, there is raised pressure for sustainability practices in marine industries to reduce waste and minimize the detrimental effect on the environment. Thus, valorization by-products through bioactive peptide mining are crucial. This review focus on various ways to obtain bioactive peptides from marine by-products through protein hydrolysis, for instance chemical hydrolysis (acid and based), biochemical hydrolysis (autolysis and enzymatic hydrolysis), microbial fermentation, and subcritical water hydrolysis. Nevertheless, these processes have benefits and drawbacks which need to be considered. This review also addresses various biological activities that are favorable in pharmaceutical industries, including antioxidant, antihypertensive, anticancer, anti-obesity, and other beneficial bioactivities. In addition, some potential marine resources of Indonesia for the marine biopeptide from their by-product or undesired marine commodities would be addressed as well.

• 한국건설순환자원학회논문집
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• 제12권3호
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• pp.306-313
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• 2024

본 연구는 국내 시멘트 산업의 폐합성수지 활용 현황과 대체연료 사용량 증가에 따른 시멘트 내 염화물 함량에 대해 조사하였으며, 국내외 시멘트 및 콘크리트 내 염화물 기준 조사를 통해 KS제도 개선 필요성에 대해 고찰하였다. 2016~2023년에 조사된 각사별 연평균 염화물 함량 중 최대값은 485 ppm이었으며, 폐합성수지 사용량 증가 시 1,033 ppm까지 증가할 것으로 계산되었다. 국내 콘크리트 염화물 관리 기준은 총량제로서 0.3 kg/m³ 로 제한하고 있지만, 계산된 시멘트 염화물량(1,033 ppm)을 기준으로 하였을때 단위시멘트량이 290 kg/m³ 이상이 되는 경우 현행 KS 염화물 기준을 만족하기 어려운 것으로 나타났다. 해외 다수의 국가에서는 시멘트 투입량에 따라 콘크리트 염화물량을 제한하는 종량제를 채택하고 있는 상황에서, 한국 또한 시멘트 산업의 탄소중립 달성을 위해서 연구수행을 통한 합리적 염화물 기준도출과 이해관계자 공감대 형성을 통해 종량제 도입 추진이 검토되어야 할 것으로 생각된다.

• 펄프종이기술
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• 제37권3호
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• pp.50-58
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• 2005

It is generally known that paper industry is the second largest industry in the use of process water, and also have the highest environmental impact load in the contaminant sources. Paper is produced from the mixtures composed of 1% fibrous raw materials and 99% water. The optimum use of process water effects on the quality properties of paper and the environmental impact load of waste water treatment. In this research, the kinds of fibrous raw material & additives used in the paperboard production line were investigated, and the quantification of environmental loads and the environmental effects of process water on COD potential were evaluated. The NBDCODs were also analyzed from process water by the method of waste water treatment in paper mill and applied for the optimum use of recycling water, and zero effluent process. In the fibrous raw materials, KOCC caused the highest COD potentials, and sack paper & UKP was comparatively low. The NBDCOD of KOCC largely reduced after biological treatment because of easily biodegradable properties, but AOCC contained non-biodegradable materials. In chemical additives, COD was high in turns of rosin>starch>deaeration agent>dye, NBDCOD greatly reduced in starch and deaeration agent. In the case of 2 kinds of paperboard product, the COD potentials was mainly high in starch, AOCC and KOCC.

• 자원리싸이클링
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• 제10권1호
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• pp.7-15
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• 2001

본 연구에서는 여러 가지 건설 부산물 중에서 단순히 폐기되거나 매립에 의존하고 있는 폐콘크리트를 대상으로 건설공사에 재이용하기 위한 기술 즉, 폐콘크리트의 콘크리트용 골재(재생골재)로서의 재이용과 콘크리트 구조용 재료로써의 재사용을 위한 기술적인 방향을 제시하고 실험적 자료를 구축하고자 하였다 실험결과, 안전을 고려하여 재생골재 대체율은 30%이하, 최대철근비를 균형 철근비의 70%이하, 깊은 보의 기준은 전단 스팬비 2.0이하로 보는 것이 타당하고, 계수전단강도의 예측에는 Zsutty식을 사용하는 것이 합리적이라고 판단된다.

• 분석과학
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• 제31권3호
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• pp.112-121
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• 2018

The hydrothermal carbonization method has received great attention because of the conversion process from biomass. The reaction produces various products in hydrochar, bio-liquid, and gas. Even though its yield cannot be ignored in amount, it is difficult to find research papers on bio-liquid generated from the hydrothermal carbonization reaction of biomass. In particular, the heterogeneity of feedstock composition may make the characterization of bio-liquid different and difficult. In this study, bio-liquid from the hydrothermal carbonization reaction of food wastes at $230^{\circ}C$ for 4 h was investigated. Among various products, fatty acid methyl esters were analyzed using two different extraction methods: liquid-liquid extraction and column chromatography. Different elutions with various solvents enabled us to categorize the various components. The eluents and fractions obtained from two different extraction methods were analyzed by gas chromatography with a mass spectrometer (GC/MS). The composition of the bio-liquid in each fraction was characterized, and seven fatty acid methyl esters were identified using the library installed in GC/MS device.

• Journal of Microbiology and Biotechnology
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• 제28권9호
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• pp.1493-1501
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• 2018

Wastewater from cider factories (losses during transfers, products discarded due to quality policies, and products returned from the market) exhibits a Chemical Oxygen Demand greater than $170,000mg\;O_2/l$, mainly due to the ethanol content and carbohydrates that are added to obtain the finished product. These effluents can represent up to 10% of the volume of cider produced, and they must be treated to meet environmental regulations. In this work, a process was developed, based on alcoholic fermentation of the available carbohydrates present in ciders. The impact of inhibitors at different pH, size and reuse of inoculums and different nutrient supplementation on the ethanol yield were evaluated. The use of a 0.5 g/l yeast inoculum and corn steep water as the nutrient source allowed for depletion of the sugars in less than 48 h, which increased the content of ethanol to more than 70 g/l.

• 한국미생물·생명공학회지
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• 제34권4호
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• pp.363-367
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• 2006

Food wastes were decomposed into the Mugri (Isung Engineering, Korea), a food waste reduction machine, with adding sawdust of cryptomeria. Degradation effects were better when the machine worked at over 45$^{\circ}C$ than those at the lower temperature. Thermophilic bacteria were isolated from cryptomeria sawdust and the food waste products degraded by the machine. The isolates from cryptomeria sawdust were classified into 3 genera (Acinetobacter baumannii, Enterobacter sp. and Erwinia cypripedii) and almost all the isolates from the degraded products were partially identified as Bacillus sp. by 16S rDNA sequence analysis. The isolated thermophilic bacteria showed degradative enzyme activities. In the case of addition of the 30 thermophilic bacteria into the machine, degradation rate of food wastes was almost twice as high with increasing process temperature up to 6$^{\circ}C$.

• 한국환경보건학회지
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• 제13권2호
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• pp.51-63
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• 1987

We identified pyrolysis condition, effect of catalyzer and pyrolysis mechanism through contact decomposed method by adding Bentonite in waste plastic of hospital solid waste. The result from this study were summarized as the followings: 1. The optimum fuel oil were obtained when hospital wasted plastic (P.P) and Bentonite were mixed in the ratio of 30:1. 2. Maximum absorption wave of hospital wasted plastic (P.P) appeared at 2900cm$^{-1}$, 1480cm$^{-1}$, 1360cm$^{-1}$ and 1180 cm$^{-1}$ by FT-IR and the plastics were identified and confirmed. 3. Reaction temperature of hospital wasted plastic started at 360$\circ$C, proceed rapidly at 437.5$\circ$C and finished at 481$\circ$C. The residue was 0.729%. When bentonire was added started at 318$\circ$C, proceed rapidly at 399.5$\circ$C and finished at 449.3$\circ$C, the residue being 4.23%. 4. Pyrolysis products of hospital wasted plastic were about 90 kinds. The Main components were 2-Heptene-3-ethyl-4-trimethyl (27.4%), 1-Heptene-2-isobutyl-6-methyl (8.6%) and 1-Heptene decene (7.7%). There was little component difference at different temperature. This is the result from stability of decomposition product. 5. Pyrolysis efficiency increased by the addition Bentonire. 6. Some of the Environmental and Sanitary problems could be solved by the pyrolysis of hospital wasted plastic and the decomposed products were to be used as fuel oil.