• 제목/요약/키워드: Waste products

검색결과 982건 처리시간 0.022초

An Insight Into the Recycling of Waste Flexible Polyurethane Foam Using Glycolysis

  • Woo Seok Jin;Pranabesh Sahu;Gyuri Kim;Seongrok Jeong;Cheon Young Jeon;Tae Gyu Lee;Sang Ho Lee;Jeong Seok Oh
    • Elastomers and Composites
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    • 제58권1호
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    • pp.32-43
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    • 2023
  • The worldwide use of polyurethane foam products generates large amounts of waste, which in turn has detrimental effects on the surroundings. Hence, finding an economical and environmentally friendly way to dispose of or recycle foam waste is an utmost priority for researchers to overcome this problem. In that sense, the glycolysis of waste flexible polyurethane foam (WFPF) from automotive seat cushions using different industrial-grade glycols and potassium hydroxide as a catalyst to produce recovered polyol was investigated. The effect of different molecular weight polyols, catalyst concentration, and material ratio (PU foam: Glycols) on the reaction conversion and viscosity of the recovered polyols was determined. The obtained recovered polyols are obtained as single or split-phase reaction products. Besides, the foaming characteristics and physical properties such as cell morphology, thermal stability, and compressive stress-strain nature of the regenerated flexible foams based on the recovered polyols were discussed. It was observed that the regenerated flexible foams displayed good seating comfort properties as a function of hardness, sag factor, and hysteresis loss compared to the reference virgin foam. With the growing demand for a sustainable and circular economy, a global valorization of glycolysis products from polyurethane scraps can be realized by transforming them into profitable substances.

붕산농축폐액 유리화 타당성 연구 (Feasibility Study on the Vitrification of Concentrated Boric Acid Waste)

  • 조현제;김득만;박종길
    • 방사성폐기물학회지
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    • 제8권2호
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    • pp.143-150
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    • 2010
  • 가압경수로 원전의 농축폐액건조설비에서 발생된 농축폐액 건조물을 유리화 하는 방안이 연구되어 왔다. 중저준위 방사성폐기물을 유리화할 경우 최종 생성물은 내구성이 우수하고 현저한 부피저감 효과의 장점을 가지고 있다. 붕산농축폐액에 대한 유리화 타당성 연구는 분말시료의 전처리 방법 개발, 유리조성 프로그램을 이용한 유리개발 및 실증시험으로 수행되었다. 분말시료에 대한 전처리 방안으로는 유리화설비에 투입하기 전에 고형성을 갖도록 펠렛화하는 것이다. 농축폐액 성분중 Na와 B의 함량 분포는 유리속에 용융되는 정도와 설비로부터의 폐기물 배출 처리에 영향을 주기 때문에 이를 고려하여 유리조성이 개발되어야 한다. 실증시험에서는 폐기물 투입률, 배기체 특성 및 최종 생성물인 유리고화체의 특성이 검토되었다. 본 연구는 붕산농축폐액에 대한 유리고화체의 물리화학적 특성을 검토하고 유리화 타당성을 확인하는데 목적이 있다.

Effect of alkali pretreatment on bioconversion of waste money bill to glucose for bio-ethanol production

  • Sheikh, M. Mominul Islam;Kim, Chul-Hwan;Park, Hyun-Jin;Kim, Sung-Ho;Kim, Gyeong-Chul;Lee, Ji-Yong;Kim, Jae-Won
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2011년도 추계학술발표회 논문집
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    • pp.167-177
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    • 2011
  • Renewable energy resources and technologies have the potential to provide long-lasting solutions of the global energy-requirements faced by the economic and environmental sectors of a nation. Therefore, waste money bills were used as renewable energy source for the production of bio-ethanol. In this study, different concentrated NaOH 0.5%. 1.0%, 2.0%, 3.0% and 0.0% (as a control) were used for 10, 20 and 30 mins at $121^{\circ}C$/15 psi in an autoclave. Saccharification and fermentation (aerobic and anaerobic) were carried out through commercial enzyme Celluclast 1.5 L, Novozymes 188 and Saccharomyces cerevisiae KCCM 11304 respectively. The results of pretreatment showed that the NaOH pre-treated substrate enhanced enzyme action and released more amount of glucose. The amount of glucose was found with the increasing concentration of NaOH and time $44996.95{\pm}6.30$, $46763.10{\pm}3.56$, $53421.32{\pm}4.72$, $63431.25{\pm}6.95$ and $56850.98{\pm}6.75\;ng/{\mu}l$ for 30 min respectively. As for bioethanol, the conversion rate of NaOH resulted $1010.08{\pm}4.71$, $1050.25{\pm}4.37$, $1109.49{\pm}4.39$, $1139.25{\pm}3.26$ and $1020.77{\pm}3.89$ ppm for aerobic; $16730.54{\pm}6.67$, $17076.45{\pm}6.25$, $17516.17{\pm}4.49$, $19782.68{\pm}6.19$ and $17973.39{\pm}7.50$ ppm for anaerobic and $18935.02{\pm}4.59$, $19895.45{\pm}5.39$, $21912.95{\pm}4.83$, $24895.21{\pm}6.72$ and $18961.21{\pm}4.90$ ppm for anaerobic condition with benzoic acid for respective condition. Thus, the results of the present work clearly revealed that with the increasing of alkali concentration might be more effective for bio-ethanol production from waste money bill, which is economic and environmental friendly.

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폐콘크리트 미분말 대체율 및 양생방법에 따른 압출경화체의 강도특성 (The strength characteristic of extruding solid according to substitution ratio and curing methods of waste concrete powder)

  • 유재성;김진만;이명진
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2015년도 추계 학술논문 발표대회
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    • pp.49-50
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    • 2015
  • Recently, by-products from concrete industry are generated in large quantities because of urban redevelopment. Accordingly, waste concrete powder(WCP) inevitably generated in the course of crushing, screening, and separating the waste concrete also show high emission and be increasing gradually, but which is mostly buried with waste concrete aggregate. This is a basic research to increase the value added utilization rate of WCP. We have examined strength characteristic of extruding panel with WCP, depending on the curing methods. The result of study shows similar strength to the base specimen in autoclave curing condition. And in autoclave curing condition, the specimen with WCP of 20% and 30% satisfy the target strength of 14MPa.

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폐유리를 혼입한 콘크리트의 동결융해 저항성에 관한 실험적 연구 (An Experimental Study on the Freeze-Thaw Resistance of Concrete Containing Waste Glass)

  • 박승범;정명일;이봉춘;이준
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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    • pp.593-598
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    • 2002
  • Recently, as industrialization is rapidly growing and the standard of life is rising, the quantities of waste glasses have been hastily increased and most of them are not recycled but abandoned. It causes some problems such as the waste of natural resources and environmental pollution. Therefore, in this study freeze-thaw resistance test was conducted to analyze the properties of concrete containing waste glasses as fine aggregates and containing industrial by-products (fly ashes, silica fumes). As a results, it was found that freeze-thaw resistance decreases as the content of waste glasses increases. Also, the content of fly ash doesn't affect to the freeze-thaw resistance, and freeze-thaw resistance decreases with tile increase of silica fume contents.

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굴패각으로 인한 산업부산물 발생과 처리현황 실태조사 (A Field Survey on the Generation of Industrial Waste Oyster Shells and their Disposal Status)

  • 김지현;송원호;문훈;정철우;이재용
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2013년도 추계 학술논문 발표대회
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    • pp.146-147
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    • 2013
  • The oyster shells of about 240,000 tons have been annually produced in south coast of South Korea. However, about 25% of the oyster shells (60,000tons) was recycled as oyster seeding and fertilizer due to the limited amount of consumption for such purposes. The stored amount of oyster shell in the fertilizer manufacturing company is overfilled, and thus cannot accept any more of the waste oyster shells. As a result, landfill and illegal dumping of waste oyster shells have become an increasingly serious issue since 2011. In this research, the problems generated by the oyster shells were investigated through surveying activities. One of the possible alternative solutions that can process large amount of waste economically was found to be the application of oyster shells as a construction materials.

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폐본차이나를 활용한 도자기 소지 개발 (Development of Ceramics Body using Waste Bone China)

  • 이제일;이용석;이병하
    • 한국세라믹학회지
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    • 제48권1호
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    • pp.46-51
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    • 2011
  • The influx of Western culture and the food culture have altered the tableware of Korea, increasing the amount of using tableware. The representative tableware is known as bone china. Considering not only the amount of bone china waste generated from broken tableware at homes and but also faulty bone china products at factories, the bone china waste disposed in simple landfills is to be a serious environmental problem to solve. In this study, following "the research on development of ceramics body using waste celadon" of which the possibility was confirmed, development of ceramics body is conducted by recycling waste bone china. From the result of the study, it was understood that maximum addition of waste bone china was 20% of the whole material on the basis of measurement of plasticity. So 20% of pulverized bone china was added and the characteristics were evaluated, and the result was that porosity, water absorptivity and plasticity were 0.756%, 0.339% and 24.13%, respectively. Bending strength was $672\;kgf/cm^2$, which showed a good sintering condition. Therefore, it was considered that waste bone china could be utilized for development of new porcelain material.

산업용제조시설과 폐기물처리시설에서 발생된 나노폐기물의 물리화학적 특성 및 안전관리방안 제시 (Suggestion of Physicochemical Characteristics and Safety Management in the Waste Containing Nanomaterials from Engineered Nano-materials Manufacturing Plants and Waste Treatment Facilities)

  • 김우일;연진모;조나현;김용준;엄남일;김기헌;이영기
    • 한국폐기물자원순환학회지
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    • 제35권7호
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    • pp.670-682
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    • 2018
  • Engineered nanomaterials (ENMs) can be released to humans and the environment through the generation of waste containing engineered nanomaterials (WCNMs) and the use and disposal of nano-products. Nanoparticles can also be introduced intentionally or unintentionally into waste streams. This study examined WCNMs in domestic industries, and target nanomaterials, such as silicon dioxide, titanium oxide, zinc oxide, nano silver, and carbon nanotubes (CNTs), were selected. We tested 48 samples, such as dust, sludge, ash, and by-products from manufacturing facilities and waste treatment facilities. We analyzed leaching and content concentrations for heavy metals and hazardous constituents of the waste. Chemical compositions were also measured by XRD and XRF, and the unique properties of nano-waste were identified by using a particle size distribution analyzer and TEM. The dust and sludge generated from manufacturing facilities and the use of nanomaterials showed higher concentrations of metals such as lead, arsenic, chromium, barium, and zinc. Oiled cloths from facilities using nano silver revealed high concentrations of copper, and the leaching concentrations of copper and lead in fly ash were higher than those in bottom ash. In XRF measurements at the facilities, we detected compounds such as silicon dioxide, sulfur trioxide, calcium oxide, titanium dioxide, and zinc oxide. We found several chemicals such as calcium oxide and silicon dioxide in the bottom ash of waste incinerators.