• Title/Summary/Keyword: Waste liquid

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Implementation of a Management Applied Program for Liquid Radioactive Waste Treatment (방사성 액체폐기물 처리공정 관리 응용프로그램 구현)

  • 이영희;안섬진;조한석;손종식
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.141-148
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    • 2003
  • A data collection of a liquid radioactive waste treatment process of a research organization became necessary while developing the RAWMIS(Radioactive Waste Management Integration System) which it can generate personal history management for efficient management of a waste, documents, all kinds of statistics. This paper introduces an input and output application program design to do to database with data in the results and a stream process of a treatment that analyzed the waste occurrence present situation and data by treatment process. Data on the actual treatment process that is not limited experiment improve by a document, human traces, saving of material resources and improve with efficiency of tracking about a radioactive waste and a process and give help to radioactive waste material valance and inventory study.

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Electrolytic Deposition of Metal Ions Using A Liquid Cadmium Cathode

  • Shim, Joon-Bo;Ahn, Byung-Gil;Kwon, Sang-Woon;Kim, Eung-Ho;Yoo, Jae-Hyung
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.337-337
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    • 2004
  • As one of researches for the P & T purposes, a basic experiment on the recovery of actinide elements from the mixture with rare earth elements by means of electrorefining using a liquid cadmium cathode in the LiCl-KC1 eutectic melt was carried out. In order to examine the behaviors of electrodeposition of metal ions on a liquid electrode, recovery experiments of rare earth metals resulting from forming electrodeposits were performed by a galvanostatic electrolysis method at various current densities. A cyclic voltammetric technique was applied to determine reduction-oxidation potential of each metal element in the melt and to detect the changes of the multi component melt composition for on-line monitoring. Also, a collaboration study with RIAR was completed to test the preliminary feasibility on a recovery of actinide elements from the mixture with rare earth elements using a liquid cadmium cathode and actinide metals. Experimental results showed that the ratio of actinides to rare earths, 9: 0.5∼1 led to the rare earth content of about 5∼10 wt% in the deposit.

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Tansport Rate of Chromium ion from Waste Water through the Liquid Surfactant Membrane Containing Carrier (운반체 함침 유화액막에 의한 폐수중 크롬(VI)의 이동속도)

  • Woo, In-Sung;Kim, Kyoung-Ho;Lee, Sang-Jin;Kang, An-Soo;Choi, Sei-Young
    • Elastomers and Composites
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    • v.23 no.1
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    • pp.11-17
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    • 1988
  • The transport of chromium(VI) ion from waste water through the liquid surfactant membrane containing tri-n-octylamine as a carrier, was analyzed by a slab model and was investigated through experiments. For the experiment of membrane stability, concentrations of surfactant and liquid paraffin oil were analyzed. Extraction experiments were carried out to observe the effect of system variables, such as concentrations of carrier, and initial chromium(VI) ion in external aqueous phase at $25^{\circ}C$. It is concluded that the most stable formation of liquid membrane emulsion was obtained when surfactant concentration is above 3 wt.% and liquid paraffin oil concentration is 50 vol.%. The theoretical equation on the transport of chromium(VI) ion agreed well with the experimental results.

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Comparative Study of Dose Evaluation of Liquid Effluent in Nuclear Power Plants for Radiological Impact on the Environment Review

  • Seokju Hwang;Si-Young Kim;Deuk-Man Kim;Young Hwan Hwang;Jungkwon Son
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.22 no.1
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    • pp.45-54
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    • 2024
  • Currently, off-site dose calculations for nuclear power plants are conducted using a computer program (K-DOSE 60). The program is developed based on the regulatory guidelines of the Korea Institute of Nuclear Safety (KINS), which is a domestic nuclear regulatory agency. In this study, a domestic application of the International Atomic Energy Agency (IAEA) TRS (Technical Reports Series)-472 methodology for 3H and 14C in liquid effluents was studied. The dose-evaluation methods adopted and the program configuration for dose evaluation are described based on 3H and 14C in the liquid-effluent-evaluation module of the computer program. The accuracy of the program is verified by comparing the program-calculated results with hand calculation values. Furthermore, a comparative evaluation with LADTAP II, which is a liquid-effluent-evaluation methodology developed by the U.S. NRC (Nuclear Regulatory Commission), is performed. The result confirms that the program-calculated results for the IAEA TRS-472 methodology are consistent with the hand calculation values. Meanwhile, the result of comparative evaluation with LADTAP II indicates different results depending on the methodology used.

Theoretical Analysis of Heat Transport Limitation in a Screen Mesh Wick Heat Pipe

  • Lee, Ki-Woo;Park, Ki-Ho;Lee, Wook-Hyun;Rhi, Seok-Ho
    • International Journal of Air-Conditioning and Refrigeration
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    • v.12 no.1
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    • pp.1-9
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    • 2004
  • The purpose of the present study is to examine the heat transport limitations in a screen mesh heat pipe for electronic cooling by theoretical analysis. Diameter of pipe was 6mm, and mesh numbers were 50, 100, 150, 200 and 250, and water was investigated as working fluid. According to the change of mesh number, wick layer, inclination and saturation temperature, the maximum heat transport limitations by capillary, entraintment, sonic and boiling were analyzed by a theoretical design method of heat pipe, including capillary pressure, pumping pressure, liquid friction coefficient in wick, vapor friction coefficient, etc. Based on the results, the capillary limitation in a small diameter of heat pipe is largely affected by mesh number and wick layer. Mesh number of 250 is desirable not to be used in pipe diameter of 6 mm, because capillary heat transport limitation decreases by the abrupt increase of liquid friction pressure due to the small liquid flow area. For the heat transport of 15 watt in 6mm diameter pipe, mesh number of 100 and one layer is an optimum wick condition, which thermal resistance is the smallest.

NUCLIDE SEPARATION MODELING THROUGH REVERSE OSMOSIS MEMBRANES IN RADIOACTIVE LIQUID WASTE

  • LEE, BYUNG-SIK
    • Nuclear Engineering and Technology
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    • v.47 no.7
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    • pp.859-866
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    • 2015
  • The aim of this work is to investigate the transport mechanism of radioactive nuclides through the reverse osmosis (RO) membrane and to estimate its effectiveness for nuclide separation from radioactive liquid waste. An analytical model is developed to simulate the RO separation, and a series of experiments are set up to confirm its estimated separation behavior. The model is based on the extended Nernst-Plank equation, which handles the convective flux, diffusive flux, and electromigration flux under electroneutrality and zero electric current conditions. The distribution coefficient which arises due to ion interactions with the membrane material and the electric potential jump at the membrane interface are included as boundary conditions in solving the equation. A high Peclet approximation is adopted to simplify the calculation, but the effect of concentration polarization is included for a more accurate prediction of separation. Cobalt and cesium are specifically selected for the experiments in order to check the separation mechanism from liquid waste composed of various radioactive nuclides and nonradioactive substances, and the results are compared with the estimated cobalt and cesium rejections of the RO membrane using the model. Experimental and calculated results are shown to be in excellent agreement. The proposed model will be very useful for the prediction of separation behavior of various radioactive nuclides by the RO membrane.

Isolation and Chemical Structure Identification of Allelopathic Substances from the Ginkgo(Ginkgo biloba L.) Leaf Waste Produced by Phamaceutical Process (제약폐기 은행잎중에 함유된 식물생육억제물질 분리동정)

  • Seong, Ki-Seog;Kim, Bok-Jin;Kwon, Oh-Kyung;Choi, Du-Hoi
    • Korean Journal of Soil Science and Fertilizer
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    • v.30 no.4
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    • pp.377-383
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    • 1997
  • Studies were conducted on the nature of allelopathic effect of the substances in the waste of ginkgo leaves from pharmaceutic factory. In the first step, to find out whether there was any allelophatic effect, young seedlings of radish and rice were grown in the water (crude) extract of ginkgo leaf waste and in different liquid/lquid partitioned fractions of EtOAc at pH 9, EtOAc at pH 3, and BuOH. As second step, attempts were made to isolate and identify the allelophatic substance in different liquid/liquid partitioned fractions using GC/MS and NMR techniques. The water (crude) extract of ginkgo leaf waste retarded the growth of radish seedlings under 10% concentration. In case of rice seedlings, the water extract of ginkgo leaf extract showed adverse effect on the growth when combined with $3.3{\times}10^{-6}M$ gibberellin A3. All of the liquid/liquid fractions of crude extract showed strong retardation of seedling growth of radish and rice at the concentration of 1%. Allelophatic substance was isolated from the crude extract using liquid/liquid partition, column chromatography and HPLC techniques. The analytical results of isolated componet using GC/MS and NMR proved that the allelophatic substance in the ginkgo leaf wastes is catechol; one of phenol compounds. Based on the experiences current study, a practical method for the testing of allelophatic effect of crude extract of some materials was proposed. In this method, rice seeds were allowed to sprout until the length of coleoptile to reach 0.5 mm. Such seedlings were submerged in the solution containing supposedly allelophatic substance and the length of shoot and root was measured 3 days after treatment.

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Development of Chemical and Biological Decontamination Technology for Radioactive Liquid Wastes and Feasibility Study for Application to Liquid Waste Management System in APR1400 (액체방사성폐기물에 대한 화학적, 생물학적 제염기술 개발 및 APR1400 액체폐기물관리계통 적용을 위한 타당성 연구)

  • Son, YoungJu;Lee, Seung Yeop;Jung, JaeYeon;Kim, Chang-Lak
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.17 no.1
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    • pp.59-73
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    • 2019
  • A decontamination technology for radioactive liquid wastes was newly developed and hypothetically applied to the liquid waste management system (LWMS) of the nuclear power plant (NPP) to evaluate its decontamination efficacy for the purpose of the fundamental reduction of spent resins. The basic principle of the developed technology is to convert major radionuclide ions in the liquid wastes into inorganic crystal minerals via chemical or biological techniques. In a laboratory batch experiment, the biological method selectively removed more than 80% of cesium within 24 hours, and the chemical method removed more than 95% of cesium. Other major nuclides (Co, Ni, Fe, Cr, Mn, Eu), which are commonly present in nuclear radioactive liquid wastes, were effectively scavenged by more than 99%. We have designed a module including the new technology that could be hypothetically installed between the reverse osmosis (R/O) package and the organic ion-exchange resin in the LWMS of the APR1400 reactor. From a technical evaluation for the virtual installation, we found that more than 90% of major radionuclides in the radioactive liquid wastes were selectively removed, resulting in a large volume reduction of spent resins. This means that if the new technology is commercialized in the future, it could possibly provide drastic cost reduction and significant extension of the life of resins in the management of spent resins, consequently leading to delay the saturation time of the Wolsong repository.

Hollandite-rich Synroc for Immobilization of Sr/Cs Separated from HLW Liquid

  • Zhao Yulong;Ii Baojun;xu Jianhua;Zhang Chuanzhi
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.11b
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    • pp.329-337
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    • 2005
  • Synroc which comprises hollandite-rich ($Ba_{1-x}Cs_{2x}\;(Al_yTi_{2-y})\;Ti_{6}O_{16},\;75wt\%$), perovskite ($Ca_{1-x}Sr_xTiO_3,\;15wt\%$) and rutile ($TiO_2,\;10wt\%$) is devised for the immobilization of Sr/Cs (1:3, wt$\%$) separated from HLW liquid. Especially, hollandite-rich Synroc with different contents of Al element is fabricated, and its mineral phase assemblage and microstructure are determined by using XRD and SEM/EDS. The durability test is carried out by using MCC-1 method, leachate is analyzed by using ICP/MS and ICP/ AES. The results indicate that hollandite-rich Synroc variants is a suitable host for Immobilization of Sr/Cs separated from HLW liquid.

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울진 5,6호기 액체방사성폐기물 처리설비 원심분리기 성능 고찰

  • Gang Hyeon-Tae;Hwang Su-Dong;Lee Hwa-Seok
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.196-199
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    • 2005
  • The centrifuge system in liquid radwaste system(LRS) is composed of several skids including Decanter and Separator. The decanter separates the sludge over 5mm in size within liquid radwaste by centrifuge force and drops it into 55gallon drum. The separator separates the sludge over $0.1{\mu}m$ in size within the liquid radwaste processed by Decanter by centrifuge force. The process of separating the sludge from the LRS keeps the resin in Ion Exchanger from being damaged and improves the performance of Ion Exchanger, and satisfies the decontamination factor suggested in Uljin 5,6 FSAR to safety discharge into the outer environment.

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