• Title/Summary/Keyword: Waste gas

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CFD Analysis on the Internal Reaction in the SNCR System (SNCR 시스템 내부의 물질 반응에 관한 전산해석적 연구)

  • Koo, Seongmo;Yoo, Kyung-Seun;Chang, Hyuksang
    • Clean Technology
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    • v.25 no.1
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    • pp.63-73
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    • 2019
  • Numerical analysis was done to evaluate the chemical reaction and the reduction rate inside of selective non-catalytic reduction to denitrification in combustion process. The $NO_X$ reduction in selective non-catalytic reduction is converted to not only nitrogen but also nitrous oxide. Simultaneous $NO_X$ reduction and nitrous oxide generation suppressing is required in selective non-catalytic reduction because nitrous oxide influences the global warming as a greenhouse gas. The current study was performed compare the computational analysis in the same temperature and amount of NaOH, and in comparison with the previous research experiments and confirmed the reliability of the computational fluid dynamics. Additionally, controlling the addition amount of NaOH to predict the $NO_X$ reduction efficiency and nitrous oxide production. Numerical analysis was done to check the mass fraction of each material in the measurement point at the end of selective non-catalytic reduction. Experimental Value and simulation value by numerical analysis showed an error of up to 18.9% was confirmed that a generally well predicted. and it was confirmed that the widened temperature range of more than 70% $NO_X$ removal rate is increased when the addition amount of NaOH. So, large and frequent changes of the reaction temperature waste incineration facilities are expected to be effective.

Characteristics of RDF Char Combustion in a Bubbling Fluidized Bed (기포 유동층 내에서 RDF 촤의 연소 특성)

  • Kang, Seong-Wan;Kwak, Yeon-Ho;Cheon, Kyoung-Ho;Park, Sung Hoon;Jeon, Jong-Ki;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.22 no.4
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    • pp.429-432
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    • 2011
  • The feasibility of applications of the char obtained from a gasification process of municipal-waste refuse derived fuel (RDF) as an auxiliary fuel was evaluated by combustion experiments. The higher heating value of the RDF char was 3000~4000 kcal/kg and its chlorine content was below the standard requirement demonstrating its potential as an auxiliary fuel. In the combustion exhaust gas, the maximum $NO_x$ and $SO_2$ concentrations were 240 ppm and 223 ppm, respectively. If an aftertreatment is applied, it is possible to control their concentrations low enough to meet the air pollutant emission standard. The HCl concentration was relatively high indicating that a care should be taken for HCl emission from the combustion of RDF. Based on the temperature distribution within the reactor, the concentration change of $O_2$ and $CO_2$, and the amount and the loss on ignition of solid residue, it was inferred that the combustion reaction was the most reliable when the excess air ratio of 1.3 was used.

Comparison of Construction Cost Applied by RC and PC Construction Method for Apartment House and Establishment of OSC Economic Analysis Framework (공동주택 RC 및 PC공법 적용 공사비 비교 및 OSC의 포괄적 경제성 분석 프레임워크 구축)

  • Yun, Won-Gun;Bae, Byung-Yun;Kang, Tai-Kyung
    • Korean Journal of Construction Engineering and Management
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    • v.23 no.6
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    • pp.30-42
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    • 2022
  • OSC is a type of supply chain and value chain that spans the entire process of construction production (planning, design, construction, maintenance, etc.). It is a method of producing the final object by manufacturing it in a factory, transporting it to the site, installing and construction. This research as is the construction cost was compared for each case A, which applied the PC method, and case B, which applied the RC method. In the case of applying the PC method (excluding the PC design cost), compared to the case where only the RC method was applied, the frame construction cost per unit quantity (m3) increased by about 70% (50% based on the total RC construction type). Of the total frame construction cost of PC method application, PC accounted for 90.2%, 'PC manufacturing cost' 54.8%, 'PC assembly cost' 28.5%, and 'transportation cost' accounted for 6.89%. Also a decision-making framework that can consider both costs and benefits was established. In the case of benefits, the construction period, defect repair, disaster occurrence, energy efficiency, noise/dust/waste, and greenhouse gas emission indicators reflecting OSC technical advantages were presented. It can contribute to providing a basis for helping decision-making on the introduction of PC apartment houses using OSC.

Optimal Capacity Determination of Hydrogen Fuel Cell Technology Based Trigeneration System And Prediction of Semi-closed Greenhouse Dynamic Energy Loads Using Building Energy Simulation (건물 에너지 시뮬레이션을 이용한 반밀폐형 온실의 동적 에너지 부하 예측 및 수소연료전지 3중 열병합 시스템 적정 용량 산정)

  • Seung-Hun Lee;Rack-Woo Kim;Chan-Min Kim;Hee-Woong Seok;Sungwook Yoon
    • Journal of Bio-Environment Control
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    • v.32 no.3
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    • pp.181-189
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    • 2023
  • Hydrogen has gained attention as an environmentally friendly energy source among various renewable options, however, its application in agriculture remains limited. This study aims to apply the hydrogen fuel cell triple heat-combining system, originally not designed for greenhouses, to greenhouses in order to save energy and reduce greenhouse gas emissions. This system can produce heating, cooling, and electricity from hydrogen while recovering waste heat. To implement a hydrogen fuel cell triple heat-combining system in a greenhouse, it is crucial to evaluate the greenhouse's heating and cooling load. Accurate analysis of these loads requires considering factors such as greenhouse configuration, existing heating and cooling systems, and specific crop types being cultivated. Consequently, this study aimed to estimate the cooling and heating load using building energy simulation (BES). This study collected and analyzed meteorological data from 2012 to 2021 for semi-enclosed greenhouses cultivating tomatoes in Jeonju City. The covering material and framework were modeled based on the greenhouse design, and crop energy and soil energy were taken into account. To verify the effectiveness of the building energy simulation, we conducted analyses with and without crops, as well as static and dynamic energy analyses. Furthermore, we calculated the average maximum heating capacity of 449,578 kJ·h-1 and the average cooling capacity of 431,187 kJ·h-1 from the monthly maximum cooling and heating load analyses.

Evaluation of human exposure to polychlorinated biphenyls using human serum by congener-specific analysis (혈액 중 PCBs 이성질체별 분석에 의한 인체 노출 평가)

  • Park, Hyo-Keun;Lee, Se-Jin;Jin, Guang-Zhu;Kang, Jung-Ho;Baek, Song-E;Chang, Yoon-Seok
    • Analytical Science and Technology
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    • v.19 no.1
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    • pp.73-85
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    • 2006
  • Blood serum concentrations of polychlorinated biphenyls (PCBs) were measured in employees who worked at a municipal solid waste incinerator (MSWI), members of residential community who lived near the MSWI (<0.3km) and members of residential community lived far from the MSWI (>10 km). Human blood serum samples were analyzed for all PCB congeners using high-resolution gas chromatography/high-resolution mass spectrometry (HRGC/HRMS). The mean levels of total PCBs and dioxin-like PCBs in 87 serum samples were 242.77 ng/g lipid and 8.83 TEQ pg/g lipid, respectively. The PCB homologue profiles showed that penta-, hexa-, hepta-chlorinated biphenyls contributed more than 80% of the total PCBs concentration. The most abundant congeners were PCB153, PCB138, PCB180, PCB187, PCB118. A statistical analysis was performed to determine whether there were significant correlations between PCB concentrations and specific variables such as age, gender, smoking habits, occupation, BMI (Body Mass Index) and time of residence. As a result, the age was found to be strongly correlated with serum PCB concentrations. In addition, there were strong correlations between total PCBs and PCB153 (r=0.93, p<.0001), dioxin-like PCBs and PCB118 (r=0.98, p<.0001). So these two congeners are satisfactory indicators for total PCB concentrations and dioxin-like PCBs in human blood respectively.

Current status of brominated flame retardants (BFR) and polybrominated dibenzo-p-dioxins and furans (PBDDs/PBDFs) (브롬화난연제 및 브롬화다이옥신류의 연구동향)

  • Kwon, Myung-Hee;Song, Ki-Bong;Kang, Yung-Ryul;Hwang, Seung-Ryu;Shin, Sun Kyoung;Kim, Kum-Hee;Park, Jin Soo;Kim, Sue-Jin;Lee, Su-Yung;Kim, Dong-Hoon;Jung, Kwang-Yong
    • Analytical Science and Technology
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    • v.21 no.6
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    • pp.443-458
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    • 2008
  • Brominated flame retardants (BFRs) are chemical compounds that inhibit the combustion of organic materials by scavenging free radicals that would otherwise encourage the spread of flames. These compounds are found in a wide variety of materials including paints, plastics, textiles, furniture and electronics. Mounting evidence, however, suggests that the non-reactive BFRs can easily leach into the environment and pose significant environmental and health concerns. PBDDs/PBDFs are often formed in the process of manufacturing brominated flame retardants and from the combustion of waste products containing flame retardants BFR. Therefore, this paper describes the general characteristics, management status, residual concentration in environments and analytical method.

A Study on Influencing Factors to build a Counter-Drone system : Focusing on national important facilities (대(對)드론(Counter-Drone)체계 구축을 위한 영향요인 분석 -국가중요시설을 중심으로-)

  • Nam-Il Lee
    • The Journal of the Convergence on Culture Technology
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    • v.10 no.4
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    • pp.483-494
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    • 2024
  • This study is a study on influencing factors to derive considerations when establishing a large drone integrated protection system targeting important national facilities. Currently, drone protection is implemented by piecemeal installation of drone protection equipment developed on the market in response to the needs of government agencies, the military, and national important facilities. For this reason, there is a waste of resources, such as duplicate installation or overlapping operation of equipment, and institutional and legal problems between operations are emerging. Accordingly, we sought to identify factors influencing the establishment of an efficient and systematic anti-drone protection system targeting national important facilities. Considering the research purpose and scope, this study derived 3 influencing factors and 12 detailed influencing factors through case analysis, protection theory research, and analysis of related laws. If the results of this study are used as considerations when building an integrated anti-drone protection system in the future, all national defense elements will be integrated and systematic integrated anti-drone protection will be possible according to their respective roles. In addition, it will provide a theoretical foundation for building an integrated anti-drone protection system. The results of this study are valuable in that they present logical and systematic influencing factors for establishing an integrated anti-drone protection system.

Scheme on Environmental Risk Assessment and Management for Carbon Dioxide Sequestration in Sub-seabed Geological Structures in Korea (이산화탄소 해양 지중저장사업의 환경위해성평가관리 방안)

  • Choi, Tae-Seob;Lee, Jung-Suk;Lee, Kyu-Tae;Park, Young-Gyu;Hwang, Jin-Hwan;Kang, Seong-Gil
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.12 no.4
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    • pp.307-319
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    • 2009
  • Carbon dioxide capture and storage (CCS) technology has been regarded as one of the most possible and practical option to reduce the emission of carbon dioxide ($CO_2$) and consequently to mitigate the climate change. Korean government also have started a 10-year R&D project on $CO_2$ storage in sea-bed geological structure including gas field and deep saline aquifer since 2005. Various relevant researches are carried out to cover the initial survey of suitable geological structure storage site, monitoring of the stored $CO_2$ behavior, basic design of $CO_2$ transport and storage process and the risk assessment and management related to $CO_2$ leakage from engineered and geological processes. Leakage of $CO_2$ to the marine environment can change the chemistry of seawater including the pH and carbonate composition and also influence adversely on the diverse living organisms in ecosystems. Recently, IMO (International Maritime Organization) have developed the risk assessment and management framework for the $CO_2$ sequestration in sub-seabed geological structures (CS-SSGS) and considered the sequestration as a waste management option to mitigate greenhouse gas emissions. This framework for CS-SSGS aims to provide generic guidance to the Contracting Parties to the London Convention and Protocol, in order to characterize the risks to the marine environment from CS-SSGS on a site-specific basis and also to collect the necessary information to develop a management strategy to address uncertainties and any residual risks. The environmental risk assessment (ERA) plan for $CO_2$ storage work should include site selection and characterization, exposure assessment with probable leak scenario, risk assessment from direct and in-direct impact to the living organisms and risk management strategy. Domestic trial of the $CO_2$ capture and sequestration in to the marine geologic formation also should be accomplished through risk management with specified ERA approaches based on the IMO framework. The risk assessment procedure for $CO_2$ marine storage should contain the following components; 1) prediction of leakage probabilities with the reliable leakage scenarios from both engineered and geological part, 2) understanding on physio-chemical fate of $CO_2$ in marine environment especially for the candidate sites, 3) exposure assessment methods for various receptors in marine environments, 4) database production on the toxic effect of $CO_2$ to the ecologically and economically important species, and finally 5) development of surveillance procedures on the environmental changes with adequate monitoring techniques.

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The Effect of Chloride Additives and pH on Direct Aqueous Carbonation of Cement Paste (시멘트 풀의 직접수성탄산화에서 Chloride 첨가제와 pH의 영향)

  • Lee, Jinhyun;Hwang, Jinyeon;Lee, Hyomin;Son, Byeongseo;Oh, Jiho
    • Journal of the Mineralogical Society of Korea
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    • v.28 no.1
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    • pp.39-49
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    • 2015
  • Recently, carbon capture and storage (CCS) techniques have been globally studied. This study was conducted to use waste cement powder as an efficient raw material of mineral carbonation for $CO_2$ sequestration. Direct aqueous carbonation experiment was conducted with injecting pure $CO_2$ gas (99.9%) to a reactor containing $200m{\ell}$ reacting solution and the pulverized cement paste (W:C = 6:4) having particle size less than 0.15 mm. The effects of two additives (NaCl, $MgCl_2$) in carbonation were analyzed. The characteristics of carbonate minerals and carbonation process according to the type of additives and pH change were carefully evaluated. pH of reacting solution was gradually decreased with injecting $CO_2$ gas. $Ca^{2+}$ ion concentration in $MgCl_2$ containing solution was continuously decreased. In none $MgCl_2$ solution, however, $Ca^{2+}$ ion concentration was increased again as pH decreased. This is probably due to the dissolution of newly formed carbonate mineral in low pH solution. XRD analysis indicates that calcite is dominant carbonate mineral in none $MgCl_2$ solution whereas aragonite is dominant in $MgCl_2$ containing solution. Unstable vaterite formed in early stage of experiment was transformed to well crystallized calcite with decreasing pH in the absence of $MgCl_2$ additives. In the presence of $MgCl_2$ additives, the content of aragonite was increased with decreasing pH whereas the content of calite was decreased.

Environmental Effects on the Growth and Development of Tomato in Composting Greenhouse (퇴비발효온실의 환경조건이 토마토의 생육에 미치는 영향)

  • 양원모;홍지형;박금주;손보균
    • Journal of Bio-Environment Control
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    • v.5 no.2
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    • pp.202-209
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    • 1996
  • The environment in composting greenhouse is very different with the traditional greenhouse by biothermal energy and $CO_2$ concentration. This experiment aimed to investigate the environmental effects on the growth and development of tomato grown at composting greenhouse. The room temperature is not different between two greenhouses because of heating and ventilation, but the soil temperature in composting greenhouse is about 7$^{\circ}C$ to 15$^{\circ}C$ higher than that of traditional greenhouse. The emission concentration of ammonia gas is the highest, 117.3ppm, at the 6th day starting the digest, and were gradually lowered from 7th day, 11 became 15.7ppm at the 16th day. The concentration of $CO_2$ in composting greenhouse were 250 to 2000ppm higher than that of traditional greenhouse for 4 months starting digest. The growth and development of tomato grown at composting greenhouse was better than that of traditional greenhouse. The yield in composting greenhouse was also better than that of traditional greenhouse. The sugar contents of tomato grown at composting greenhouse became about 1 $^{\circ}$Brix higher than that of traditional greenhouse.

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