• Title/Summary/Keyword: Waste ceramic

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Relationship of Ceramic Insulation Panel System Development and Verification of LCC

  • Han, Min-Cheol;Jeon, Kyu-Nam;Lee, Gun-Cheol;Kim, Tae-Hui
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.4
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    • pp.386-392
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    • 2012
  • In this study, life cycle cost (LCC) is analyzed according to insulation panel system type using a deterministic LCC analysis method. Through this analysis, it was found that the construction cost in the deterministic LCC analysis for Ceramic panels was low compared to the construction cost for metal and stone panels. Also, the difference in cost between the Ceramic panel and the metal panel was about 2 times. In the area of maintenance cost, it was found to be similar to the previously analyzed construction cost, in which the metal panel has the highest cost due to the high cost of construction and the frequent need for maintenance. In the case of the stone panel, a small difference in cost is shown compared with that of the Ceramic panel, but the cost is higher than the Ceramic panel. Regarding the cost of waste disposal, the Ceramic panel can reduce the cost by at least 1.5 times and up to 2 times compared to other panel systems. Finally, in the analysis of sensitivity according to changes in discount rates, the Ceramic panel and metal panel systems have a similar cost, and the cost of the metal panel is a bit larger than that of other panel systems. Thus, in the subjects used in the analysis, the Ceramic panel system shows the highest economic benefits.

Synthesis and Properties of Calcium Sulfoaluminate Clinker Using Waste Shell, Spent Oil-Refining Catalyst and Desulfurized Gypsum (폐패각-정유폐촉매-배연탈황석고를 사용한 Calcium Sulfoaluminate 클링커의 합성과 특성)

  • Lee, Keon-Ho;Song, Tae-Woong
    • Journal of the Korean Ceramic Society
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    • v.42 no.7 s.278
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    • pp.483-489
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    • 2005
  • For the raw materials of 3CaO$\cdot$3Al$_{2}$O$_{3}$ $\cdot$CaSO$_{4}$(CSA) clinker manufacturing, the applications of industrial wastes such as waste shell, spent oil-refining catalyst and desulfurized gypsum were examined. The c1inkerbility of the raw mix and the behaviour of formation of clinker minerals were studied and then some hydraulic properties of cements containing the clinker were also investigated. By virtue of the high reactivity of thermally decomposed raw materials, CSA clinkers were obtained at relatively low temperature of 1250$^{\circ}C$ and thus oil-refining catalysts were more desirable than aluminium hydroxide as an aluminous raw material. The expansive cement samples showed somewhat lower flow value than that of OPC, but their compressive strengths were developed earlier and higher than that of OPC due to formation of ettringite in the early hydration time, which indicated the possibility of practical use of low-cost CSA clinker using industrial wastes only.

Effects of Additives on the Phase Sepration and the Chemical Durability of Sodium Borosilicate Glasses (붕규산 소다 유리의 분상 및 화학적 내구성에 대한 첨가제의 영향)

  • 현상훈;천광수;송원선
    • Journal of the Korean Ceramic Society
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    • v.25 no.2
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    • pp.173-183
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    • 1988
  • Effects of oxide additives such as MoO3, MnO2 ZrO2 and Fe2O3 on the phase separation and the chemical durability of sodium borosilicate glasses which are the host of waste glasses have been investigated as the basic study on the nuclear-waste immobilization through vitrification. MoO3 and MnO2 were found to be phase separation promotors which increased the temperature as well as catalyzed nucleation and growth for the phase separation of the 10Na2-O-3OB2O3-6OSiO2 (wt%) parent glass within the immiscibility region. The glasses had the interconnected phase-separated structure as the amount of addition increased. On the other hand, ZrO2 and Fe2O3 were inhibitors which showed the reverse effects to the above promotors. It was also found that addition of MoO3 could cause the phase separaton of the 20Na2O-10B2O3-70SiO2(wt%) glass even within the miscibility region. Addition of ZrO2 and Fe2O3 increased the chemical durability of the parent glass within the immiscibility region. Within the miscibility region, however, the addition of 1.96 wt % of MoO3 increased the chemical durability considerably, while MnO2 had little effects.

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Manufacture and Properties of Coal Fly Ash-Clay Body (석탄회-점토계 소지의 제조 및 물성)

  • 송종택;윤성대;류동우;한경섭
    • Journal of the Korean Ceramic Society
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    • v.33 no.7
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    • pp.771-778
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    • 1996
  • Utilization of fly ash by-produced from coal fired power plants and classified as general waste became very important problem to solve in the environmental protection and recycling of waste materials. The possibility of large scale substitution of fly ash as a raw material for bricks and wet tiles was highly expected because the chemical compositions of fly ash were mostly Al2O3 and SiO2 and the properties of it were very similar with clay. Accordingly in order to investigate the substitutional limit these specimens were substituted from 0 to 100 wt% fly ash by 20wt% increment for clay. Fly ash-clay bodies were fired at 1200, 1250 and 130$0^{\circ}C$ and then their properties were measured, It was found that these specimens sintered at 125$0^{\circ}C$ had a good bending strength. Especially when these sintered bodies were added to 20, 40 and 60 wt% fly ash the bending strength of those were 201 , 205 and 191kg.cm2 respectively with the water absorption below 1%, This showed that fly ash could be substituted ab 60 wt% in this experiment.

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Fabrication and Physical Properties of Tiles Recycled Waste Glass (폐유리를 재활용한 타일 제조 및 물리적 특성)

  • Kim, Young-Kil;Jung, Yeon-Gil;Song, Jun-Baek;Shin, Min-Chul;Lee, Hee-Soo
    • Journal of the Korean Ceramic Society
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    • v.42 no.3 s.274
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    • pp.193-197
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    • 2005
  • Wall and floor tiles were fabricated by a dry pressing method using waste glass and clay. The physical properties of the tiles such as absorption, bulk density, porosity, compressive strength, and abrasion loss are investigated with the firing temperature and glass contents. The physical properties are improved with increasing the firing temperature and glass contents. The composition containing the glass of $70 wt%$ and fired at $1050^{\circ}C$ for 2 h has the good properties. The optimal properties obtained in the tiles are the water absorprion of about $0.9\%$, the bulk density of about $2.3\;g/cm^3$, the apparent porosity of about $2.1 \%$, the compressive strength of about 210 MPa, and the abrasion loss of about 0.022 g, when the composition containing the glass of $70\;wt\%$ is fired at $1050^{\circ}C$. The physical proper1ies of tiles fabricated were enhanced compared to the commercial clay tiles, due to easy melting and densification of glassy phase during the firing process.

Performance of High Temperature Filter System for Radioactive Waste Vitrification Plant (방사성폐기물 유리화 플랜트 고온여과시스템의 성능 특성)

  • Seung-Chul, Park;Tae-Won, Hwang;Sang-Woon, Shin;Jong-Hyun, Ha;Hey-Suk, Kim;So-Jin, Park
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.3
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    • pp.201-209
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    • 2004
  • Important operation parameters and performance of a high temperature ceramic candle filter system were evaluated through a series of demonstration tests at a pilot-scale vitrification plant. At the initial period of each test, due to the growth of dust cake on the surface of ceramic candles, the pressure drop across the filter media increased sharply. After that it became stable to a certain range and varied continuously proportion to the face velocity of off-gas. On the contrary, at the initial period of each test, the permeability of filter element decreased rapidly and then it became stable. Back flushing of the filter system was effective under the back flushing air pressure range of 3∼5 bar. Based on the dust concentrations measured by iso-kinetic dust sampling at the inlet and outlet point of HTF, the dust collection efficiency of HTF evaluated. The result met the designed performance value of 99.9%. During the demonstration tests including a hundred hour long test, no specific failure or problem affecting the performance of HTF system were observed.

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The Preparation of porous ceramic material from aluminum waste dross (알루미늄 廢드로스를 活用한 세라믹 多孔體의 製造)

  • Kim, Ki-Seok;Park, Jay-Hyun;Park, Jai-Koo
    • Resources Recycling
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    • v.14 no.2
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    • pp.19-27
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    • 2005
  • The recycling possibility of aluminum waste dross(AWD) as a ceramic raw material of porous light-weight material was examined. A aluminum waste dross was washed 4-7 consecutive times and roasted at 900$^{\circ}% for 1hour as pre-treatments. The properties of the pre-treatment of aluminum waste dross was investigated. It was conformed by XRD result that the spinel crystalline was grown in AWD, after roasting. After the roasted AWD was ground in aqueous state, the sodium hexaphosphate(SHP) as a dispersant which is used for stabilizing the concentrated slurry was added to the AWD slurry. The porous material was prepared by slurry foaming method with surfactant at room temperature. The foamed slurry volumes were 2 and 3 times of the original slurry volume. The properties of porous material with extended volume of 3 times was following: the porosity was about 84%, bulk density was 0.59 g/cm$^3$, the range of pore was from 50 ${\mu}m$ to 500 ${\mu}m$ and mean pore size was about 200 ${\mu}m$. AWD porous material was sintered at 1150$^{\circ}C-1250$^{\circ}C. It was colcluded that AWD was sintered well at 1200$^{\circ}C from material surface observation by SEM.

Survey on the Recycling of Waste Slag Generated by Smelting Reduction of Deep-Sea Manganese Nodules (망간단괴 용융환원 폐슬래그의 재활용 방안)

  • Park, Hyungkyu;Nam, Chulwoo;Kim, Sungdon
    • Resources Recycling
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    • v.23 no.4
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    • pp.69-74
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    • 2014
  • Slags generated in the smelting reduction of deep sea manganese nodule could be utilized as an additional materials for making Fe-Si-Mn alloys by mixing with cokes and re-smelting at an arc furnace. In this re-melting process slag is also generated, and the secondary slag is treated as waste. In this survey, recycling of the waste slag of Mn nodule was studied. It is tried to utilize the waste slag as ceramic materials or construction materials. However, it is difficult to use the waste slag directly as an additional material to ceramics such as portland cement or castable refractory material due to the much difference of chemical compositions. As an altercation road constructing material is considered, and toxicity on the soil of the waste slag was tested according to Korean Standard for testing permissible amount of toxic substances. The test result was satisfied with the requirements on the standard. So, it should be suggested that the waste slag of the Mn nodule could be utilized as constructing materials such as road filler or base materials.

The Separation of Particulate within PFC Decontamination Wastewater Generated by PFC Decontamination (PFC 제염 후 발생된 제염폐액 내 오염입자의 제거)

  • Kim Gye-Nam;Lee Sung-Yeol;Won Hui-Jun;Jung Chong-Hun;Oh Won-Zin;Park Jin-Ho;narayan M.
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.32-39
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    • 2005
  • When PFC(Perfluorocarbonate) decontamination technology is applied to removal of radioactive contaminated particulate adhered at surface during the operation of nuclear research facilities, it is necessary to develop a filtration equipment to reuse of PFC solution due to high price, also to minimize the volume of second wastewater. Contaminated characteristics of hot particulate was investigated and a filtration process was presented to remove suspended radioactive particulate from PFC decontamination wastewater generated on PFC decontamination. The range of size of hot particulate adhered at the surface of research facilities measured by SEM was $0.1{\sim}10{\mu}m$. Hot particulate of more than $2{\mu}m$ in PFC contamination wastewater was removed by first filter and then hot particulate of more than $0.2{\mu}m$ was removed by second filter. Results of filter experiments showed that filtration efficiency of PVDF(Poly vinylidene fluoride), PP(Polypropylene), Ceramic filter was $95{\sim}97\%$. A ceramic filter showed a higher filtration efficiency with a little low permeate volume. Also, a ceramic of inorganic compound could be broken easily on experiment and has a high price but was highly stable at radioactivity in comparison of PVDF and PP of a macromolecule which generate $H_2$ gas in alpha radioactivity environment.

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Environmentally Adaptive Stabilization of the Hazardous Heavy Metal Waste by Cementious Materials(II) (산업폐기물 중의 유해중금속의 환경친화적 안정화 처리(II))

  • Won, Jong-Han;Choi, Kwang-Hui;Choi, Sang-Hul;Lee, Hun-Ha;Sohn, Jin-Gun;Shim, Kwang-Bo
    • Journal of the Korean Ceramic Society
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    • v.39 no.12
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    • pp.1138-1142
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    • 2002
  • Slag cement and supersulfated slag cement were fabricated by mixing blast furnace slag and ordinary portland cement and adapted to solidify/stabilize heavy metal contained hazardous waste sludge. In case of slag cement, it showed continuous increase of their compressive strengths, which is attributed to the formation of the C-S-H, ettringite and monosulfate with STS sludge. However, BF and COREX sludge has a different shape and composition. therefore, adequate compressive strength could not be achieved with this slag cement. In case of the mixture of the each sludge like the STS-BF or the STS-COREX, the compressive strength over the standard level for disposing the wastes could be obtained with slag cement. The supersulfated slag cement that contain accelerators was very effective in solidifying the COREX sludge, which was difficult to solidify using different cement and obtained high compressive strength only for 3 days.