• Clean Technology
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• v.28 no.2
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• pp.97-102
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• 2022

Lithium sulfur (Li-S) batteries have attracted considerable attention as a promising candidate for next-generation power sources due to their high theoretical energy density, low cost, and eco-friendliness. However, the poor electrical conductivity of sulfur and its insoluble discharging products (Li₂S₂/Li₂S), large volume changes, severe self-discharge, and dissolution of lithium polysulfide intermediates result in rapid capacity fading, low Coulombic efficiency, and safety risks, hindering Li-S battery commercial development. In this study, a three-dimensionally (3D) connected hierarchical porous carbon framework (HPCF) derived from waste sunflower seed shells was synthesized as a sulfur host for Li-S batteries via a chemical activation method. The natural 3D connected structure of the HPCF, originating from the raw material, can effectively enhance the conductivity and accessibility of the electrolyte, accelerating the Li⁺/electron transfer. Additionally, the generated micropores of the HPCF, originated from the chemical activation process, can prevent polysulfide dissolution due to the limited space, thereby improving the electrochemical performance and cycling stability. The HPCF/S cell shows a superior capacity retention of 540 mA h g^-1 after 70 cycles at 0.1 C, and an excellent cycling stability at 2 C for 700 cycles. This study provides a potential biomass-derived material for low-cost long-life Li-S batteries.

• Resources Recycling
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• v.28 no.6
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• pp.79-86
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• 2019

Recently, the use of lithium ion battery(LIB) has increased. As a result, the price of lithium and the amount spent lithium on ion battery has increased. For this reason, research on recycling lithium in waste LIBs has been conducted1). In this study, the effect of roasting for the selective lithium leaching from the spent LIBs is studied. Chemical transformation is required for selective lithium leaching in NCM LiNi_xCo_yMn_zO₂) of the spent LIBs. The carbon in the waste EV cell powder reacts with the oxygen of the oxide at high temperature. After roasting at 550 ~ 850 ℃ in the Air/N₂ atmosphere, the chemical transformation is analysed by XRD. The heat treated powders are leached at a ratio of 1:10 in D.I water for ICP analysis. As a result of XRD analysis, Li₂CO₃ peak is observed at 700 ℃. After the heat treatment at 850 ℃, a peak of Li₂O was confirmed because Li₂CO₃ is decomposed into Li₂O and CO₂ over 723 ℃. The produced Li₂O reacted with Al at high temperature to form LiAlO₂, which does not leach in D.I water, leading to a decrease in lithium leaching ratio. As a result of lithium leaching in water after heat treatment, lithium leaching ratio was the highest after heat treatment at 700 ℃. After the solid-liquid separation, over 45 % of lithium leaching was confirmed by ICP analysis. After evaporation of the leached solution, peak of Li₂CO₃ was detected by XRD.

• Journal of Korean Society for Atmospheric Environment
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• v.24 no.5
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• pp.574-583
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• 2008

The results of HAPs emission data using TRI (Toxic Release Inventory), SODAM (Source Data Management system) were investigated and the emissions of 7 heavy metals from their sources and emission processes were also analyzed. Questionnaire for source data analysis as well as the stack sampling were carried out for 17 factories among 6 selected industrial types. The annual amount of emissions was estimated based on the measured concentration and flow rates. All sources were operated with high efficiency control devices and the concentration levels of all heavy metals were shown to be below 0.1 to of regulation standard. The highest emission source of heavy metals was steel manufacturing industry with the annual emission of 342.9 kg/yr and followed by hazardous waste incinerator, paint manufacturing, nonferrous metal manufacturing, rolling & press goods manufacturing and storage battery manufacturing. In the case of Hg, the emissions were quite significant from electric acros of steel manufacturing industry, although the concentration level was below the emission standard, showing the necessity of specific care for its management.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.6 no.4
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• pp.1076-1089
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• 2012

Home automation networks are good environments for merging sensor networks and consumer electronics technologies. It is very important to reduce the energy consumption of each sensor node because sensor nodes operate with limited power based on a battery that cannot be easily replaced. One of the primary mechanisms for achieving low energy operation in energy-constrained wireless sensor networks is the duty-cycle operation, but this operation has several problems. For example, unnecessary energy consumption occurs during synchronization between transmission schedules and sleep schedules. In addition, a low duty-cycle usually causes more performance degradation, if the network becomes congested. Therefore, an appropriate control scheme is required to solve these problems. In this paper, we propose UDC (Unsynchronized Duty-cycle Control), which prevents energy waste caused by unnecessary preamble transmission and avoids congestion using duty-cycle adjustment. In addition, the scheme adjusts the starting point of the duty-cycle in order to reduce sleep delay. Our simulation results show that UDC improves the reliability and energy efficiency while reducing the end-to-end delay of the unsynchronized duty-cycled MAC (Media Access Control) protocol in sensor-based home automation networks.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.4 no.5
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• pp.753-775
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• 2010

Greedy forwarding is a key mechanism of geographic routing using distance as a metric. As greedy forwarding only uses 1-hop neighbor node information, it minimizes routing overhead and is highly scalable. In existing greedy forwarding schemes, a node selects a next forwarding node based only on the distance. However, the signal strength in a realistic environment reduces exponentially depending on the distance, so that by considering only the distance, it may cause a large number of data packet retransmissions. To solve this problem, many greedy forwarding schemes have been proposed. However, they do not consider the unreliable and asymmetric characteristics of wireless links and thus cause the waste of limited battery resources due to the data packet retransmissions. In this paper, we propose a reliable and energy-efficient opportunistic greedy forwarding scheme for unreliable and asymmetric links (GF-UAL). In order to further improve the energy efficiency, GF-UAL opportunistically uses the path that is expected to have the minimum energy consumption among the 1-hop and 2-hop forwarding paths within the radio range. Comprehensive simulation results show that the packet delivery rate and energy efficiency increase up to about 17% and 18%, respectively, compared with the ones in PRR${\times}$Distance greedy forwarding.

• Journal of the Korean institute of surface engineering
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• v.56 no.4
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• pp.259-264
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• 2023

As the demand for lithium-ion batteries, a key power source in electric vehicles and energy storage systems, continues to increase for achieving global carbon neutrality, there is a growing concern about the environmental impact of disposing of spent batteries. Extensive research is underway to develop efficient recycling methods. While hydrometallurgy and pyrometallurgy methods are commonly used to recover valuable metals from spent cathode materials, they have drawbacks including hazardous waste and complex processes. Hence, alternative recycling methods that are environmentally friendly are being explored. However, recycling spent cathode materials still remains complex and energy-intensive. This study focuses on a novel approach called solid-state synthesis, which aims at regenerating the performance of spent cathode materials. The method offers a simpler process and reduces energy consumption. Optimal heat treatment conditions were identified based on experimental results, contributing to the development of sustainable recycling technologies for lithium-ion batteries.

• Journal of the Korea Society of Computer and Information
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• v.14 no.6
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• pp.73-81
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• 2009

TCP assumes that packet loss is always happened by congestionlike wired networks because is can not distinguish between congestion loss and transmission error loss,. This assumption results in unnecessary TCP performance degradation in wireless networks by reducing sender's congestion window size and retransmitting the lost packets. Also, repeated retransmissions loed to waste the limited battery power of mobile devices. In this paper, we propose the new congestion control scheme that add the algorithms monitoring networks states and the algorithms preventing congestion to improve TCP throughput performance and energy efficiency in wireless ad-hoc networks. Using NS2, we showd our scheme improved throughput performance and energy efficiency.

• Resources Recycling
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• v.28 no.5
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• pp.51-59
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• 2019

This study focused on the synthesis of the nickel hydroxide using ammonium sulfate in leaching solution from waste nickel-cadmium batteries. The effect of pH, temperature and the input amount of ammonium sulfate in leaching solution was investigated. The ammonium nickel sulfate with high purity was obtained in acidic leaching solution and the solution temperature of $60^{\circ}C$. The suitable molar ratio of the input amount of ammonium sulfate to nickel in solution is 2:1. The impurity about 1.4 at.% of Cd was included in the nickel hydroxide precipitates when ammonium nickel sulfate was used. At the process using sodium sulfide which precipitates the cadmium in solution, nickel and iron compounds were precipitated together.

• Journal of the Korean Chemical Society
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• v.63 no.6
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• pp.446-452
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• 2019

We have developed a method that can leach Co, Mn, and Ni in the cathode active material safely using lactic acid. When cathode active material was leached by lactic acid, lactic acid showed the highest efficiency at 2 N than 1 N and above 4 N concentration. When the cathode active material was added incrementally into the solution of lactic acid, the maximum solubility was 30 g/L at 2 N concentration. Oxalic acid was added in the solution of lactic acid and it showed that rare metals represent the most economical recovery efficiency at 4 g/L. Based on this study, it was found that the optimal condition for recovery of rare metals from cathode active material is oxalic acid : cathode active material = 7 : 1 as a ratio of weight. In addition, it was observed that the precipitate produced by oxalic acid is a polynuclear crystalline material bonded with 3 components of Co, Ni, and Mn.

• The KIPS Transactions:PartC
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• v.17C no.6
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• pp.499-504
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• 2010

The flooding is the simplest and effective way to disseminate a packet to all nodes in a wireless sensor network (WSN). However, basic flooding makes all nodes transmit the packet at least once, resulting in the broadcast storm problem in a serious case, in turn network resources become severely wasted. Particularly, power is one of the most valuable resources of WSNs as nodes are powered by battery, then the waste of energy by the basic flooding lessens the lifetime of WSNs. In order to solve the broadcast storm problem, this paper proposes a dynamic probabilistic flooding that utilizes the neighbor information like the number of child and sibling nodes. Simulation results show that the proposed method achieves a higher packet delivery ratio with the similar number of duplicate packets as compared to existing schemes.