• Title/Summary/Keyword: Waste acid

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An Experimental Study on the Utilization of Phosphogypsum as Daily and Intermediate Cover Materials (일일 및 중간복토재로서 인산석고 재활용을 위한 실험 연구)

  • 이용수;정형식
    • Journal of the Korean Geotechnical Society
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    • v.18 no.1
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    • pp.133-140
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    • 2002
  • Phosphogypsum is a by-product from the phosphoric acid process for manufacturing fertilizers. It consists mainly of $(CaSO_4.2H_2O)$ and contains some impurities such as$(P_2O_5)$, 불소$(F_-)$, and organic substances. The annual world production of this material is up to 150 million tons and is up to 1.57 million tons in Korea. Therefore studies describe application of phosphogypsum to daily and middle cover materials in landfill. For this Purpose, experiments were performed to evaluate the engineering properties of the material by sieve analysis, specific gravity, consistency of soil, compaction, CBR, permeability, mi environmental characteristics of leaching test, reactor test. The results of this study are as follows : The mixing and layer conditions of CBR value are 6.2~6.3%, coefficient of permeability is $\alpha$$\times10_{-5}~10_{-6}cm/sec$. And leaching test results are far below than those of regulatory requirement of Waste Management Act, Soil Environment Preservation Act in Korea and RCRA in USA. Therefore phosphogypsum can be used as daily and intermediate cover materials in landfill.

Possible Use of NIR Spectroscopy for Soil Testing (토양검정에서 근적외 분광분석기의 이용 가능성)

  • Ryu, Kwan-Shig;Cho, Rae-Kwang;Park, Woo-Churl;Kim, Bok-Jin
    • Korean Journal of Soil Science and Fertilizer
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    • v.34 no.4
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    • pp.273-277
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    • 2001
  • Traditional methods of chemical analysis for the soil properties take time and produce harmful waste. The purpose of this research was to evaluate an NIR technique for measuring some soil properties that are rapid and accurate in soil fertility assessments. The NIR instrument (InfraAlyzer 500, Bran & Luebbe Co.) was used for obtaining spectral data from 140 finely ground soil for calibrations and validation estimating pH, CEC, extractable Ca, Mg, K, $SiO_2$, humic acid and EC. Partial least square regression analysis was used to develop a calibration of NIR spectroscopy method. The results indicated that NIR spectroscopy could be used as a routine nondestructive method quantitatively determining soil chemical properties quickly. However the NIR technique may require sample preparation to obtain even diffuse reflection spectra from the soil and data manipulations to obtain optimal predictions.

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Development of Assembly for Fast BOD Estimation and Its Applications (신속한 BOD 측정장치의 개발과 응용)

  • Soon, Moo-Jeong;Kim, Eun-Jeong;Jang, Seh-Yong;Hong, Daeil
    • Analytical Science and Technology
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    • v.7 no.3
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    • pp.285-291
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    • 1994
  • A microbial BOD sensor for the continuous estimation of BOD was been developed by immobilizing Trichosporon cutaneum, which was immobilized between a dialysis and a gas-permeable membrane, on an oxygen electrode. The optimum pH and temperature for BOD measurement using this sensor were pH 7.0 and $32{\sim}33^{\circ}C$, respectively. The best result was obtained at 2~3ml/min flow rate in 0.1M phosphate buffer solution. A linear relationship was observed between ${\Delta}DO$ and the concentration of standard GGA solution below 60mg/l(90ppm $BOD_5$). The reproducibility was found to be within 3% for the standard solution containing glucose 30mg/l and glutamic acid 30mg/l. The output DO value of this sensor was almost constant for 30 dalys. The response time and the recovery time were about 5 and 10 min, respectively. This sensor was employed for the BOD measurement of waste pollutants and was compared with $BOD_5$ method.

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Effects of Supplementing Gamba Grass (Andropogon gayanus) with Cassava (Manihot esculenta Crantz) Hay and Cassava Root Chips on Feed Intake, Digestibility and Growth in Goats

  • Phengvichith, Vanthong;Ledin, Inger
    • Asian-Australasian Journal of Animal Sciences
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    • v.20 no.5
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    • pp.725-732
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    • 2007
  • The effects of supplementing Gamba grass (Andropogon gayanus) with varying levels of hay from cassava (Manihot esculenta Crantz) and dried cassava root chip on growth and diet digestibility were studied using local male goats with an average initial body weight of 14.0 kg. Thirty-two animals were allocated to a completely randomized $2{\times}2$ factorial design with eight animals per treatment. The factors were two levels of cassava hay (25% and 35% of an expected dry matter (DM) intake of 3% of body weight) and cassava root chips (0 or 1% of body weight) on an individual basis with grass offered ad libitum. Another four animals were assigned to a $4{\times}4$ Latin square design to study digestibility, and were given the same four diets as in the growth experiment. Total DM intake was significantly higher in the group fed diets with cassava hay and root while the DM intake of Gamba grass was not significantly different between treatments. The supplementation with cassava hay and root increased the apparent digestibility of DM, organic matter and N and resulted in a higher N-retention. The apparent digestibility of neutral detergent fibre and acid detergent fiber was not affected significantly. The average daily gain of animals fed diets supplemented with both cassava hay and root was significantly higher than for the animals supplemented with cassava hay alone. The highest daily gain recorded was 70 g/day. In conclusion, supplementing a basal diet of Gamba grass with cassava hay and root chips improved DM intake, digestibility, N-retention and weight gain. In order to minimize the waste of cassava hay, the inclusion level of cassava hay can be recommended to be 25% of expected DM intake, which would give acceptable intake and growth performance when cassava root is included in the diet.

Utilization of Potato Starch Processing Wastes to Produce Animal Feed with High Lysine Content

  • Li, Ying;Liu, Bingnan;Song, Jinzhu;Jiang, Cheng;Yang, Qian
    • Journal of Microbiology and Biotechnology
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    • v.25 no.2
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    • pp.178-184
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    • 2015
  • This work aims to utilize wastes from the potato starch industry to produce single-cell protein (SCP) with high lysine content as animal feed. In this work, S-(2-aminoethyl)-L-cysteine hydrochloride-resistant Bacillus pumilus E1 was used to produce SCP with high lysine content, whereas Aspergillus niger was used to degrade cellulose biomass and Candida utilis was used to improve the smell and palatability of the feed. An orthogonal design was used to optimize the process of fermentation for maximal lysine content. The optimum fermentation conditions were as follows: temperature of 40℃, substrate concentration of 3%, and natural pH of about 7.0. For unsterilized potato starch wastes, the microbial communities in the fermentation process were determined by terminal restriction fragment length polymorphism analysis of bacterial 16S rRNA genes. Results showed that the dominant population was Bacillus sp. The protein quality as well as the amino acid profile of the final product was found to be significantly higher compared with the untreated waste product at day 0. Additionally, acute toxicity test showed that the SCP product was non-toxic, indicating that it can be used for commercial processing.

Ammonia Removal Characteristics of Artificial Zeolite Pellet Using Multi-Stage Adsorption Column (다단계 흡착장치를 이용한 인공제오라이트 펠렛의 암모니아 제거 특성)

  • 김완태;이성오;윤연흠;신방섭
    • Resources Recycling
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    • v.7 no.1
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    • pp.20-26
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    • 1998
  • The mdy is to investigate the capanty and charactoristics of ammonia removal from waste water by artificial zeolite pellet which was synlhesized physicochemically using fly ash. A multi-stage adsorption method was adapted anrl the zeolile pellct as well as two types of natural zeolites are used for adsorption tests of ammonia io order to compare he adsorption capabilities with one anothcr. The expzrimmts was conducted into thrze stages, lhat is early, mddle and last according la the adsorbing stage and lhe number of column used. When camparing the removal efiicicncy in the final stage namral rcolites ratcd 64.5% and 78 5%, while zeohtc pdct rated 80.596, which showed larger amount of ammonia was adsorbed continuously than in other samples. Thc amount of adsorbed ammonia increased rs thc concenlraiion of ammonia increased and tl~e va~iation depending on the pH range showcd that larger amaunt of ammonia tended to be adsorbed m the neutral or akali pH range than in the acid pH range.

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The Optimization of Hydrometallurgical Process for Recovery of Zinc from Electric Arc Furnace Dust (Part I : leaching process) (습식산화법을 이용한 제강분진 내 아연회수를 위한 최적조건 도출에 관한 연구(Part I; 침출공정))

  • Moon, Dea-Hyun;Ahn, Sang-Woo;Kim, Han-lae;Kim, Ji-Tae;Chang, Soon-Woong
    • Resources Recycling
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    • v.24 no.3
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    • pp.27-33
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    • 2015
  • EAFD (Electric Arc Furnace Dust) is considered as pernicious pollutant, assigned hazardous waste. Since this dust is a by-product of industry, it contains valuable metals such as Fe, Zn, Ni, Cu which can be turned into resources by recycling process. In this study, hydrometallurgical process was applied to recover Zn from Electric Arc Furnace Dusts. The result showed 95% Zn recovery at 3M $H_2SO_4$, Solids/Liquid ratio 1:2 and aeration of 1.8L/min for 2hr. However there was 80% Zn recovery at lower $H_2SO_4$ concentration apply for pilot scale plant.

Application of geophysical and geochemical methods to investigation of AMD environment (AMD 환경평가를 위한 지구물리${\cdot}$지구화학탐사의 적용사례)

  • Kim Jisoo;Han Soohyung;Choi Sanghoon;Lee Pyeongkoo
    • 한국지구물리탐사학회:학술대회논문집
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    • 2005.05a
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    • pp.267-272
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    • 2005
  • Geophysical surveys were performed in three abandoned mines: Jangpoong, Kwangyang, Imchon. The main objectives of the researches include delineating the pathways of leachate from acid mine drainage(AMD), mapping buried rock wastes and tailings, detecting drainage pipes, and investigating the gallery and membrane, if they exist, Geophysical responses were well correlated with the results from water sample data(i.e., pH, EC, heavy metal contents, $SO_4^{-2}$). Main pathways of the leachate were successfully detected in electrical resistivity sections and self-potential(SP) profiles, whereas waste rocks, drainage pipes, and membranes were effectively located by incorporating seismic refraction, electrical resistivity and GPR methods.

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Evaluation of membrane fouling characteristics due to manganese and chemical cleaning efficiency in microfiltration membrane process (막여과 정수처리공정에서 망간에 의한 막오염 특성 및 화학세정효율 평가)

  • Kang, Joon-Seok;Park, Seogyeong;Song, Jiyoung;Jeong, Ahyoung;Lee, Jeong-Jun;Kim, Han-Seung
    • Journal of Korean Society of Water and Wastewater
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    • v.31 no.6
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    • pp.539-549
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    • 2017
  • In water treatment process using microfiltration membranes, manganese is a substance that causes inorganic membrane fouling. As a result of analysis on the operation data taken from I WTP(Water Treatment Plant), it was confirmed that the increase of TMP was very severe during the period of manganese inflow. The membrane fouling fastened the increase of TMP and shortened the service time of filtration or the cleaning cycle. The TMP of the membrane increased to the maximum of $2.13kgf/cm^2$, but it was recovered to the initial level ($0.17kgf/cm^2$) by the 1st acid cleaning step. It was obvious that the main membrane fouling contaminants are due to inorganic substances. As a result of the analysis on the chemical waste, the concentrations of aluminum(146-164 mg/L) and manganese(110-126 mg/L) were very high. It is considered that aluminum was due to the residual unreacted during coagulation step as a pretreatment process. And manganese is thought to be due to the adsorption on the membrane surface as an adsorbate in feed water component during filtration step. For the efficient maintenance of the membrane filtration facilities, optimization of chemical concentration and CIP conditions is very important when finding the abnormal level of influent including foulants such as manganese.

Geochemical Characteristics of Intertidal Sediment in the Semi-enclosed Bays of the Southern Region of Jeollanam Province (전남 남부 반폐쇄적인 내만 갯벌 퇴적물의 지화학적 특성)

  • Hwang, Dong-Woon;Kim, Pyoung-Joong;Jeon, Sang-Back;Koh, Byoung-Seol
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.46 no.5
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    • pp.638-648
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    • 2013
  • To understand the geochemical characteristics of intertidal sediment in a semi-enclosed bay, we measured various geochemical parameters, including grain size, ignition loss (IL), chemical oxygen demand (COD), acid volatile sulfide (AVS), and trace metals (Al, Fe, Cu, Pb, Zn, Cd, Hg, and As), in intertidal sediment from three bays (Deukryang Bay, Yeoja Bay, and Gamak Bay) in the southern region of Jeollanam Province. The intertidal sediment in Deukryang Bay consisted of various sedimentary types, such as sand, gravelly muddy sand, mud, and silt, whereas the intertidal sediments in Yeoja and Gamak Bays were composed mainly of mud. The concentrations of IL, COD, AVS and trace metals in the intertidal sediments of the three study regions were relatively high near areas affected by input of stream waters and/or shellfish farming waste. The concentrations of organic matter and trace metals in Gamak Bay were much higher than those in Deukryang and Yeoja Bays, which appears to be due to the influence of anthropogenic pollutants, originating from the city and the industrial complex near Gamak Bay. The evaluation results of organic matter and metal pollution using the sediment quality guidelines showed that the intertidal sediments in the three study regions were not polluted in terms of organic matter and trace metals. In future, sustainable management for sources of organic matter and trace metal is necessary to conserve a healthy benthic ecosystem in intertidal sediments.