• Proceedings of the Korean Institute of Building Construction Conference
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• 2016.10a
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• pp.56-57
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• 2016

Recently amongst Korea's construction companies there has been heightened interest in environment load reduction and resource recycling. As a result, the construction industry is examining recycled materials alternative to cement and blast-furnace slag (BS henceforth) cement, such as waste refractories and desulfurized plaster. This study analyzes the liquidity and intensity characteristics of mortar according to changes in replacement ratios of waste refractories and desulfurized plaster, used as industry by-products in mortar environments that use BS 3-type cements and circulated fine aggregate. As a result, the greater the increase in replacement ratios of desulfurized plaster, the greater the increase in liquidity and air quantity, as well as compression strength.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.2
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• pp.185-191
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• 2017

The objective of this paper is to investigate the effect of waste refractory powder(WRP) and desulfurization gypsum(FGD) as activators on the flow properties and the strength development of high volume blast furnace slag mortar incorporating illite(BSM) having adsorption and deodorization. To fabricate the BSMs with 60% of W/B, blast furnace slag are incorporated with 45% and 65%, respectively. WRP and FGD are substituted from 5 to 10%. Test results indicate that the flow is decreased with increase of WRP and FGD, while increase of WRP and FGD enhance the compressive strength due to accelerated reaction of blast furnace slag, The use of illite results in a decrease of compressive strength. pH has increasing tendency until 7days, while it has reduction. In this paper, optimal dosages of WRP and FGD are believed to be around 5% each.

• Journal of the Korean GEO-environmental Society
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• v.12 no.1
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• pp.35-40
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• 2011

Magnesia-carbon brick is used to refractory material in Converter and/or Ladle furnace for molten steel manufacturing. The rapid growth of steel making industry, molten steel industry is increased. Therefore, growth of molten steel industry lead to make waste magnesia-carbon brick by repair of Converter and/or Ladle furnace. These waste magnesia-carbon brick is abandoned all. Besides, as it is loosely composed of silt and clay including sand falling according to the type of gangue, rainwater inflows and outflows relatively easily, but silt or clay particles absorb water for a long period, weakening ground. This study tried to show that when colluvial soil is solidified using waste magnesia-carbon brick powder as a way to solidify strengthen the rigidity of colluvial soil.

• Journal of Korean Society on Water Environment
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• v.25 no.5
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• pp.674-681
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• 2009

Characteristics of organic matters (OM) in wastewater and the removal efficiencies were investigated using the influent and the effluent samples collected from 21 wastewater treatment plants. The OM characteristics investigated included biodegradability, humic content, specific UV absorbance (SUVA), the distribution percentage of refractory OM (R-OM), and synchronous fluorescence spectra. The types of wastewater (sewage, livestock waste/night soils, industrial waste) were easily distinguished by comparing the synchronous fluorescence spectra of the influent wastewater. The prominent peak of protein-like fluorescence (PLF) was observed for livestock waste/night soils whereas sewage exhibited a unique fluorescence peak at a wavelength of 370 nm. Irrespective of the wastewater types, the distribution percentage of R-OM increased from the influent to the effluent. Livestock waste/night soils showed the highest removal efficiency among all the three types of wastewater. There was no statistical difference of the removal efficiency between a traditional activated sludge and biological advanced treatment processes. Removal efficiency based on dissolved organic carbon DOC presented good correlations with the distribution percentage of R-OM and fulvic-like fluorescence (FLF) of the influent. The prediction for DOC removal efficiency was improved by using multiple regression analyses based on some selected OM characteristics and mixed liquid suspended solid (MLSS).

• Journal of the Korean Ceramic Society
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• v.13 no.1
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• pp.25-29
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• 1976

The properties vary with quality of ferric-oxide that is major material of ferrites. In this point of view, a manufacturing method of pure and homogeneous fine ferric oxide is very important. The characters of this study are as follows: 1) Ferric oxide was made from waste pickling liquor of steel. 2) The crude ferric-oxide that is made by roasting the pickling liquor was dissolved in 20% HCI solution and then produced ferric chloride is purified by ethyl ether extraction. 3) The methanol solution of purified ferric chloride was sprayed into the refractory tube with compressed air and propane gas and then ignited leading to the ferric-oxide powder. 4) The produced oxide powder was introduced to the scrubber type vessel throught cooling system in order to collect the powder. 5) Crystalline phase of the powder was identified by X-ray diffraction and particle size, crystalline shape of the powder were investigated by settling method and electron microscope and the effects of concentration of ferric chloride in methanol on grain size were discussed. Results were obtained as fellows: 1) Total impurity in the ferric oxide produced from waste pickling liquor was 3.7%. 2) The solubilityof crude ferric oxide that was made from waste pickling liquor in HCI solution increased with the HCI concentration and reached to saturation range at 15% HCI concentration. 3) Extraction of FeCl3 increased with HCI concentration which is solvent. 4) Alpha ferric oxide obtained was very fine crystalline particles, the mean crystalline grain increased with the concentration of ferric chloride, and mean grain size distributed from 3.5$\mu$(at 0.5mole/l) to 0.5$\mu$(at 0.05mole/l).

• Journal of Korean Society of Environmental Engineers
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• v.35 no.12
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• pp.960-966
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• 2013

In this study, operation data from an actual plant in M city were analyzed to evaluate effects of water supply into sewage sludge on the co-incineration of municipal solid waste (MSW) and sewage sludge. Design capacity of the stoker incinerator is 50 m3/day. Maximum portion of sewage sludge in the total waste input was 20%. According to this research, moisture content increase up to 85% of sewage sludge could be possible by water supply on MSW input to the incinerator. Therefore, stable operation of incinerator could be achieved. As water was added into sewage sludge up to 85%, input quantity of sewage sludge to frequency (Hz) was similar to theoretical input. Also, it is concluded that stable management of incinerator without leachate combustion and damages of refractory bricks and castable could be achieved by the reduction of low heating value.

• Journal of Environmental Science International
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• v.22 no.3
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• pp.269-279
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• 2013

In this paper, an environmental assessment was carried out on the whole process of industrial business activities to establish a basic plan for climate change mitigation and energy independency. The whole process was divided into each discharge process in terms of water, air, solid waste, green house gases and refractory organic compounds. The flowcharts and basic unit of process were analysed for three years (2008-2010), being utilized as basic information for the life cycle assessment. It was found that the unit loading for the whole process significantly depends on changes in the operation rate change and highly concentrated wastewater inflow. About 35% of solid waste production was reduced by improving the incineration method with co-combustion in coal boiler, generating about 57% of electricity used for the whole process, and consequently reducing the energy costs. As the eco-efficiency index was found to be more than 1, compared to the previous years, it can be said that improvement in general has taken place.

• Proceedings of the KIEE Conference
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• 2005.11a
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• pp.191-193
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• 2005

This study has investigated the effects of the etching method of a Ti substrate for a metal oxide electrode on the electrochemical characteristics of the electrode. The HCl etching develops a fine and homogeneous roughness on the Ti substrate. Fabrication and material properties of the catalytic oxide electrode, which is known to be so effective to destruct refractory organics in aqueous waste, were studied. A method to enhance the fabrication reproducibility of the oxide electrode was tested for Ru, Zr, Sn oxide on the Ti substrate using SEM, XRD, Cyclic voltammetry.

• Journal of Korean Society on Water Environment
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• v.18 no.3
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• pp.245-251
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• 2002

Reactive dyes waste water, a toxic and refractory pollutant, was treated by an electrochemical method using $Ti/IrO_2$ as anode and Stainless Steel 316 as cathode. In this technique, sodium chloride as an electrolyte was added. A number of experiments were run in a batch system. Artificial samples (reactive blue 19, red 195, yellow 145) were used. Operation parameters, such as supporting electrolyte concentration, current density, pH and sample concentration have been investigated for their influences on COD and color removal efficiencies during electrolysis. After 5 and 90 minites of eletrolysis, color was reduced by 51.5% and 98.9% respectively. Under the condition of current density $10A/dm^2$, NaCl concentration 12mg/l and pH 3, 62.9% of $COD_{Cr}$ was removed after electrolysis for 90 minites. The optimum condition of color removal and COD reduction in this work was found to be the following : pH 3, sodium chloride concentration 20g/l, current density $10A/dm^2$. As a result, we confirmed to be effective to color removal and reduction of refractory organic material.

• Resources Recycling
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• v.18 no.4
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• pp.14-23
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• 2009

In terms of resources recycling and resolving waste disposal problems, it is very important to recover precious metals like Au, Ag and Pd and valuable metals like Cu, Sn and Ni from the scraps of waste electrical and electronic equipment(WEEE) that consists of detective electrical and electronic parts discarded during manufacturing electrical and electronic equipments and waste electrical and electronic parts generated during disassembling them. In general, the scraps of WEEE are composed of various metals and alloys as well as refractory oxides and plastic components. Precious and valuable metals from the scraps of WEEE can be recovered by gas-phase-volatilization, hydrometallurgical, or pyrometallurgical processes. However, the gas-phase-volatilization and hydrometallurgical processes have been suggested but not yet commercialized. At the present time, most of the commercial plants for recovering precious and valuable metals from the scraps of WEEE adopt pyrometallurgical processes. Therefore, in this paper, the technical and environmental aspects on the important pyrometallurgical processes through literature survey are reviewed, and the scale-up result of a new pyrometallurgical process for recovering the precious and valuable metals contained in the scraps of WEEE using waste copper slag is presented.